DOI: https://doi.org/10.14710/jksa.22.5.184-191

Pengoptimuman Kondisi Adsorpsi Cd(II) oleh Adsorben Berbasis Silika Termodifikasi Glisina Menggunakan Central Composite Design

Optimization of Cd(II) adsorption condition by glycine-modified silica-based adsorbent using central composite design

Department of Chemistry, Faculty of Mathematics and Natural Sciences, IPB University, Indonesia

Received: 30 May 2019; Revised: 24 Aug 2019; Accepted: 9 Sep 2019; Published: 30 Sep 2019.
Open Access Copyright 2019 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract
Silica gel (SG) is one of common adsorbent on solid phase extraction for preconcentration. Due to the low selectivity and effectiveness of adsorption to metal ions, SG should be modified. The SG was modified with d-glycine (Si-Gly) using 3-aminopropyltrimethoxysilane and glutaraldehyde as a crosslinker. Capability of Si-Gly as adsorbent for cadmium ions (Cd) was investigated using batch adsorption. The result was proved by infrared spectra. The optimum condition of Cd adsorption by the Si-Gly was obtained at pH 5, with 0.3 g of adsorbent and 11 minutes of contact time. The percentage of Cd adsorption at the optimum condition by the Si-Gly (99.34%) which is greater than the SG (89.03%). The maximum adsorption capacity of the Si-Gly is 9.77 mg/g, obtained at 400 mg/L. The Cd(II) adsorption on the SG and the Si-Gly follow the Langmuir isotherm equation.
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Keywords: Adsorbent; Cd(II); D-glycine; silica gel

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Language : ID
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  2. Gunnar F. Nordberg, Historical perspectives on cadmium toxicology, Toxicology and Applied Pharmacology, 238, 3, (2009) 192-200 https://doi.org/10.1016/j.taap.2009.03.015
  3. Ernest Hodgson, A Textbook of Modern Toxicology, John Wiley & Sons, 2004
  4. Pemerintah Republik Indonesia, Peraturan Pemerintah No. 82 Tahun 2001 tentang Pengelolaan Kualitas Air dan Pengendalian Pencemaran Air, in: P.R. Indonesia (Ed.), Jakarta, 2001
  5. C Supriyanto, A Purwanto, Validasi Metode Spektrometri Serapan Atom pada Analisis Logam Berat Cr, Cu, Cd, Fe, Pb, Zn dan Ni dalam Contoh Uji Air Laut, in: Pertemuan dan Presentasi Ilmiah - Penelitian Dasar Ilmu Pengetahuan dan Teknologi Nuklir (PPI-PDIPTN), Pusat Teknologi Akselerator dan Proses Bahan–BATAN, Yogyakarta, 2010, pp. 115-122
  6. Bakri Ridla, Utari Tresye, Sari Indra Puspita, Kaolin Sebagai Sumber SiO2 untuk Pembuatan Katalis Ni/SiO2: Karakterisasi dan Uji Katalis pada Hidrogenasi Benzena Menjadi Sikloheksana, Makara Journal of Science, 12, 1, (2008) 37-43 https://doi/org/10.7454/mss.v12i1.304
  7. Buhani Buhani, Narsito Narsito, Nuryono Nuryono, Eko Sri Kunarti, Amino and Mercapto-Silica Hybrid for Cd(II) Adsorption in Aqueous Solution, Indonesian Journal of Chemistry, 9, 2, (2009) 170-176 https://doi.org/10.22146/ijc.21525
  8. B. Puzio, B. Mikula, B. Feist, Preconcentration of Cd(II), Pb(II), Co(II), Ni(II), and Cu(II) by solid-phase extraction method using 1,10-phenanthroline, Journal of Analytical Chemistry, 64, 8, (2009) 786-790 http://doi.org/10.1134/S1061934809080036
  9. Mahmood Payehghadr, Farzaneh Nourifard, Chiman Shahoei, Mehdi Kalhor, Flame Atomic Absorption Determination of Cd and Cu in Biological Samples After Solid Phase Extraction by Octadecyl Silica Membrane Disks Modified With a Schiff Base Ligand, Orbital: The Electronic Journal of Chemistry, 10, 7, (2018) 489-495 http://dx.doi.org/10.17807/orbital.v10i7.1111
  10. Saman Bagheri, Mostafa M. Amini, Mohammad Behbahani, Ghazal Rabiee, Low cost thiol-functionalized mesoporous silica, KIT-6-SH, as a useful adsorbent for cadmium ions removal: A study on the adsorption isotherms and kinetics of KIT-6-SH, Microchemical Journal, 145, (2019) 460-469 https://doi.org/10.1016/j.microc.2018.11.006
  11. Nahid Pourreza, Roya Mirzajani, Ali Reza Kiasat, Rezvan Abdollahzadeh, Simultaneous preconcentration of Cu(II), Cd(II) and Mn(II) on silica-polyethylene glycol and determination by flame atomic absorption spectrometry, Química Nova, 35, (2012) 1945-1949 http://dx.doi.org/10.1590/S0100-40422012001000011
  12. Xinyan Bi, Rong Jia Lau, Kun-Lin Yang, Preparation of Ion-Imprinted Silica Gels Functionalized with Glycine, Diglycine, and Triglycine and Their Adsorption Properties for Copper Ions, Langmuir, 23, 15, (2007) 8079-8086 http://doi.org/10.1021/la7008072
  13. P. Vejayakumaran, I. A. Rahman, C. S. Sipaut, J. Ismail, C. K. Chee, Structural and thermal characterizations of silica nanoparticles grafted with pendant maleimide and epoxide groups, Journal of Colloid and Interface Science, 328, 1, (2008) 81-91 https://doi.org/10.1016/j.jcis.2008.08.054
  14. Hongbo Xu, Yun Wu, Jian Wang, Xuewei Shang, Xiaojun Jiang, Simultaneous preconcentration of cadmium and lead in water samples with silica gel and determination by flame atomic absorption spectrometry, Journal of Environmental Sciences, 25, (2013) S45-S49 https://doi.org/10.1016/S1001-0742(14)60624-0
  15. Nurhajawarsi Nurhajawarsi, Mohamad Rafi, Utami Dyah Syafitri, Eti Rohaeti, L-Histidine-Modified Silica from Rice Husk and Optimization of Adsorption Condition for Extractive Concentration of Pb(II), The Journal of Pure and Applied Chemistry Research, 7, 2, (2018) 198-208 http://dx.doi.org/10.21776/ub.jpacr.2018.007.02.402
  16. Wenlu Guo, Rui Chen, Yan Liu, Minjia Meng, Xiangguo Meng, Zhaoyong Hu, Zhilong Song, Preparation of ion-imprinted mesoporous silica SBA-15 functionalized with triglycine for selective adsorption of Co(II), Colloids and Surfaces A: Physicochemical and Engineering Aspects, 436, (2013) 693-703 https://doi.org/10.1016/j.colsurfa.2013.08.011
  17. Zaharaddeen N. Garba, Idris Bello, Ahmad Galadima, Aisha Y. Lawal, Optimization of adsorption conditions using central composite design for the removal of copper (II) and lead (II) by defatted papaya seed, Karbala International Journal of Modern Science, 2, 1, (2016) 20-28 https://doi.org/10.1016/j.kijoms.2015.12.002
  18. Mahmoud A. A. Aslani, Fatih Celik, Sabriye Yusan, Ceren Kutahyali Aslani, Assessment of the adsorption of thorium onto styrene–divinylbenzene-based resin: Optimization using central composite design and thermodynamic parameters, Process Safety and Environmental Protection, 109, (2017) 192-202 https://doi.org/10.1016/j.psep.2017.02.019
  19. Shun He, Wenbing Zhang, Deguang Li, Pingliang Li, Yuncong Zhu, Mingming Ao, Jianqiang Li, Yongsong Cao, Preparation and characterization of double-shelled avermectin microcapsules based on copolymer matrix of silica–glutaraldehyde–chitosan, Journal of Materials Chemistry B, 1, 9, (2013) 1270-1278 http://doi.org/10.1039/C2TB00234E
  20. Tayebeh Nazari, Mahdi Alijanianzadeh, Ahmad Molaeirad, Maryam Khayati, Immobilization of Subtilisin Carlsberg on Modified Silica Gel by Cross-linking and Covalent Binding Methods, Biomacromolecular Journal, 2, 1, (2016) 53-58
  21. Xiaoyu Wang, Pan Wang, Zihao Dong, Zhengping Dong, Zongyan Ma, Jian Jiang, Rong Li, Jiantai Ma, Highly Sensitive Fluorescence Probe Based on Functional SBA-15 for Selective Detection of Hg2+, Nanoscale Research Letters, 5, 9, (2010) 1468 http://doi.org/10.1007/s11671-010-9663-5
  22. B. D. Mistry, A Handbook of Spectroscopic Data Chemistry: (UV, IR, PMR, 13CNMR and Mass Spectroscopy), Oxford Book Company, 2009
  23. A.O Dada, A.P Olalekan, A.M Olatunya, O Dada, Langmuir, Freundlich, Temkin and Dubinin–Radushkevich Isotherms Studies of Equilibrium Sorption of Zn2+ Unto Phosphoric Acid Modified Rice Husk, IOSR Journal of Applied Chemistry (IOSR-JAC), 3, 1, (2012) 38-45

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