DOI: https://doi.org/10.14710/jksa.23.5.160-166

Utilization of Jengkol Peel (Pithecellobium jiringa (Jack) Prain) as Lead (II) Ions Bio-sorbent with Column Method

1STIKes Bakti Tunas Husada Tasikmalaya, Indonesia

2Universitas Muhammadiyah Tasikmalaya, Indonesia

Received: 20 Jan 2020; Revised: 23 Apr 2020; Accepted: 4 May 2020; Published: 31 May 2020.
Open Access Copyright 2020 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

Citation Format:
Cover Image
Abstract
Problems arising from laboratory waste include the content of lead metal ions in it, which can affect health. While on the other hand, Jengkol peel is a market waste and has no economic value. Jengkol peel contains hydroxyl groups and carboxylates to bind heavy metals such as lead (II) ions. So, this study aims to determine the effect of variations in flow rate, adsorbent height, and solution acidity and determine the ability of Jengkol peel in adsorbing lead (II) ions in the laboratory liquid by the column method. Organic groups that include active sides can be removed using 1N sodium hydroxide to increase the adsorption ability. Sodium hydroxide functions to dissolve lignin in lignocellulose compounds so that carboxylic groups are formed in cellulose, which has a role in binding metal ions. The determination of functional groups was carried out by Fourier-transform Infrared Spectroscopy. The identification of the adsorbent morphology was carried out by Scanning Electron Microscope. The adsorption of lead (II) ions by Jengkol peel was determined by calculating the difference between the lead (II) ions in the solution after and before passing through the column. The amount of lead metal remaining in solution was determined using Atomic Absorption Spectroscopy. Sodium hydroxide solution with a concentration of 1N can separate lignin from cellulose contained in lignocellulose to enhance the bio-sorbent ability of the Jengkol peel in binding metal ions. The smaller the flow rate in the column, the higher the amount of lead (II) ions adsorbed in the bio-sorbent. The acidity of the solution has the best adsorption at pH 5. The metal ions from the simulation sample can reduce the number of lead (II) metal ions adsorbed by 11%.
Fulltext View|Download
Keywords: Jengkol peel; laboratory liquid; lead (II) metal ions; column method
Funding: Sekolah Tinggi Ilmu Kesehatan Bakti Tunas Husada Tasikmalaya

Article Metrics:

Article Info
Section: Research Articles
Language : EN
Recent articles
Electrocoating Polypyrrole on Gold-Wire Electrode as Potential Mediator Membrane Candidate for Anionic Surfactant Electrode Sensor Utilization of Jengkol Peel (Pithecellobium jiringa (Jack) Prain) as Lead (II) Ions Bio-sorbent with Column Method Stability Improvement of Humic Acid as Sorbent through Magnetite and Chitin Modification Validation of High-Performance Liquid Chromatography Method for Determination of Vitamin B1 in Powder Milk Polymerization Domain Translated from 0.9 kb Gene Fragment of DNA Polymerase I from a Thermo-Halophilic PLS A Strain More recent articles
Most cited articles
Innovation of Carbon from Pectin Templated in Fabrication of Interlayer-free Silica-Pectin Membrane Conversion of Wood Waste to be a Source of Alternative Liquid Fuel Using Low Temperature Pyrolysis Method Impregnasi Nikel Klorida pada Zeolit-Y untuk Katalis Hidrorengkah Minyak Bumi Sintesis Metilisoeugenol dari Metileugenol Menggunakan Katalis KOH dalam Etanol Isolation of Flavonoid Compounds from Eceng Gondok (Eichhornia crassipes) and Antioxidant Tests with DPPH (1,1-Diphenyl-2-Picrylhydrazyl) Method More cited articles
  1. Wilyanda, Yelmida and Chairul, Pengolahan Limbah Cair Logam Berat (Limbah B3) secara Presipitasi dan Koagulasi di UPT Pengujian Dinas Pekerjaan Umum, Jurnal Online Mahasiswa FT Universitas Riau, 2, 2, (2015), 1-10
  2. Alok Mittal, Meenu Teotia, RK Soni and Jyoti Mittal, Applications of egg shell and egg shell membrane as adsorbents: a review, Journal of Molecular Liquids, 223, (2016), 376-387 https://doi.org/10.1016/j.molliq.2016.08.065
  3. Iva Rezić, Cellulosic fibers—Biosorptive materials and indicators of heavy metals pollution, Microchemical Journal, 107, (2013), 63-69 https://doi.org/10.1016/j.microc.2012.07.009
  4. Biljana Pejic, Marija Vukcevic, Mirjana Kostic and Petar Skundric, Biosorption of heavy metal ions from aqueous solutions by short hemp fibers: effect of chemical composition, Journal of Hazardous Materials, 164, 1, (2009), 146-153 https://doi.org/10.1016/j.jhazmat.2008.07.139
  5. Huaqing Qin, Tianjue Hu, Yunbo Zhai, Ningqin Lu and Jamila Aliyeva, The improved methods of heavy metals removal by biosorbents: A review, Environmental Pollution, 258, (2020), 113777 https://doi.org/10.1016/j.envpol.2019.113777
  6. Adhni Ranti Janatul, Pemanfaatan Ampas Teh sebagai Biosorben untuk Meningkatkan Kualitas Minyak Jelantah, undergraduate thesis, Program Studi Farmasi, STIKes BTH Tasikmalaya, Tasikmalaya
  7. Eny Yulianti, Rif'atul Mahmudah and Isna Royana, Pemanfaatan Biosorben Batang Jagung Teraktivasi Asam Nitrat dan Asam Sulfat untuk Penurunan Angka Peroksida–Asam Lemak Bebas Minyak Goreng Bekas, ALCHEMY: Journal of Chemistry, 5, 1, (2018), 9-18 http://dx.doi.org/10.18860/al.v5i1.3685
  8. Iin Safrianti, Nelly Wahyuni and Titin Anita Zaharah, Adsorpsi timbal (II) oleh selulosa limbah jerami padi teraktivasi asam nitrat: pengaruh pH dan waktu kontak, Jurnal Kimia Khatulistiwa, 1, 1, (2012), 1-7
  9. Meri Suhartini, Modifikasi Limbah Kulit Pisang untuk Adsorbenion Logam Mn (II) dan Cr(VI), Jurnal Sains Materi Indonesia, 14, 3, (2018), 229-234 http://dx.doi.org/10.17146/jsmi.2013.14.3.4414
  10. Dwi Arista Ningsih, Irwan Said and Purnama Ningsih, Adsorpsi Logam Timbal (Pb) dari Larutannya dengan Menggunakan Adsorben dari Tongkol Jagung, Jurnal Akademika Kimia, 5, 2, (2016), 55-60
  11. Novi Sylvia, Meriatna, Lukman Hakim, Fitriani and Anisma Fahmi, Kinerja Kolom Adsorpsi pada Penjerapan Timbal (Pb2+) dalam Limbah Artifisial Menggunakan Cangkang Kernel Sawit, Jurnal Integrasi Proses, 6, 4, (2017), 185-190 http://dx.doi.org/10.36055/jip.v6i4.2549
  12. Gatut Ari Wardani and Winda Trisna Wulandari, Pengaruh waktu kontak terhadap daya adsorpsi kulit jengkol (Pithecellobium jiringa) pada ion timbal (II), Prosiding Seminar Nasional Kimia UNY-2017, (2017)
  13. Julhim S. Tangio, Adsorpsi logam timbal (Pb) dengan menggunakan biomassa enceng gondok (Eichhorniacrassipes), Jurnal Entropi, 8, 1, (2013), 500-506
  14. Army Sany Haidar, Studi Adsorpsi Logam Pb(II) Menggunakan Adsorben Kulit Rambutan Teraktivasi HNO3 dan NaOH, Undergraduate Thesis, Program Studi Kimia, Universitas Islam Indonesia, Yogyakarta
  15. Guiyin Wang, Shirong Zhang, Ping Yao, Yue Chen, Xiaoxun Xu, Ting Li and Guoshu Gong, Removal of Pb (II) from aqueous solutions by Phytolacca americana L. biomass as a low cost biosorbent, Arabian Journal of Chemistry, 11, 1, (2018), 99-110 https://doi.org/10.1016/j.arabjc.2015.06.011
  16. Eddy Heraldy, Witri Wahyu Lestari, Diah Permatasari and Devita Dwi Arimurti, Biosorbent from tomato waste and apple juice residue for lead removal, Journal of Environmental Chemical Engineering, 6, 1, (2018), 1201-1208 https://doi.org/10.1016/j.jece.2017.12.026
  17. Nana Wang, Yuyin Qiu, Tangfu Xiao, Jianqiao Wang, Yuxiao Chen, Xingjian Xu, Zhichao Kang, Lili Fan and Hongwen Yu, Comparative studies on Pb(II) biosorption with three spongy microbe-based biosorbents: High performance, selectivity and application, Journal of Hazardous Materials, 373, (2019), 39-49 https://doi.org/10.1016/j.jhazmat.2019.03.056
  18. Kindy Nopiana Irma, Nelly Wahyuni and Titin Anita Zaharah, Adsorpsi Fenol Menggunakan Adsorben Karbon Aktif dengan Metode Kolom, Jurnal Kimia Khatulistiwa, 4, 1, (2015), 24-28
  19. Runping Han, Dandan Ding, Yanfang Xu, Weihua Zou, Yuanfeng Wang, Yufei Li and Lina Zou, Use of rice husk for the adsorption of congo red from aqueous solution in column mode, Bioresource technology, 99, 8, (2008), 2938-2946 https://doi.org/10.1016/j.biortech.2007.06.027
  20. Jyotsna Goel, Krishna Kadirvelu, Chitra Rajagopal and Vinod Kumar Garg, Removal of lead (II) by adsorption using treated granular activated carbon: batch and column studies, Journal of Hazardous Materials, 125, 1-3, (2005), 211-220 https://doi.org/10.1016/j.jhazmat.2005.05.032
  21. Neni Sri Wahyuni Nasir, Nurhaeni Nurhaeni and Musafira Musafira, Pemanfaatan Arang Aktif Kulit Pisang Kepok (Musa Normalis) sebagai Adsorben untuk Menurunkan Angka Peroksida dan Asam Lemak Bebas Minyak Goreng Bekas, Natural Science: Journal of Science and Technology, 3, 1, (2014), 18-30
  22. Yati B Yuliyati, Solihudin Solihudin and Atiek Rostika Noviyanti, Effect of Sodium Periodate on the Adsorption Capacity of Silica-Lignin from Rice Husk on Chromium (VI), Jurnal Kimia Sains dan Aplikasi, 22, 6, 242-249 https://doi.org/10.14710/jksa.22.6.242-249
  23. Nurussakinah, Skrining Fitokimia dan Uji Aktivitas Antibakteri Ekstrak Kulit Buah Tanaman Jengkol (Pithecellobium jiringa (Jack) Prain) terhadap Bakteri Streptococcus mutans, Staphylococcus aureus, dan Esherichia coli, undergraduate thesis, Fakultas Farmasi, Universitas Sumatera Utara, Medan
  24. Istifiarti Mandasari and Alfan Purnomo, Penurunan ion besi (Fe) dan mangan (Mn) dalam air dengan serbuk gergaji kayu kamper, Jurnal Teknik ITS, 5, 1, (2016), F11-F16 http://dx.doi.org/10.12962/j23373539.v5i1.15113
  25. Setiaty Pandia and Budi Warman, Pemanfaatan Kulit Jengkol sebagai Adsorben dalam Penyerapan Logam Cd (II) pada Limbah Cair Industri Pelapisan Logam, Jurnal Teknik Kimia USU, 5, 4, (2016), 57-63 https://doi.org/10.32734/jtk.v5i4.1556
  26. Departemen Kesehatan Republik Indonesia, Parameter standar umum ekstrak tumbuhan obat, in, Departemen Kesehatan Republik Indonesia, Jakarta, 2000, pp. 3-30
  27. Indo Esse, Pemanfaatan Lignin Hasil Delignifikasi Ampas Tebu Sebagai Perekat Lignin Resorsinol Formaldehida (LRF), undergraduate thesis, Fakultas Sains dan Teknologi, Universitas Islam Negeri Alauddin Makassar, Makassar
  28. Selviza Safaria, Idiawatin Nora and Titin Anita Zaharah, Efektivitas campuran enzim selulase dari Aspergillus niger dan Trichoderma reesei dalam menghidrolisis substrat sabut kelapa, Jurnal Kimia Khatulistiwa, 2, 1, (2013), 46-51
  29. Amarendra Dhar Dwivedi, Shashi Prabha Dubey, Krishna Gopal and Mika Sillanpää, Strengthening adsorptive amelioration: Isotherm modeling in liquid phase surface complexation of Pb (II) and Cd (II) ions, Desalination, 267, 1, (2011), 25-33 https://doi.org/10.1016/j.desal.2010.09.002
  30. Yuvaraja Gutha, Venkata Subbaiah Munagapati, Mu Naushad and Krishnaiah Abburi, Removal of Ni(II) from aqueous solution by Lycopersicum esculentum (Tomato) leaf powder as a low-cost biosorbent, Desalination and Water Treatment, 54, 1, (2015), 200-208 https://doi.org/10.1080/19443994.2014.880160
  31. Gatut Ari Wardani and Winda Trisna Wulandari, Studi Kinetika dan Isoterm Adsorpsi Timbal (II) pada Kulit Jengkol (Pithecellobium jiringa) Teraktivasi, KOVALEN: Jurnal Riset Kimia, 3, 3, (2017), 252-257
  32. Aris Wijayanti, Eko Budi Susatyo, Cepi Kurniawan and Sukarjo Sukarjo, Adsorpsi Logam Cr (VI) dan Cu (II) pada Tanah dan Pengaruh Penambahan Pupuk Organik, Indonesian Journal of Chemical Science, 7, 3, (2018), 242-248
  33. Nimibofa Ayawei, Seimokumo Samuel Angaye, Donbebe Wankasi and Ezekiel Dixon Dikio, Synthesis, characterization and application of Mg/Al layered double hydroxide for the degradation of congo red in aqueous solution, Open Journal of Physical Chemistry, 5, 3, (2015), 56-70 http://dx.doi.org/10.4236/ojpc.2015.53007
  34. G.G. Stanley, The Extractive Metallurgy of Gold in South Africa, South African Institute of Mining and Metallurgy, Johannesberg, 1987
  35. Gulnaziya Issabayeva, Mohamed Kheireddine Aroua and Nik Meriam Nik Sulaiman, Removal of lead from aqueous solutions on palm shell activated carbon, Bioresource technology, 97, 18, (2006), 2350-2355 https://doi.org/10.1016/j.biortech.2005.10.023
  36. Dewi Martina, Rum Hastuti and Didik Setiyo Widodo, Peran Adsorben Selulosa Tongkol Jagung (Zea mays) dengan Polivinil Alkohol (PVA) untuk Penyerapan Ion Logam Timbal (Pb2+), Jurnal Kimia Sains dan Aplikasi, 19, 3, (2016), 77-82 https://doi.org/10.14710/jksa.19.3.77-82

Last update:

  1. Adsorptive removal of boron from aqueous solutions using peels of jering seeds (Archidendron pauciflorum): isotherm, kinetic and thermodynamic studies

    Fawaz Al-Badaii, Riyadh Abdulmalek Hassan, Nurul ‘Ain Abdul Jalil, Azhar Abdul Halim. Desalination and Water Treatment, 312 , 2023. doi: 10.5004/dwt.2023.30074

Last update: 2024-11-13 21:30:26

No citation recorded.