DOI: https://doi.org/10.14710/jksa.26.1.19-27

Fabrication of Polystyrene Sulfonate-Chitosan (PSS-Chitosan) Membrane as Dodecyl Benzene Sulfonate (DBS) Adsorbent in Laundry Wastewater

1Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Yogyakarta 55281, Indonesia

2Department of Biology Faculty of Biology, Universitas Gadjah Mada, Yogyakarta 55281, Indonesia

Received: 25 Sep 2022; Revised: 13 Nov 2022; Accepted: 20 Jan 2023; Published: 31 Jan 2023.
Open Access Copyright 2023 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

Citation Format:
Cover Image
Abstract
The combination of polystyrene and chitosan can form polyelectrolyte (PE) membranes. Polystyrene sulfonate-chitosan (PSS-chitosan) adsorbent membrane can adsorb dodecyl benzene sulfonate (DBS) in laundry wastewater. This study aimed to synthesize, identify characteristics, and formulate adsorption effectiveness by PSS-chitosan membranes. The research methods included converting polystyrene into PSS, isolating chitosan, optimizing geometry, making PSS-chitosan membranes, studying adsorption, and applying membranes to laundry wastewater. The resulting membrane was characterized using FTIR and SEM. The results of the infrared spectra showed vibrations of –OH and –NH2 groups at 3418 cm–1, while the SEM image showed a homogeneous membrane surface. The quality of chitosan isolation from shrimp shells was indicated by the degree of deacetylation of 61.3%. The results of the geometry optimization showed the change in the structure’s total energy after adsorption. The PSS-chitosan membrane is resistant to acids but decomposes under alkaline conditions. Optimum adsorption of PSS-chitosan membrane on DBS occurred at pH 8 for 100 minutes. The adsorption kinetics of the PSS-chitosan membrane follows the first pseudo-order equation. PSS-chitosan membrane adsorption isotherm follows the Langmuir isotherm model with an adsorption capacity and efficiency of 3.97 mg.g–1 and 76.6%, respectively, at 0.6 ppm. At the application stage, the PSS-chitosan membrane could adsorb DBS in laundry wastewater by (62.4 ± 7.2) %.
Fulltext View|Download
Keywords: DBS; chitosan; laundry wastewater; PSS-chitosan membrane; styrofoam
Funding: Universitas Gadjah Mada

Article Metrics:

Article Info
Section: Research Articles
Language : EN
Recent articles
Antioxidant, Cytotoxic, and Insulinotropic Activities of Several Leaves Extracts of Medicinal Plants Synthesis of Zinc Oxide (ZnO) Nanoparticles Using Microwave Assistance and Its Application as Photocatalyst in Degrading Methylene Blue Fabrication of Polystyrene Sulfonate-Chitosan (PSS-Chitosan) Membrane as Dodecyl Benzene Sulfonate (DBS) Adsorbent in Laundry Wastewater More recent articles
Most cited articles
Pengolahan Limbah Cair Industri Batik dengan Metoda Elektrokoagulasi Menggunakan Besi Bekas Sebagai Elektroda Aktivitas Antioksidan dan Antibakteri Produk Fermentasi Susu Kedelai dan Whey Tahu menggunakan Bakteri Asam Laktat Komersial Removal of natural organic matter for wetland saline water desalination by coagulation-pervaporation Pengaruh Perlakuan Asam dan Kalium Permanganat terhadap Karakter Zeolit Tasik Pemanfaatan Montmorillonit Terpilar Al-Cr pada Adsorpsi Zat Warna Rhodamin B dengan Variasi Massa Adsorben dan Waktu Adsorpsi More cited articles
  1. HDIN Research, Polystyrene Market Global Review and Outlook, 2019
  2. Muhammad Reza Cordova, Intan Suci Nurhati, Major sources and monthly variations in the release of land-derived marine debris from the Greater Jakarta area, Indonesia, Scientific Reports, 9, 18730, (2019), 18730 https://doi.org/10.1038/s41598-019-55065-2
  3. Bayu Pamungkas, Rahmat Kurnia, Etty Riani, Potential Plastic Waste Input from Citarum River, Indonesia, Aquaculture, Aquarium, Conservation & Legislation Bioflux, 14, 1, (2021), 103-110
  4. Joseph A. Davis, Styrofoam Facts — Why You May Want To Bring Your Own Cup, 2019
  5. Elanda Fikri, Aprilia Veronica, Efektivitas Penurunan Konsentrasi Karbon Monoksida (CO) dengan Sistem Kontak Media Karbon Aktif Menggunakan Variasi Ukuran Partikel Pada Proses Pembakaran Sampah Polistirena Foam, Jurnal Kesehatan Lingkungan Indonesia, 17, 1, (2018), 32-38 http://dx.doi.org/10.14710/jkli.17.1.32-38
  6. Ali N. Siyal, Saima Q. Memon, Latif Elçi, Aydan Elçi, Extraction of Polystyrene from Styrofoam Waste: Synthesis of Novel Chelating Resin for the Enrichment and Speciation of Cr (III)/Cr (VI) Ions in Industrial Effluents, International Journal of Environmental and Ecological Engineering, 8, 3, (2014), 212-215
  7. Mohamed E. Mahmoud, Azza E. H. Abdou, Somia B. Ahmed, Conversion of waste styrofoam into engineered adsorbents for efficient removal of cadmium, lead and mercury from water, ACS Sustainable Chemistry & Engineering, 4, 3, (2016), 819-827 https://doi.org/10.1021/acssuschemeng.5b01149
  8. Nurillahi Febria Leswana, Dwi Siswanta, Adhitasari Suratman, Sintesis Membran Polielektrolit Komplek Polistirena Sulfonat-Kitosan dari Limbah Styrofoam Sebagai Adsorben Logam Cu(II) dan Ni(II), Jurnal Farmasi Etam, 1, 1, (2021), 10-25
  9. Shu-Hui Liu, Chun-Cheng Lu, Chi-Wen Lin, Shih-Hsien Chang, Rapid modification of waste expanded polystyrene with H2SO4/trace persulfate in one pot for effective adsorption of fluoroquinolone antibiotic and its regeneration, Chemosphere, 271, 129529, (2021), https://doi.org/10.1016/j.chemosphere.2020.129529
  10. Ministry of Maritime Affairs and Fisheries, Produksi Perikanan, 2020
  11. Beni Setha, Fitriani Rumata, Characteristics of Chitosan from White Leg Shrimp Shells Extracted Using Different Temperature and Time of the Deasetilation Process, Jurnal Pengolahan Hasil Perikanan Indonesia, 22, 3, (2019), 498-507 https://doi.org/10.17844/jphpi.v22i3.29317
  12. Rikha Yolanda, Pembuatan Kompleks Polielektrolit Polistirena Sulfonat-Kitosan dari Limbah Styrofoam sebagai Adsorben Zat Warna Biru Metilen dan Hijau Malakhit, Master Thesis, Magister Kimia, Universitas Gadjah Mada, Yogyakarta, 2018
  13. R. D. A. Opier, D. Siswanta, Synthesis of polyelectrolyte complex (PEC) membrane chitosan-polystyrene sulfonate (PSS) from styrofoam waste as adsorbents of Cd (II) and Pb (II) ions, IOP Conference Series: Earth and Environmental Science, 2020 https://doi.org/10.1088/1755-1315/483/1/012028
  14. Setijo Bismo, Pengolahan Air yang Mengandung Linear Alkyl Benzene Sulfonate (LAS) dan Amonia dengan Kombinasi Proses Ozonasi Gelembung Mikro dan Filtrasi Membran, Jurnal Purifikasi, 12, 2, (2011), 9-20
  15. Yusmidiarti Yusmidiarti, Analisis Pengelolaan Limbah Cair Usaha Laundry, Jurnal Media Kesehatan, 9, 1, (2016), 30-34
  16. Hendra Hendra, Eri Barlian, Abdul Razak, Hary Sanjaya, Photo-degradation of surfactant compounds using UV rays with addition of TiO2 catalysts in laundry waste, Sainstek: Jurnal Sains dan Teknologi, 7, 1, (2016), 59-68 http://dx.doi.org/10.31958/js.v7i1.126
  17. Aldila Maretta, Qomarudin Helmy, Degradasi Surfaktan Sodium Lauryl Sulfat dengan Proses Fotokatalisis Menggunakan Nano Partikel ZnO, Jurnal Teknik Lingkungan, 21, 1, (2015), 1-8 https://doi.org/10.5614/jtl.2015.21.1.1
  18. Julie Wolanin, Loïc Barré, Christine Dalmazzone, Daniela Bauer, Investigation of the adsorption of a mixture of two anionic surfactants, AOT and SDBS, on silica at ambient temperature, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 613, 126098, (2021), https://doi.org/10.1016/j.colsurfa.2020.126098
  19. Rayane R. B. Corona, Cristina M. S. Sad, Mayara da Silva, Diulliany L. Lopes, Juliéte S. D. Leite, Glória M. de F. Viegas, Gustavo R. Gonçalves, Paulo R. Filgueiras, Eustáquio V. R. de Castro, Adsorption of anionic surfactant in graphite oxide: A study for treatment of laundry wastewater, Journal of Environmental Chemical Engineering, 9, 6, (2021), 106858 https://doi.org/10.1016/j.jece.2021.106858
  20. Marco Masulli, Zi-Long Liu, Feng-Zhi Guo, Xue Li, Ernst J. R. Sudhölter, Naveen Kumar, Temperature effect on the dynamic adsorption of anionic surfactants and alkalis to silica surfaces, Petroleum Science, 19, 4, (2022), 1866-1876 https://doi.org/10.1016/j.petsci.2021.11.008
  21. Achmad Syarifudin Anwar, Analisis Sifat Mekanik Komposit Rami Epoxy dengan Penambahan Silikon Karbida (SiC) sebagai Bahan Plate Rompi Anti Peluru, Bachelor of Physics, Universitas Islam Negeri Maulana Malik Ibrahim, Malang, 2022
  22. Sry Agustina, I Made Dira Swantara, I Nyoman Suartha, Isolasi kitin, karakterisasi, dan sintesis kitosan dari kulit udang, Jurnal Kimia, 9, 2, (2015), 271-278 https://doi.org/10.24843/JCHEM.2015.v09.i02.p19
  23. Dian Harjuna Sukma, Etty Riani, Edward Nixon Pakpahan, Pemanfaatan Kitosan sebagai Adsorben Sianida pada Limbah Pengolahan Bijih Emas, Jurnal Pengolahan dan Hasil Perikanan Indonesia, 21, 3, (2018), 460-470
  24. Ahmed A. Moosa, Ali Mousa Ridha, Noor Ali Kadhim, Use of Biocomposite Adsorbents for the Removal of Methylene Blue Dye from Aqueous Solution, American Journal of Materials Science, 6, 5, (2016), 135-146
  25. Hamza El Fargani, Rajae Lakhmiri, Nezha Ait Oukharaz, Abdallah Albourine, Mohamed Safi, Omar Cherkaoui, Removal of Reactive Yellow 135 from Wastewaterof Textile Industry onto Chitosan Extracted by Hydrothermo-Chemical Method, Chemistry and Materials Research, 9, 10, (2017), 21-29
  26. Emil Salim, Afrizal Afrizal, Zilfadli Zilfadli, Synthesis of Polystyrene Sulfonate and Its Characterization as a Polymer Electrolyte Membrane, Akta Kimia Indonesia, 6, 1, (2021), 153-161 http://dx.doi.org/10.12962/j25493736.v6i2.10916
  27. Indri Hermiyati, Swatika Juhana, Synthesis of chitosan from the scales of starry trigger fish (Abalistes Stelaris), Oriental Journal of Chemistry, 35, 1, (2019), 377-383 http://dx.doi.org/10.13005/ojc/350147
  28. Robby Gus Mahardika, Muhammad Jumnahdi, Yekti Widyaningrum, Deasetilasi Kitin Cangkang Rajungan (Portunus pelagicus) Menjadi Kitosan Menggunakan Iradiasi Microwave, Al-Kimia, 8, 2, (2020), 149-158
  29. I. G. Wenten, K. Khoiruddin, A. N. Hakim, P. T. P. Aryanti, Teori perpindahan dalam membran, Teknik Kimia, Institut Teknologi Bandung, Bandung, 2012
  30. Kun Ma, Peixun Li, Zi Wang, Yao Chen, Mario Campana, James Doutch, Robert Dalgliesh, Armando Maestro, Robert K. Thomas, Jeff Penfold, Strong synergistic interactions in zwitterionic–anionic surfactant mixtures at the air–water interface and in micelles: The role of steric and electrostatic interactions, Journal of Colloid and Interface Science, 613, (2022), 297-310 https://doi.org/10.1016/j.jcis.2022.01.045
  31. Kuntari Kuntari, Nurul Hidayat Aprilita, Suherman Suherman, Utilization of Coal Bottom Ash a Low-Cost Adsorbent for the Removal Acid Red 114 Dye, EKSAKTA: Journal of Sciences and Data Analysis, 17, 1, (2017), 11-19 https://doi.org/10.20885/eksakta.vol17.iss1.art2
  32. Andrio Suhadi, Rizarullah Rizarullah, Feriyani Feriyani, Simulasi docking senyawa aktif daun binahong sebagai inhibitor enzyme aldose reductase, SEL Jurnal Penelitian Kesehatan, 6, 2, (2019), 55-65 https://doi.org/10.22435/sel.v6i2.1651
  33. Suhas Gotla, Christopher Tong, Silvina Matysiak, Load-Bearing Nanostructures in Composites of Chitosan with Anionic Surfactants: Implications for Programmable Mechanomaterials, ACS Applied Nano Materials, 5, 5, (2022), 6463-6473 https://doi.org/10.1021/acsanm.2c00560
  34. Rika Wulandari, Dwi Siswanta, Adsorption of sodium dodecylbenzene sulfonate (DBS) by C-3, 4-di-methoxyphenylcalix [4resorcinarene triphenylphosphonium chloride, Jurnal Riset Teknologi Pencegahan Pencemaran Industri, 9, 1, (2018), 1-8 https://doi.org/10.21771/jrtppi.2018.v9.no1.p1-8
  35. Westriani Prambaningrum, Khabibi Khabibi, Muhammad Cholid Djunaidi, Adsorpsi Ion Besi (III) dan Kadmium (II) Menggunakan Gel Kitosan, Jurnal Kimia Sains dan Aplikasi, 12, 2, (2009), 47-51 https://doi.org/10.14710/jksa.12.2.47-51

Last update:

  1. Polystyrene Sulfonate-Chitosan Membrane from Styrofoam Waste as The Adsorbent for Fe (III) Metals from Ex-Tin Mining

    Faizah Alivia Putri, Widia Widia, Addela Amelia, Robby Gus Mahardika. Jurnal Kimia Sains dan Aplikasi, 26 (11), 2023. doi: 10.14710/jksa.26.11.445-450

Last update: 2024-11-20 10:57:49

No citation recorded.