DOI: https://doi.org/10.14710/jksa.25.9.322-328

Enhanced SOFC Cathode Performance Through Surface Modification of NdBa0.5Sr0.5Co2O5+δ Nanoparticles

Department of Mechanical Engineering, Institut Teknologi Nasional Yogyakarta, Daerah Istimewa Yogyakarta 55281, Indonesia

Received: 7 Aug 2022; Revised: 28 Nov 2022; Accepted: 29 Nov 2022; Available online: 23 Dec 2022; Published: 23 Dec 2022.
Open Access Copyright 2022 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

Citation Format:
Cover Image
Abstract

The cathode materials fabrication with outstanding performance and stability at intermediate temperatures of 600–800℃ is required for the prospective mass production of solid oxide fuel cells (SOFCs). Infiltration is a potential method because it has proven successful in fabrication and cell performance enhancement. This study mainly focuses on the electrical conductivity and long-term reliability of cathode symmetric cells NdBa0.5Sr0.5Co2O5+δ (NBSC) fabricated by traditional solid-state reaction techniques. The electrical conductivity value of the cathode is in the range of 174–278 S.cm-1. Impedance analysis showed that the infiltration of 0.5M SDC on the NBSC cathode surface dramatically reduced the polarization resistance (Rp) between layers (cathode-electrolyte) from 3.32 Ω.cm2 to 1.82 Ω.cm2 at 600℃ or decreased by 45 % compared to NBSC cathode without 0.5M SDC infiltration. The enhanced stability of NBSC cathode specimens with 0.5M SDC infiltration (NBSC+0.5 M SDC) under SOFC operating conditions proves that samples with infiltration extend their lifetime. Compared to the NBSC cathode, the NBSC+0.5 M SDC cathode has better long-term stability with a lower RP value of 2.35 Ω.cm2. In the OPP range of 0.214-0.0027 atm at 800℃, the relatively tiny Rp value of the symmetrical cell is between 0.030 Ω.cm2 and 0.039 Ω.cm2, below the 0.15 Ω.cm2 suitable performance limit for solid oxide fuel cells.

Fulltext View|Download
Keywords: SOFC; Cathode; Electrical conductivity; Infiltration; Long-term performance stability

Article Metrics:

Article Info
Section: Research Articles
Language : EN
Recent articles
Synthesis of Cardanol-Based Acetaldehyde Novolac Resin from Cashew Nut Shell Liquid (CNSL) Enhanced SOFC Cathode Performance Through Surface Modification of NdBa0.5Sr0.5Co2O5+δ Nanoparticles Preparation of Biosorbent from Kapok Fruit Peel (Ceiba pentandra) for Adsorption of Lead Waste More recent articles
Most cited articles
Pengaruh Pemerangkapan Enzim Alkalin Fosfatase ke dalam Silika dari Abu Sekam Padi terhadap Aktivitas Enzimatiknya Dimerisasi Metilisoeugenol dengan Katalis HCl Isolasi Bakteri Endofit pada Rimpang Jahe Merah (Zingiber officinale Linn. Var Rubrum) Penghasil Senyawa Antioksidan Hidrorengkah Fraksi Berat Minyak Bumi Menggunakan Katalis Lempung Terpilar Aluminium Berpengemban Nikel Synthesis of Nano Chitosan as Carrier Material of Cinnamon’s Active Component More cited articles
  1. Caineng Zou, Qun Zhao, Guosheng Zhang, Bo Xiong, Energy revolution: From a fossil energy era to a new energy era, Natural Gas Industry B, 3, 1, (2016), 1-11 https://doi.org/10.1016/j.ngib.2016.02.001
  2. Jung-Ho Wee, Contribution of fuel cell systems to CO2 emission reduction in their application fields, Renewable and Sustainable Energy Reviews, 14, 2, (2010), 735-744 https://doi.org/10.1016/j.rser.2009.10.013
  3. Kazui Yoshida, Hom B. Rijal, Kazuaki Bohgaki, Ayako Mikami, Hiroto Abe, Energy-saving and CO2-emissions-reduction potential of a fuel cell cogeneration system for condominiums based on a field survey, Energies, 14, 20, (2021), 6611 https://doi.org/10.3390/en14206611
  4. Huangang Shi, Chao Su, Ran Ran, Jiafeng Cao, Zongping Shao, Electrolyte materials for intermediate-temperature solid oxide fuel cells, Progress in Natural Science: Materials International, 30, 6, (2020), 764-774 https://doi.org/10.1016/j.pnsc.2020.09.003
  5. Beom-Kyeong Park, Scott A. Barnett, Boosting solid oxide fuel cell performance via electrolyte thickness reduction and cathode infiltration, Journal of Materials Chemistry A, 8, 23, (2020), 11626-11631 https://doi.org/10.1039/D0TA04280C
  6. Michał Mosiałek, Małgorzata Zimowska, Dzmitry Kharytonau, Anna Komenda, Miłosz Górski, Marcel Krzan, Improvement of La0.8Sr0.2MnO3−δ Cathode Material for Solid Oxide Fuel Cells by Addition of YFe0.5Co0.5O3, Materials, 15, 642, (2022), 1-14 https://doi.org/10.3390/ma15020642
  7. Jun Ho Kim, Jeong Woo Yun, Sulfur Tolerance Effects on Sr0.92Y0.08Ti0.5Fe0.5O3-δ as an Alternative Anode in Solid Oxide Fuel Cells, Journal of Electrochemical Science and Technology, 9, 2, (2018), 133-140 https://doi.org/10.5229/JECST.2018.9.2.133
  8. Andrei I. Klyndyuk, Ekaterina A. Chizhova, Dzmitry S. Kharytonau, Dmitry A. Medvedev, Layered oxygen-deficient double perovskites as promising cathode materials for solid oxide fuel cells, Materials, 15, 1, (2021), 141 https://doi.org/10.3390/ma15010141
  9. Renato Pelosato, Giulio Cordaro, Davide Stucchi, Cinzia Cristiani, Giovanni Dotelli, Cobalt based layered perovskites as cathode material for intermediate temperature Solid Oxide Fuel Cells: A brief review, Journal of Power Sources, 298, (2015), 46-67 https://doi.org/10.1016/j.jpowsour.2015.08.034
  10. Wei Xia, Xianglin Liu, Fangjun Jin, Xuelin Jia, Yu Shen, Jinhua Li, Evaluation of calcium codoping in double perovskite PrBaCo2O5+δ as cathode material for IT-SOFCs, Electrochimica Acta, 364, 137274, (2020), 1-11 https://doi.org/10.1016/j.electacta.2020.137274
  11. Quan Yang, Dong Tian, Rui Liu, Haodong Wu, Yonghong Chen, Yanzhi Ding, Xiaoyong Lu, Bin Lin, Exploiting rare-earth-abundant layered perovskite cathodes of LnBa0.5Sr0.5Co1.5Fe0.5O5+δ (Ln= La and Nd) for SOFCs, International Journal of Hydrogen Energy, 46, 7, (2021), 5630-5641 https://doi.org/10.1016/j.ijhydene.2020.11.031
  12. Hailei Zhao, Yu Zheng, Chunyang Yang, Yongna Shen, Zhihong Du, Konrad Świerczek, Electrochemical performance of Pr1−xYxBaCo2O5+δ layered perovskites as cathode materials for intermediate-temperature solid oxide fuel cells, International Journal of Hydrogen Energy, 38, 36, (2013), 16365-16372 https://doi.org/10.1016/j.ijhydene.2013.10.003
  13. Li-Na Xia, Zhi-Ping He, X. W. Huang, Yan Yu, Synthesis and properties of SmBaCo2−xNixO5+δ perovskite oxide for IT-SOFC cathodes, Ceramics International, 42, 1, (2016), 1272-1280 https://doi.org/10.1016/j.ceramint.2015.09.062
  14. Xiubing Huang, Jie Feng, Hassan R. S. Abdellatif, Jing Zou, Guan Zhang, Chengsheng Ni, Electrochemical evaluation of double perovskite PrBaCo2-xMnxO5+δ (x= 0, 0.5, 1) as promising cathodes for IT-SOFCs, International Journal of Hydrogen Energy, 43, 18, (2018), 8962-8971 https://doi.org/10.1016/j.ijhydene.2018.03.163
  15. Matthew West, Arumugam Manthiram, Layered LnBa1−xSrxCoCuO5+δ (Ln= Nd and Gd) perovskite cathodes for intermediate temperature solid oxide fuel cells, International Journal of Hydrogen Energy, 38, 8, (2013), 3364-3372 https://doi.org/10.1016/j.ijhydene.2012.12.133
  16. Sangwook Joo, Junyoung Kim, Jeeyoung Shin, Tak-Hyoung Lim, Guntae Kim, Investigation of a layered perovskite for IT-SOFC cathodes: B-site Fe-doped YBa0.5Sr0.5Co2-xFexO5+δ, Journal of The Electrochemical Society, 163, 14, (2016), F1489-F1495 https://doi.org/10.1149/2.0371614jes
  17. Adi Subardi, Ching-Cheng Chen, Meng-Hsien Cheng, Wen-Ku Chang, Yen-Pei Fu, Electrical, thermal and electrochemical properties of SmBa1−xSrxCo2O5+δ cathode materials for intermediate-temperature solid oxide fuel cells, Electrochimica Acta, 204, (2016), 118-127 https://doi.org/10.1016/j.electacta.2016.04.069
  18. Chihiro Kuroda, Kun Zheng, Konrad Świerczek, Characterization of novel GdBa0.5Sr0.5Co2−xFexO5+δ perovskites for application in IT-SOFC cells, International Journal of Hydrogen Energy, 38, 2, (2013), 1027-1038 https://doi.org/10.1016/j.ijhydene.2012.10.085
  19. Fuchang Meng, Tian Xia, Jingping Wang, Zhan Shi, Jie Lian, Hui Zhao, Jean-Marc Bassat, Jean-Claude Grenier, Evaluation of layered perovskites YBa1−xSrxCo2O5+δ as cathodes for intermediate-temperature solid oxide fuel cells, International Journal of Hydrogen Energy, 39, 9, (2014), 4531-4543 https://doi.org/10.1016/j.ijhydene.2014.01.008
  20. Kun Zheng, Konrad Świerczek, Joanna Bratek, Alicja Klimkowicz, Cation-ordered perovskite-type anode and cathode materials for solid oxide fuel cells, Solid State Ionics, 262, (2014), 354-358 https://doi.org/10.1016/j.ssi.2013.11.009
  21. Rong-Tsu Wang, Horng-Yi Chang, Jung-Chang Wang, An Overview on the Novel Core-Shell Electrodes for Solid Oxide Fuel Cell (SOFC) Using Polymeric Methodology, Polymers, 13, 16, (2021), 2774 https://doi.org/10.3390/polym13162774
  22. Adi Subardi, Meng-Hsien Cheng, Yen-Pei Fu, Chemical bulk diffusion and electrochemical properties of SmBa0.6Sr0.4Co2O5+δ cathode for intermediate solid oxide fuel cells, International Journal of Hydrogen Energy, 39, 35, (2014), 20783-20790 https://doi.org/10.1016/j.ijhydene.2014.06.134
  23. Lifang Nie, Mingfei Liu, Yujun Zhang, Meilin Liu, La0.6Sr0.4Co0.2Fe0.8O3−δ cathodes infiltrated with samarium-doped cerium oxide for solid oxide fuel cells, Journal of Power Sources, 195, 15, (2010), 4704-4708 https://doi.org/10.1016/j.jpowsour.2010.02.049
  24. Adi Subardi, Yen-Pei Fu, Electrochemical and thermal properties of SmBa0.5Sr0.5Co2O5+δ cathode impregnated with Ce0.8Sm0.2O1.9 nanoparticles for intermediate-temperature solid oxide fuel cells, International Journal of Hydrogen Energy, 42, 38, (2017), 24338-24346 https://doi.org/10.1016/j.ijhydene.2017.08.010
  25. Jinhua Piao, Kening Sun, Naiqing Zhang, Xinbing Chen, Shen Xu, Derui Zhou, Preparation and characterization of Pr1−xSrxFeO3 cathode material for intermediate temperature solid oxide fuel cells, Journal of Power Sources, 172, 2, (2007), 633-640 https://doi.org/10.1016/j.jpowsour.2007.05.023
  26. Yen-Pei Fu, Jie Ouyang, Chien-Hung Li, Shao-Hua Hu, Chemical bulk diffusion coefficient of Sm0.5Sr0.5CoO3−δ cathode for solid oxide fuel cells, Journal of Power Sources, 240, (2013), 168-177 https://doi.org/10.1016/j.jpowsour.2013.03.138
  27. Shiquan Lü, Xiangwei Meng, Yuan Ji, Chengwei Fu, Cuicui Sun, Hongyuan Zhao, Electrochemical performances of NdBa0.5Sr0.5Co2O5+x as potential cathode material for intermediate-temperature solid oxide fuel cells, Journal of Power Sources, 195, 24, (2010), 8094-8096 https://doi.org/10.1016/j.jpowsour.2010.06.061
  28. Abhishek Jaiswal, Eric D. Wachsman, Bismuth-ruthenate-based cathodes for IT-SOFCs, Journal of the Electrochemical Society, 152, 4, (2005), A787-A790 https://doi.org/10.1149/1.1866093
  29. Jiyoun Kim, Won-yong Seo, Jeeyoung Shin, Meilin Liu, Guntae Kim, Composite cathodes composed of NdBa0.5Sr0.5Co2O5+δ and Ce0.9Gd0.1O1.95 for intermediate-temperature solid oxide fuel cells, Journal of Materials Chemistry A, 1, 3, (2013), 515-519 https://doi.org/10.1039/C2TA00025C
  30. Arumugam Manthiram, Jung-Hyun Kim, Young Nam Kim, Ki-Tae Lee, Crystal chemistry and properties of mixed ionic-electronic conductors, Journal of Electroceramics, 27, 2, (2011), 93-107 https://doi.org/10.1007/s10832-011-9635-x
  31. Abdullah Abdul Samat, Abdul Azim Jais, Mahendra Rao Somalu, Nafisah Osman, Andanastuti Muchtar, Kean Long Lim, Electrical and electrochemical characteristics of La0.6Sr0.4CoO3-δ cathode materials synthesized by a modified citrate-EDTA sol-gel method assisted with activated carbon for proton-conducting solid oxide fuel cell application, Journal of Sol-Gel Science and Technology, 86, 3, (2018), 617-630 https://doi.org/10.1007/s10971-018-4675-1
  32. Adi Subardi, Kun-Yu Liao, Yen-Pei Fu, Oxygen transport, thermal and electrochemical properties of NdBa0.5Sr0.5Co2O5+δ cathode for SOFCs, Journal of the European Ceramic Society, 39, 1, (2019), 30-40 https://doi.org/10.1016/j.jeurceramsoc.2018.01.022
  33. Yinkai Lei, Tian-Le Cheng, You-Hai Wen, Phase field modeling of microstructure evolution and concomitant effective conductivity change in solid oxide fuel cell electrodes, Journal of Power Sources, 345, (2017), 275-289 https://doi.org/10.1016/j.jpowsour.2017.02.007
  34. Atef Zekri, Martin Knipper, Jürgen Parisi, Thorsten Plaggenborg, Microstructure degradation of Ni/CGO anodes for solid oxide fuel cells after long operation time using 3D reconstructions by FIB tomography, Physical Chemistry Chemical Physics, 19, 21, (2017), 13767-13777 https://doi.org/10.1039/C7CP02186K
  35. Adi Subardi, Kun-Yu Liao, Yen-Pei Fu, Oxygen permeation, thermal expansion behavior and electrochemical properties of LaBa0.5Sr0.5Co2O5+δ cathode for SOFCs, RSC Advances, 7, 24, (2017), 14487-14495 https://doi.org/10.1039/C7RA00125H

Last update:

No citation recorded.

Last update: 2024-11-03 17:56:03

No citation recorded.