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The Effect of Mole Ratio Natural-CaCO₃/KF in the Synthesis of KCaF₃ Perovskite Base Catalyst

Department of Chemistry, Faculty of Mathematics and Natural, Universitas Sebelas Maret, Surakarta 57126, Indonesia

Received: 2 Nov 2023; Revised: 24 Aug 2024; Accepted: 26 Aug 2024; Published: 31 Aug 2024.
Open Access Copyright 2024 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract
The KCaF3 perovskite catalyst was successfully synthesized by reacting limestone (natural-CaCO3) with potassium fluoride (KF). The synthesis of the KCaF3 catalyst was conducted with several variations in the mole ratio of CaCO3 to KF (1:1, 1:2, and 1:3). The research results showed that the addition of KF can affect the characteristics of the catalyst. The optimal catalyst is the KCaF3 catalyst with a mole ratio variation of 1:3. X-ray diffractometer analysis revealed that the highest KCaF3 phase composition reached 74.05%, while thermogravimetric analysis indicated a CaCO3 concentration of 34.50%. Surface Area Analyzer analysis shows that KCaF3 has the largest surface area, which is 187.1 m2/g. This catalyst efficiently facilitated the transesterification of palm oil, yielding 93.4% biodiesel.
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Keywords: Perovskite Catalyst; KCaF3; natural-CaCO3; KF
Funding: Universitas Sebelas Maret

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  1. Markus E. Borges, L. Díaz, Recent developments on heterogeneous catalysts for biodiesel production by oil esterification and transesterification reactions: A review, Renewable Sustainable Energy Reviews, 16, 5, (2012), 2839-2849 https://doi.org/10.1016/j.rser.2012.01.071
  2. Bishwajit Changmai, Chhangte Vanlalveni, Avinash Prabhakar Ingle, Rahul Bhagat, Samuel Lalthazuala Rokhum, Widely used catalysts in biodiesel production: a review, RSC Advances, 10, 68, (2020), 41625-41679 https://doi.org/10.1039/D0RA07931F
  3. Libai Wen, Yun Wang, Donglian Lu, Shengyang Hu, Heyou Han, Preparation of KF/CaO nanocatalyst and its application in biodiesel production from Chinese tallow seed oil, Fuel, 89, 9, (2010), 2267-2271 https://doi.org/10.1016/j.fuel.2010.01.028
  4. Hui Liu, Lingyan Su, Yong Shao, Lubin Zou, Biodiesel production catalyzed by cinder supported CaO/KF particle catalyst, Fuel, 97, (2012), 651-657 https://doi.org/10.1016/j.fuel.2012.02.002
  5. Lingmei Yang, Pengmei Lv, Zhongming Wang, Zhenhong Yuan, Wen Luo, Huiwen Li, Luo Yu, Hongzhe Sun, Promotional effect of transition metal doping on the properties of KF/CaO catalyst for biodiesel synthesis, International Journal of Green Energy, 14, 9, (2017), 784-791 https://doi.org/10.1080/15435075.2017.1330752
  6. Xiaozhou Ye, Wei Wang, Xiaoli Zhao, Tao Wen, Yongjun Li, Zhonghua Ma, Libai Wen, Jianfeng Ye, Yun Wang, The role of the KCaF3 crystalline phase on the activity of KF/CaO biodiesel synthesis catalyst, Catalysis Communications, 116, (2018), 72-75 https://doi.org/10.1016/j.catcom.2018.08.016
  7. Sagar Tanpure, Vishvanath Ghanwat, Bipin Shinde, Kiran Tanpure, Shamrao Lawande, The Eggshell Waste Transformed Green and Efficient Synthesis of K-Ca(OH)2 Catalyst for Room Temperature Synthesis of Chalcones, Polycyclic Aromatic Compounds, 42, 4, (2022), 1322-1340 https://doi.org/10.1080/10406638.2020.1776740
  8. Gajanan Sahua, Narendra Kumar Sahoo, Pavan Kumar Gupta, Vishal Chauhan, Shiva K. Saw, Characterization and Testing of KF/CaO Heterogeneous Catalyst for Biodiesel Production, Indian Journal of Engineering and Materials Sciences, 29, 5, (2022), 573-580 https://doi.org/10.56042/ijems.v29i5.50912
  9. I. F. Nurcahyo, Karna Wijaya, Arief Budiman, Yun Hin Taufiq-Yap, Synthesis and Characterization of Natural Ca(OH)2/KF Superbase Catalyst for Biodiesel Production from Palm Oil, Oriental Journal of Chemistry, 34, 2, (2018), 750-756 http://dx.doi.org/10.13005/ojc/340218
  10. Jharna Gupta, Madhu Agarwal, A. K. Dalai, Experimental evaluation of the catalytic efficiency of calcium based natural and modified catalyst for biodiesel synthesis, International Journal of Green Energy, 14, 11, (2017), 878-888 https://doi.org/10.1080/15435075.2017.1333434
  11. M. López Granados, M. D. Zafra Poves, D. Martín Alonso, R. Mariscal, F. Cabello Galisteo, R. Moreno-Tost, J. Santamaría, J. L. G. Fierro, Biodiesel from sunflower oil by using activated calcium oxide, Applied Catalysis B: Environmental, 73, 3, (2007), 317-326 https://doi.org/10.1016/j.apcatb.2006.12.017
  12. Dj. Vujicic, D. Comic, A. Zarubica, R. Micic, G. Boskovic, Kinetics of biodiesel synthesis from sunflower oil over CaO heterogeneous catalyst, Fuel, 89, 8, (2010), 2054-2061 https://doi.org/10.1016/j.fuel.2009.11.043
  13. Leandro Marques Correia, Rosana Maria Alves Saboya, Natália de Sousa Campelo, Juan Antonio Cecilia, Enrique Rodríguez-Castellón, Célio Loureiro Cavalcante, Rodrigo Silveira Vieira, Characterization of calcium oxide catalysts from natural sources and their application in the transesterification of sunflower oil, Bioresource Technology, 151, (2014), 207-213 https://doi.org/10.1016/j.biortech.2013.10.046
  14. Mansoor Anbia, Sholeh Masoomi, Sotoudeh Sedaghat, Mohammad Sepehrian, Potassium halides-impregnated eggshell as a heterogeneous nanocatalysts for biodiesel production, Journal of Environmental Treatment Techniques, 7, 1, (2019), 103-108
  15. Subramaniapillai Niju, Muhammed Niyas, Kader Mohamed Meera Sheriffa Begum, Narayanan Anantharaman, KF-impregnated clam shells for biodiesel production and its effect on a diesel engine performance and emission characteristics, Environmental Progress & Sustainable Energy, 34, 4, (2015), 1166-1173 https://doi.org/10.1002/ep.12070
  16. K. S. W. Sing, Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984), Pure and Applied Chemistry, 57, 4, (1985), 603-619 https://doi.org/10.1351/pac198557040603
  17. Dalibor M. Marinković, Miroslav V. Stanković, Ana V. Veličković, Jelena M. Avramović, Marija R. Miladinović, Olivera O. Stamenković, Vlada B. Veljković, Dušan M. Jovanović, Calcium oxide as a promising heterogeneous catalyst for biodiesel production: Current state and perspectives, Renewable and Sustainable Energy Reviews, 56, (2016), 1387-1408 https://doi.org/10.1016/j.rser.2015.12.007

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