skip to main content

Sorption Ability of Bentonite Rocks from Yogyakarta to Eliminate the Radiocesium Elements in Solution

Center for Radioactive Waste Technology, National Nuclear Energy Agency, Indonesia

Received: 26 Oct 2018; Revised: 16 Jan 2019; Accepted: 25 Jan 2019; Published: 31 Jan 2019.
Open Access Copyright 2019 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

Citation Format:
Cover Image
Abstract

This activity was to examine the ability of bentonite minerals from Yogyakarta to absorb the radiocesium contained in the solution. The purposes of the experiment were to determine sorption ability of bentonite mineral from Yogyakarta to absorb radiocesium in solution or groundwater and to enrich the Indonesia bentonite capability database to absorb radiocesium. The bentonite material was planned to be used as a buffer material of the engineered barrier system on the radwaste disposal facility in the future. The contact time, the presence of Na and K ions in the solution, as well as the variable of dissolved CsCl concentration were considered as experiment parameters. The value of Kd was also used as the indicator of radiocesium sorption into the bentonite samples. The experiment results shown that the maximum of Kd value was about 6800 mL/g for sample-1, and the presence of dissolved Na and K ions in the solution could reduce the values of Kd which were 800 and 300 mL/g for sample-1, respectively. Determination of isotherm sorption of radiocesium by bentonite from Yogyakarta was approximated by using linear equation or Freundlich law.

Fulltext View|Download
Keywords: bentonite; sorption; barrier material; 137Cs
Funding: Center for Radioactive Waste Technology-BATAN

Article Metrics:

  1. International Atomic Energy Agency, Scientific and technical basis for the near surface disposal of low and intermediate level waste, in: Technical reports series no. 412, International Atomic Energy Agency, Vienna, 2002
  2. Patrik Sellin and Olivier X. Leupin, The Use of Clay as an Engineered Barrier in Radioactive-Waste Management – A Review, Clays and Clay Minerals, 61, 6, (2013) 477-498 http://doi.org/10.1346/ccmn.2013.0610601
  3. Roland Pusch, Sven Knutsson, Laith Al-Taie and Mohammed Hatem Mohammed, Optimal ways of disposal of highly radioactive waste, Natural Science, 4, 11, (2012) 906-918 http://dx.doi.org/10.4236/ns.2012.431118
  4. Nikolai P. Laverov, Sergey V. Yudintsev, Boris T. Kochkin and Victor I. Malkovsky, The Russian Strategy of using Crystalline Rock as a Repository for Nuclear Waste, Elements, 12, 4, (2016) 253-256 http://doi.org/10.2113/gselements.12.4.253
  5. Ulla Bergstroem, Karin Pers and Ylva Almen, International perspective on repositories for low level waste, in, Swedish Nuclear Fuel and Waste Management Co., Stockholm, 2011, pp. 72
  6. Geraldina Geraldina, Taslimah Taslimah and Rahmad Nuryanto, Pemanfaatan Montmorillonit Terpilar Al-Cr pada Adsorpsi Zat Warna Rhodamin B dengan Variasi Massa Adsorben dan Waktu Adsorpsi, Jurnal Kimia Sains dan Aplikasi, 19, 3, (2016) 99-106 10.14710/jksa.19.3.99-106
  7. M.J. Wilson, Rock-forming Minerals, Geological Society, 2013
  8. Guosheng Yang, Hirofumi Tazoe and Masatoshi Yamada, 135Cs activity and 135Cs/137Cs atom ratio in environmental samples before and after the Fukushima Daiichi Nuclear Power Plant accident, Scientific Reports, 6, (2016) 24119 https://dx.doi.org/10.1038%2Fsrep24119
  9. Budi Setiawan, Oktri Mila and Safni, Interaction of Sr-90 with site candidate soil for demonstration disposal facility at Serpong, AIP Conference Proceedings, 1589, 1, (2014) 325-328 http://doi.org/10.1063/1.4868811
  10. Budi Setiawan, Elfira Mayasari and Shely Meidhika, Evaluation of Radiocesium Sorption in Some Materials as Safety Barrier System of Radioactive Waste Disposal Demonstration Facility, Procedia Chemistry, 16, (2015) 445-450 https://doi.org/10.1016/j.proche.2015.12.077
  11. Budi Setiawan, Yusran Dani and Nurmaya Arofah, Sorption Characteristics of 137 Cs and 90 Sr into Rembang and Sumedang Soils, Indonesian Journal of Chemistry, 16, 3, (2018) 277-282 http://doi.org/10.22146/ijc.21142
  12. Karin Norrfors, Stability and sorption capacity of montmorillonite colloids : Investigation of size fractional differences and effects of γ-irradiation, Doctoral thesis, comprehensive summary, TRITA-CHE-Report, KTH Royal Institute of Technology, Stockholm
  13. B. Yıldız, H. N. Erten and M. Kış, The sorption behavior of Cs+ ion on clay minerals and zeolite in radioactive waste management: sorption kinetics and thermodynamics, Journal of Radioanalytical and Nuclear Chemistry, 288, 2, (2011) 475-483 http://doi.org/10.1007/s10967-011-0990-5
  14. Chad B. Durrant, James D. Begg, Annie B. Kersting and Mavrik Zavarin, Cesium sorption reversibility and kinetics on illite, montmorillonite, and kaolinite, Science of The Total Environment, 610-611, (2018) 511-520 https://doi.org/10.1016/j.scitotenv.2017.08.122
  15. V. V. Krupskaya, S. V. Zakusin, E. A Tyupina, O. V. Dorzhieva, A. P. Zhukhlistov, P. E Belousov and M. N. Timofeeva, Experimental Study of Montmorillonite Structure and Transformation of Its Properties under Treatment with Inorganic Acid Solutions, Minerals, 7, 49, (2017) 1-11 http://doi.org/10.20944/preprints201612.0100.v1
  16. Barbara Bartoś, Barbara Filipowicz, Monika Łyczko and Aleksander Bilewicz, Adsorption of 137Cs on titanium ferrocyanide and transformation of the sorbent to lithium titanate: a new method for long term immobilization of 137Cs, Journal of Radioanalytical and Nuclear Chemistry, 302, 1, (2014) 513-516 http://dx.doi.org/10.1007/s10967-014-3218-7
  17. Mohamed H. Ali, Abd-Ellatif M. Hussian, Amaal M. Abdel-Satar, Mohamed E. Goher, Agnieszka Napiórkowska-Krzebietke and Ahmed M. Abd El-Monem, The isotherm and kinetic studies of the biosorption of heavy metals by non-living cells of Chlorella vulgaris, Journal of Elementology, 21, 4, (2016) 1263-1276 http://doi.org/10.5601/jelem.2016.21.1.1040
  18. Juan Carlos Moreno-Piraján and Liliana Giraldo, Heavy Metal Ions Adsorption from Wastewater Using Activated Carbon from Orange Peel, E-Journal of Chemistry, 9, 2, (2012) http://doi.org/10.1155/2012/383742

Last update:

  1. Diffusion capability of Cs-137 in compacted soil and bentonite under groundwater-saturated condition

    Sufi Adzkia Salma, Nurul Efri Ekaningrum, Hendra Adhi Pratama, Budi Setiawan. Discover Environment, 2 (1), 2024. doi: 10.1007/s44274-024-00057-x

Last update: 2024-11-20 19:54:41

No citation recorded.