DOI: https://doi.org/10.14710/jksa.26.7.249-260

Corrosion Inhibition Behavior of DL-Methionine and L-Tryptophan on Carbon Steel

Research Division of Inorganic and Physical Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Bandung, Indonesia

Received: 11 May 2023; Revised: 6 Oct 2023; Accepted: 9 Oct 2023; Published: 5 Nov 2023.
Open Access Copyright 2023 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

Citation Format:
Cover Image
Abstract
The cost-effective, efficient, and environmentally friendly corrosion inhibitors have become increasingly significant within the oil and gas sector. Consequently, this research was conducted to evaluate the corrosion inhibition behavior of the amino acids DL-Met and L-Tryp on carbon steel in acidic (0.05 M HCl), alkaline (0.05 M NH4OH), and neutral (3% NaCl) environments. This study used Electrochemical Impedance Spectroscopy (EIS) and Potentiodynamic Polarization (PDP) to assess the performance of amino acids as corrosion inhibitors. The EIS and PDP measurements revealed that DL-Met and L-Tryp exhibited corrosion inhibition effects exclusively in acidic conditions. In this environment, DL-Met demonstrated a corrosion inhibition efficiency (η) of 49.7% at a concentration of 525 ppm, while L-Tryp reached an efficiency of 87.08% at a concentration of 25 ppm. Under the same conditions, DL-Met reduced the corrosion rate from 10 mm/year to 4.468 mm/year, and L-Tryp reduced it from 10.95 mm/year to 5.003 mm/year. However, the corrosion inhibition activity of DL-Met and L-Tryp in neutral and alkaline conditions did not yield positive results according to EIS measurements. In neutral conditions, 100 ppm DL-Met exhibited -22.46% inhibitory activity. Meanwhile, in alkaline conditions, 150 ppm DL-Met and 5 ppm L-Tryp exhibited inhibition efficiencies of -72.39% and -81.9%, respectively. This research aims to provide the oil and gas industry with a natural-based corrosion inhibitor alternative, offering a solution to corrosion-related challenges in acidic conditions.
Fulltext View|Download
Keywords: Corrosion; bio-inhibitors; Amino Acids; DL-Methionine; L-Tryptophan

Article Metrics:

Article Info
Section: Research Articles
Language : EN
Recent articles
Synthesis and Computational Study of Bis-(1-(3-Chlorobenzoyl)-3-Phenylthiourea) Cobalt (III) as Anticancer Candidate Corrosion Inhibition Behavior of DL-Methionine and L-Tryptophan on Carbon Steel The Effect of Various Sterilization Methods and Volume Containers on Phytochemical Content of Methanol Extract of Phyllanthus urinaria More recent articles
Most cited articles
Analisis Pangan: Penentuan Angka Peroksida dan Asam Lemak Bebas pada Minyak Kedelai dengan Variasi Menggoreng Sintesis Zeolit A dan Kemungkinan Penggunaannya Sebagai Penukar Kation Pengaruh Keasaman Medium dan Imobilisasi Gugus Organik pada Karakter Silika Gel dari Abu Sekam Padi Aktivitas Antioksidan dan Antibakteri Produk Fermentasi Susu Kedelai dan Whey Tahu menggunakan Bakteri Asam Laktat Komersial Sintesis Metilisoeugenol dari Metileugenol Menggunakan Katalis KOH dalam Etanol More cited articles
  1. Sri Handani, Megi Septia Elta, Pengaruh inhibitor ekstrak daun pepaya terhadap korosi baja karbon schedule 40 grade B ERW dalam medium air laut dan air tawar, Jurnal Riset Kimia, 5, 2, (2012), 175-175 https://doi.org/10.25077/jrk.v5i2.219
  2. Hala A. El Nagy, ElSayed H. El Tamany, Hana Ashour, Olfat E. El-Azabawy, Elsayed G. Zaki, Shimaa M. Elsaeed, Polymeric Ionic Liquids Based on Benzimidazole Derivatives as Corrosion Inhibitors for X-65 Carbon Steel Deterioration in Acidic Aqueous Medium: Hydrogen Evolution and Adsorption Studies, ACS Omega, 5, 47, (2020), 30577-30586 https://doi.org/10.1021/acsomega.0c04505
  3. Li Feng, Shengtao Zhang, Yujie Qiang, Shenying Xu, Bochuan Tan, Shijin Chen, The synergistic corrosion inhibition study of different chain lengths ionic liquids as green inhibitors for X70 steel in acidic medium, Materials Chemistry and Physics, 215, (2018), 229-241 https://doi.org/10.1016/j.matchemphys.2018.04.054
  4. Ebrahim Kamali Ardakani, Elaheh Kowsari, Ali Ehsani, Seeram Ramakrishna, Performance of all ionic liquids as the eco-friendly and sustainable compounds in inhibiting corrosion in various media: A comprehensive review, Microchemical Journal, 165, (2021), 106049 https://doi.org/10.1016/j.microc.2021.106049
  5. Vishal Varshney, Abhishek Verma, Vishnu Kumar, Tej Pratap Singh, A review paper on green corrosion and its inhibitors, International Journal of Materials Science, 4, 1, (2023), 27-31
  6. Megawati Zunita, Deana Wahyuningrum, I. Gede Wenten, Raj Boopathy, Carbon steel corrosion inhibition activity of tofu associated proteins, Bioresource Technology Reports, 17, (2022), 100973 https://doi.org/10.1016/j.biteb.2022.100973
  7. M. A. Deyab, Sulfonium-based ionic liquid as an anticorrosive agent for thermal desalination units, Journal of Molecular Liquids, 296, (2019), 111742 https://doi.org/10.1016/j.molliq.2019.111742
  8. Abhinay Thakur, Ashish Kumar, Shveta Sharma, Richika Ganjoo, Humira Assad, Computational and experimental studies on the efficiency of Sonchus arvensis as green corrosion inhibitor for mild steel in 0.5 M HCl solution, Materials Today: Proceedings, 66, (2022), 609-621 https://doi.org/10.1016/j.matpr.2022.06.479
  9. Entian Li, Yingping Li, Songling Liu, Pei Yao, Choline amino acid ionic liquids as green corrosion inhibitors of mild steel in acidic medium, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 657, (2023), 130541 https://doi.org/10.1016/j.colsurfa.2022.130541
  10. Entian Li, Songling Liu, Fang Luo, Pei Yao, Amino acid imidazole ionic liquids as green corrosion inhibitors for mild steel in neutral media: Synthesis, electrochemistry, surface analysis and theoretical calculations, Journal of Electroanalytical Chemistry, 944, (2023), 117650 https://doi.org/10.1016/j.jelechem.2023.117650
  11. S. Kshama Shetty, A. Nityananda Shetty, Eco-friendly benzimidazolium based ionic liquid as a corrosion inhibitor for aluminum alloy composite in acidic media, Journal of Molecular Liquids, 225, (2017), 426-438 https://doi.org/10.1016/j.molliq.2016.11.037
  12. F. El-Hajjaji, E. Ech-Chihbi, N. Rezki, F. Benhiba, M. Taleb, Dheeraj Singh Chauhan, M. A. Quraishi, Electrochemical and theoretical insights on the adsorption and corrosion inhibition of novel pyridinium-derived ionic liquids for mild steel in 1 M HCl, Journal of Molecular Liquids, 314, (2020), 113737 https://doi.org/10.1016/j.molliq.2020.113737
  13. Xihua Xu, Ambrish Singh, Zhipeng Sun, K. R. Ansari, Yuanhua Lin, Theoretical, thermodynamic and electrochemical analysis of biotin drug as an impending corrosion inhibitor for mild steel in 15% hydrochloric acid, Royal Society Open Science, 4, 12, (2017), 170933 https://doi.org/10.1098/rsos.170933
  14. Megawati Zunita, Yosef Juliyus Kevin, Ionic liquids as corrosion inhibitor: From research and development to commercialization, Results in Engineering, 15, (2022), 100562 https://doi.org/10.1016/j.rineng.2022.100562
  15. Muhammad Wasim, Milos B. Djukic, External corrosion of oil and gas pipelines: A review of failure mechanisms and predictive preventions, Journal of Natural Gas Science and Engineering, 100, (2022), 104467 https://doi.org/10.1016/j.jngse.2022.104467
  16. Tamires Cristina Costa, Letiane Thomas Hendges, Bruna Temochko, Luciana Prazeres Mazur, Belisa Alcantara Marinho, Silvio Edegar Weschenfelder, Priscilla Lopes Florido, Adriano da Silva, Antônio Augusto Ulson de Souza, Selene M. A. Guelli Ulson de Souza, Evaluation of the technical and environmental feasibility of adsorption process to remove water soluble organics from produced water: A review, Journal of Petroleum Science and Engineering, 208, (2022), 109360 https://doi.org/10.1016/j.petrol.2021.109360
  17. B. El Ibrahimi, A. Jmiai, L. Bazzi, S. El Issami, Amino acids and their derivatives as corrosion inhibitors for metals and alloys, Arabian Journal of Chemistry, 13, 1, (2020), 740-771 https://doi.org/10.1016/j.arabjc.2017.07.013
  18. H. Ashassi-Sorkhabi, Z. Ghasemi, D. Seifzadeh, The inhibition effect of some amino acids towards the corrosion of aluminum in 1M HCl+1M H2SO4 solution, Applied Surface Science, 249, 1, (2005), 408-418 https://doi.org/10.1016/j.apsusc.2004.12.016
  19. Abdullah Hasan Jabbar, Suhair Mohammad Husein Kamona, Sarah Kamil Abbood, Talib Kh Hussein, Dahlia N. Al-Saidi, Safaa Mustafa Hameed, Rashid Abdul Kareem Rashid, Hussein Abdullah Abbas, Mustafa M. Kadhim, The effective and sustainable application of a green amino acid-based corrosion Inhibitor for Cu metal, Chemical Physics Impact, 7, (2023), 100316 https://doi.org/10.1016/j.chphi.2023.100316
  20. Sadegh Pour-Ali, Reza Tavangar, Seyedsina Hejazi, Comprehensive assessment of some L-amino acids as eco-friendly corrosion inhibitors for mild steel in HCl: Insights from experimental and theoretical studies, Journal of Physics and Chemistry of Solids, 181, (2023), 111550 https://doi.org/10.1016/j.jpcs.2023.111550
  21. Q. H. Zhang, N. Xu, Developing two amino acid derivatives as high-efficient corrosion inhibitors for carbon steel in the CO2-containing environment, Industrial Crops and Products, 201, (2023), 116883 https://doi.org/10.1016/j.indcrop.2023.116883
  22. Abhinay Thakur, Savas Kaya, A. S. Abousalem, Shveta Sharma, Richika Ganjoo, Humira Assad, Ashish Kumar, Computational and experimental studies on the corrosion inhibition performance of an aerial extract of Cnicus Benedictus weed on the acidic corrosion of mild steel, Process Safety and Environmental Protection, 161, (2022), 801-818 https://doi.org/10.1016/j.psep.2022.03.082
  23. Everton de Britto Policarpi, Almir Spinelli, Application of Hymenaea stigonocarpa fruit shell extract as eco-friendly corrosion inhibitor for steel in sulfuric acid, Journal of the Taiwan Institute of Chemical Engineers, 116, (2020), 215-222 https://doi.org/10.1016/j.jtice.2020.10.024
  24. B. Arifa Farzana, A. Mushira Banu, K. Riaz Ahamed, Andrographis echioides leaves extract as an eco-friendly corrosion inhibitor for mild steel in acid medium, Materials Today: Proceedings, 47, (2021), 2080-2090 https://doi.org/10.1016/j.matpr.2021.04.478
  25. Rajesh Haldhar, Dwarika Prasad, Indra Bahadur, Omar Dagdag, Avni Berisha, Evaluation of Gloriosa superba seeds extract as corrosion inhibition for low carbon steel in sulfuric acidic medium: A combined experimental and computational studies, Journal of Molecular Liquids, 323, (2021), 114958 https://doi.org/10.1016/j.molliq.2020.114958
  26. Q. H. Zhang, Y. Y. Li, Y. Lei, X. Wang, H. F. Liu, G. A. Zhang, Comparison of the synergistic inhibition mechanism of two eco-friendly amino acids combined corrosion inhibitors for carbon steel pipelines in oil and gas production, Applied Surface Science, 583, (2022), 152559 https://doi.org/10.1016/j.apsusc.2022.152559
  27. Jia-Jun Fu, Su-Ning Li, Lin-Hua Cao, Ying Wang, Lian-He Yan, Lu-De Lu, L-Tryptophan as green corrosion inhibitor for low carbon steel in hydrochloric acid solution, Journal of Materials Science, 45, (2010), 979-986 https://doi.org/10.1007/s10853-009-4028-0
  28. Jiaxin Luo, Xiong Cheng, Chaofa Zhong, Xinhua Chen, Y. W. Ye, H. Zhao, H. Chen, Effect of reaction parameters on the corrosion inhibition behavior of N-doped carbon dots for metal in 1 M HCl solution, Journal of Molecular Liquids, 338, (2021), 116783 https://doi.org/10.1016/j.molliq.2021.116783
  29. N. Wint, J. H. Sullivan, D. J. Penney, The Role of pH on the Inhibition of Aqueous Zinc Corrosion by L-tryptophan, Journal of The Electrochemical Society, 164, 7, (2017), C356 https://doi.org/10.1149/2.0981707jes
  30. Zhe Zhang, Ningchen Tian, Lingzhi Zhang, Ling Wu, Inhibition of the corrosion of carbon steel in HCl solution by methionine and its derivatives, Corrosion Science, 98, (2015), 438-449 https://doi.org/10.1016/j.corsci.2015.05.048
  31. Güray Kilinççeker, Hasan Demir, The inhibition effects of methionine on corrosion behavior of copper in 3.5% NaCl solution at pH = 8.5, Protection of Metals and Physical Chemistry of Surfaces, 49, (2013), 788-797 https://doi.org/10.1134/S2070205113060221
  32. Dong-Ying Li, Yi-Chin Cho, Ming Huang Hsu, Yi-Pin Lin, Recovery of phosphate and ammonia from wastewater via struvite precipitation using spent refractory brick gravel from steel industry, Journal of Environmental Management, 302, (2022), 114110 https://doi.org/10.1016/j.jenvman.2021.114110
  33. L. P. Gossen, L. M. Velichkina, Environmental problems of the oil-and-gas industry (Review), Petroleum Chemistry, 46, (2006), 67-72 https://doi.org/10.1134/S0965544106020010
  34. Uwe Reimer, Yun Cai, Ruiyu Li, Dieter Froning, Werner Lehnert, Time Dependence of the Open Circuit Potential of Platinum Disk Electrodes in Half Cell Experiments, Journal of The Electrochemical Society, 166, 7, (2019), F3098 https://doi.org/10.1149/2.0121907jes
  35. Mohammed Aider, Djamel Djenane, Wassef B. Ounis, Amino acid composition, foaming, emulsifying properties and surface hydrophobicity of mustard protein isolate as affected by pH and NaCl, International Journal of Food Science & Technology, 47, 5, (2012), 1028-1036 https://doi.org/10.1111/j.1365-2621.2012.02937.x
  36. Hamad M. Adress Hasan, Ibrahim H. Habib, Ahlam M. Ali, Spectrophotometric Determination of The Ionization Constants of Methionine, Cystine and Cysteine, European Chemical Bulletin, 6, 8, (2017), 355-358
  37. Patrick S. Germain, Wendy G. Pell, Brian E. Conway, Evaluation and origins of the difference between double-layer capacitance behaviour at Au-metal and oxidized Au surfaces, Electrochimica Acta, 49, 11, (2004), 1775-1788 https://doi.org/10.1016/j.electacta.2003.12.009
  38. A. Kadhim, A. A. Al-Amiery, R. Alazawi, M. K. S. Al-Ghezi, R. H. Abass, Corrosion inhibitors. A review, International Journal of Corrosion and Scale Inhibition, 10, 1, (2021), 54-67 http://dx.doi.org/10.17675/2305-6894-2021-10-1-3
  39. F. El-Hajjaji, E. Ech-chihbi, N. Rezki, F. Benhiba, M. Taleb, Dheeraj Singh Chauhan, M. A. Quraishi, Electrochemical and theoretical insights on the adsorption and corrosion inhibition of novel pyridinium-derived ionic liquids for mild steel in 1 M HCl, Journal of Molecular Liquids, 314, (2020), 113737 https://doi.org/10.1016/j.molliq.2020.113737
  40. Husnul Fuad Zein, Ibrar Alam, Piyapong Asanithi, Thana Sutthibutpong, Molecular dynamics study on the effects of charged amino acid distribution under low pH condition to the unfolding of hen egg white lysozyme and formation of beta strands, PLoS One, 17, 3, (2022), e0249742 https://doi.org/10.1371/journal.pone.0249742
  41. Chunzheng Li, Gang Gui, Li Zhang, Anqi Qin, Chen Zhou, Xiaoming Zha, Overview of Methionine Adenosyltransferase 2A (MAT2A) as an Anticancer Target: Structure, Function, and Inhibitors, Journal of Medicinal Chemistry, 65, 14, (2022), 9531-9547 https://doi.org/10.1021/acs.jmedchem.2c00395

Last update:

No citation recorded.

Last update: 2024-11-04 00:47:53

No citation recorded.