DOI: https://doi.org/10.14710/jksa.27.8.388-394

The Effect of Mole Ratio Natural-CaCO₃/KF in the Synthesis of KCaF₃ Perovskite Base Catalyst

Department of Chemistry, Faculty of Mathematics and Natural, Universitas Sebelas Maret, Surakarta 57126, Indonesia

Received: 2 Nov 2023; Revised: 24 Aug 2024; Accepted: 26 Aug 2024; Published: 31 Aug 2024.
Open Access Copyright 2024 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract
The KCaF3 perovskite catalyst was successfully synthesized by reacting limestone (natural-CaCO3) with potassium fluoride (KF). The synthesis of the KCaF3 catalyst was conducted with several variations in the mole ratio of CaCO3 to KF (1:1, 1:2, and 1:3). The research results showed that the addition of KF can affect the characteristics of the catalyst. The optimal catalyst is the KCaF3 catalyst with a mole ratio variation of 1:3. X-ray diffractometer analysis revealed that the highest KCaF3 phase composition reached 74.05%, while thermogravimetric analysis indicated a CaCO3 concentration of 34.50%. Surface Area Analyzer analysis shows that KCaF3 has the largest surface area, which is 187.1 m2/g. This catalyst efficiently facilitated the transesterification of palm oil, yielding 93.4% biodiesel.
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Keywords: Perovskite Catalyst; KCaF3; natural-CaCO3; KF
Funding: Universitas Sebelas Maret

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Section: Research Articles
Language : EN
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