Thermodynamic Study of Chitosan as a Corrosion Inhibitor for Carbon Steel in Chloride Solutions (NaCl and HCl) at Various Temperatures and Concentrations

Khafid Ubay Ilyas; Eni Budiyati; Nur Hidayati; Tri Widayatno

doi:10.14710/jksa.27.12.569-579

DOI: https://doi.org/10.14710/jksa.27.12.569-579

Thermodynamic Study of Chitosan as a Corrosion Inhibitor for Carbon Steel in Chloride Solutions (NaCl and HCl) at Various Temperatures and Concentrations

Khafid Ubay Ilyas, Eni Budiyati

, Nur Hidayati

, Tri Widayatno

Department of Chemical Engineering, Faculty of Engineering, Universitas Muhammadiyah Surakarta, Surakarta, Indonesia

Received: 25 Jul 2024; Revised: 10 Dec 2024; Accepted: 19 Dec 2024; Published: 31 Dec 2024.

BibTex Citation Data :

@article{JKSA65362,
    author = {Khafid Ilyas and Eni Budiyati and Nur Hidayati and Tri Widayatno},
    title = {Thermodynamic Study of Chitosan as a Corrosion Inhibitor for Carbon Steel in Chloride Solutions (NaCl and HCl) at Various Temperatures and Concentrations},
    journal = {Jurnal Kimia Sains dan Aplikasi},
  volume = {27},
    number = {12},
    year = {2024},
    keywords = {Chitosan; Corrosion Inhibition; Carbon Steel; Thermodynamic Parameters; Adsorption Mechanisms},
    abstract = {This research investigates the thermodynamic characteristics of chitosan as a corrosion inhibitor for carbon steel in chloride electrolyte environments, specifically saturated sodium chloride and 1 M hydrochloric acid, across different temperatures and concentrations. The study aimed to evaluate the effectiveness of chitosan in preventing corrosion and to examine the thermodynamic characteristics of the adsorption process. The results revealed that chitosan achieved the highest inhibition efficiency of 90.07% in a 1 M hydrochloric acid solution with a concentration of 250 mg/L at 303.15 K. In contrast, the maximum inhibition efficiency in a saturated sodium chloride solution was 50.50% at the same concentration of 250 mg/L and 303.15 K. Thermodynamic analysis showed that the adsorption of chitosan is spontaneous and exothermic in both media. The standard free energy of adsorption was found to be -38.63 kJ/mol at 303.15 K, decreasing to -43.69 kJ/mol at 343.15 K in saturated NaCl, and -42.40 kJ/mol at 303.15 K, decreasing to -48.65 kJ/mol at 343.15 K in 1 M HCl. The enthalpy of adsorption was -0.24976 kJ/mol in NaCl and 4.93560 kJ/mol in HCl, while the entropy of adsorption was -0.12661 J/mol·K in NaCl and -0.15610 J/mol·K in HCl. Additionally, the activation energy for corrosion increased from 1.61 kJ/mol at 0 mg/L to 6.96 kJ/mol at 250 mg/L chitosan in NaCl and from 4.10 kJ/mol at 0 mg/L to 23.79 kJ/mol at 250 mg/L chitosan in HCl. SEM analysis confirms the formation of a protective chitosan film, significantly reducing corrosion damage compared to uninhibited conditions. These findings indicate that chitosan is a highly effective corrosion inhibitor with favorable thermodynamic characteristics for applications in chloride-containing environments.},
   issn = {2597-9914},   pages = {569--579}  doi = {10.14710/jksa.27.12.569-579},
    url = {https://ejournal.undip.ac.id/index.php/ksa/article/view/65362}
}

Citation Format:

Abstract

This research investigates the thermodynamic characteristics of chitosan as a corrosion inhibitor for carbon steel in chloride electrolyte environments, specifically saturated sodium chloride and 1 M hydrochloric acid, across different temperatures and concentrations. The study aimed to evaluate the effectiveness of chitosan in preventing corrosion and to examine the thermodynamic characteristics of the adsorption process. The results revealed that chitosan achieved the highest inhibition efficiency of 90.07% in a 1 M hydrochloric acid solution with a concentration of 250 mg/L at 303.15 K. In contrast, the maximum inhibition efficiency in a saturated sodium chloride solution was 50.50% at the same concentration of 250 mg/L and 303.15 K. Thermodynamic analysis showed that the adsorption of chitosan is spontaneous and exothermic in both media. The standard free energy of adsorption was found to be -38.63 kJ/mol at 303.15 K, decreasing to -43.69 kJ/mol at 343.15 K in saturated NaCl, and -42.40 kJ/mol at 303.15 K, decreasing to -48.65 kJ/mol at 343.15 K in 1 M HCl. The enthalpy of adsorption was -0.24976 kJ/mol in NaCl and 4.93560 kJ/mol in HCl, while the entropy of adsorption was -0.12661 J/mol·K in NaCl and -0.15610 J/mol·K in HCl. Additionally, the activation energy for corrosion increased from 1.61 kJ/mol at 0 mg/L to 6.96 kJ/mol at 250 mg/L chitosan in NaCl and from 4.10 kJ/mol at 0 mg/L to 23.79 kJ/mol at 250 mg/L chitosan in HCl. SEM analysis confirms the formation of a protective chitosan film, significantly reducing corrosion damage compared to uninhibited conditions. These findings indicate that chitosan is a highly effective corrosion inhibitor with favorable thermodynamic characteristics for applications in chloride-containing environments.

Fulltext View|Download

Keywords: Chitosan; Corrosion Inhibition; Carbon Steel; Thermodynamic Parameters; Adsorption Mechanisms

Funding: Ministry of Education, Culture, Research and Technology under contract 108/E5/PG.02.00.PL/2024

Article Metrics:

Article Info

Section: Research Articles

Language : EN

In Vol 27, No 12 (2024): Volume 27 Issue 12 Year 2024

Recent articles

Green Synthesis of 4-Nitro-4’-Methoxy Chalcone by Grinding Technique and its Antibacterial Activity Thermodynamic Study of Chitosan as a Corrosion Inhibitor for Carbon Steel in Chloride Solutions (NaCl and HCl) at Various Temperatures and Concentrations Cigarette Filter-Based Membranes with Tannin and FeCl₃ Additives for Enhancing the Antifouling Properties of Oil Emulsion Filtration More recent articles

Most cited articles

Chitosan succinate/PVA-PEG Membrane: Preparation, Characterization and Permeation Ability Test on Creatinine Modifikasi Zeolit Alam Menggunakan TiO2 sebagai Fotokatalis Zat Pewarna Indigo Carmine Biolubrication Synthesis Made from Used Cooking Oil and Bayah Natural Zeolite Catalyst Activity Test of Suji Leaf Extract (Dracaena angustifolia Roxb.) on in vitro cholesterol lowering Preparasi Katalis Zeolit Alam Asam sebagai Katalis dalam Proses Pirolisis Katalitik Polietilena More cited articles

Somya Tanwer, Sudhish Kumar Shukla, Recent advances in the applicability of drugs as corrosion inhibitor on metal surface: A review, Current Research in Green and Sustainable Chemistry, 5, (2022), 100227 https://doi.org/10.1016/j.crgsc.2021.100227
Agus Yulianto, Agung S. Darmawan, Herry Purnama, Bibit Sugito, Turnad L. Ginta, Abdul Hamid, Enhancing Gray Cast Iron with Varying Nickel Electroplating Times, International Journal of Mechanical Engineering and Robotics Research, 13, 6, (2024), 601-607 https://doi.org/10.18178/ijmerr.13.6.601-607
Shitao Liu, Jun Zhou, Guangchuan Liang, Xidi Lyu, Ying He, Lanting Feng, Hao Peng, Inhibition of carbon steel corrosion in CO2-saturated 3.5 wt.% NaCl solution by vanillin chitosan oligosaccharide and synergistic effect of KI additive, Petroleum, 10, 4, (2024), 705-718 https://doi.org/10.1016/j.petlm.2023.10.003
Xiuli He, Zhifeng Yan, Hongyu Liang, Denghui Wang, Corrosion fatigue acoustic emission characteristics and evaluation of friction stir welding joints of AZ31 magnesium alloy in 3.5 wt.% NaCl solution, Journal of Materials Research and Technology, 25, (2023), 4582-4594 https://doi.org/10.1016/j.jmrt.2023.06.240
Agung Setyo Darmawan, Pramuko Ilmu Purboputro, Bibit Sugito, Bambang Waluyo Febriantoko, Agus Yulianto, Suprapto Suprapto, Tjipto Sujitno, Judha Purbolaksono, Increasing Hardness and Corrosion Resistance of Commercially Pure Titanium by Using Plasma Nitrocarburizing Process, Acta Metallurgica Slovaca, 28, 1, (2022), 14-18 https://doi.org/10.36547/ams.28.1.1266
Fengshuang Han, Zhili Gong, Rui Wang, Sufang Dang, Corrosion inhibition effect of mebendazole on 5Cr pipeline steel in 1 M HCl solution, International Journal of Electrochemical Science, 18, 10, (2023), 100319 https://doi.org/10.1016/j.ijoes.2023.100319
Nelvi Helmania Putri, Siska Dwi Febryani, Rabena Aprilla, Hilfi Pardi, Analisis Pengaruh Sifat Kimia Air Laut Terhadap Korosi Logam dan Pengendaliannya Menggunakan Proteksi Katodik, Journal of Research Education Chemistry, 6, 1, (2024), 34-34 https://doi.org/10.25299/jrec.2024.vol6(1).17173
XueHui Pang, WenJuan Guo, WeiHua Li, JianDong Xie, BaoRong Hou, Electrochemical, quantum chemical and SEM investigation of the inhibiting effect and mechanism of ciprofloxacin, norfloxacin and ofloxacin on the corrosion for mild steel in hydrochloric acid, Science in China Series B: Chemistry, 51, 10, (2008), 928-936 https://doi.org/10.1007/s11426-008-0099-z
Sibel Zor, Sulfathiazole as potential corrosion inhibitor for copper in 0.1 M NaCl, Protection of Metals and Physical Chemistry of Surfaces, 50, 4, (2014), 530-537 https://doi.org/10.1134/S2070205114040200
Kabiru Haruna, Tawfik A. Saleh, M. A. Quraishi, Expired metformin drug as green corrosion inhibitor for simulated oil/gas well acidizing environment, Journal of Molecular Liquids, 315, (2020), 113716 https://doi.org/10.1016/j.molliq.2020.113716
Chunlong Du, Xiaoming Wang, Yanyun Chen, Xiao Lu, Hu Wang, Synergistic effect between two quaternary ammonium salts and thiourea as corrosion inhibitors for X70 steels in CO2 saturated 3.5% NaCl solution, International Journal of Electrochemical Science, 19, 1, (2024), 100443 https://doi.org/10.1016/j.ijoes.2023.100443
Abdel Ghany F. Shoair, Mariem M. Motawea, Abdulraheem S. A. Almalki, Mai M. A. H. Shanab, Amir El-Basiony, Hany A. Nasef, Expired terazosin as environmentally safe corrosion inhibitor for 1018 carbon steel in 1 M HCl solution: Experimental and computational studies, International Journal of Electrochemical Science, 19, 1, (2024), 100397 https://doi.org/10.1016/j.ijoes.2023.100397
Ghalia A. Gaber, Marwa M. Soliman, Zeinab Adel Nasr, Amira M. Hyba, Comprehensive investigation of sustainable corrosion inhibitors on Cu–Zn alloy in simulated cooling water: Electrochemical explorations, SEM/EDX analysis, and DFT/molecular simulations utilizing expired Bepotastine-B as a green inhibitor, Sustainable Chemistry and Pharmacy, 37, (2024), 101340 https://doi.org/10.1016/j.scp.2023.101340
Intan Endah Rachmawati, Ngadiwiyana Ngadiwiyana, Ismiyarto Ismiyarto, Sintesis Turunan Azomethin Sebagai Zat Aktif Inhibitor Korosi pada Logam Menggunakan Bahan Dasar Piperonal dan 2-Aminopiridin, Jurnal Kimia Sains dan Aplikasi, 20, 3, (2017), 136-139 https://doi.org/10.14710/jksa.20.3.136-139
Ghalia A. Gaber, Aisha Y. Hassan, Mona S. Kadh, Nashwa M. Saleh, Eman S. Abou-Amra, Amira M. Hyba, A computational and experimental investigation of novel synthesis fused pyrazolopyrimidine as zinc corrosion inhibitor in 1 M HNO3, Chemical Papers, 78, 5, (2024), 3189-3203 https://doi.org/10.1007/s11696-024-03303-x
Femiana Gapsari, Syarif Hidayatullah, Putu Hadi Setyarini, Kartika A. Madurani, Hendra Hermawan, Effectiveness of a fish scales-derived chitosan coating for corrosion protection of carbon steel, Egyptian Journal of Petroleum, 31, 1, (2022), 25-31 https://doi.org/10.1016/j.ejpe.2022.02.001
Waad M. Alotaibi, Saedah R. Al-Mhyawi, Soha M. Albukhari, Chitosan-Clay Nanocomposite as a Green Corrosion Inhibitor for Mild Steel in Hydrochloric Acid Solution, International Journal of Electrochemical Science, 17, 8, (2022), 220848 https://doi.org/10.20964/2022.08.50
Sung-Wook Kim, Sang-Yoon Park, Chang-Hyun Roh, Sun-Byeong Kim, High-temperature electrochemical corrosion behavior of SA106 Grade B carbon steel with corrosion inhibitors in HyBRID solution, Nuclear Engineering and Technology, 55, 6, (2023), 2256-2262 https://doi.org/10.1016/j.net.2023.03.008
Clarissa Welny Saleh, Harmami Harmami, Ita Ulfin, Pengendalian korosi menggunakan inhibitor kitosan larut air untuk baja lunak dalam media HCl 1M, Jurnal Sains dan Seni ITS, 6, 1, (2017), C1-C4 http://dx.doi.org/10.12962/j23373520.v6i1.22414
Peipei Kong, Nali Chen, Yong Lu, Huixia Feng, Jianhui Qiu, Corrosion by Polyaniline/Salicylaldehyde Modified Chitosan in Hydrochloric Acid Solution, International Journal of Electrochemical Science, 14, 10, (2019), 9774-9784 https://doi.org/10.20964/2019.10.11
Gamal A. El-Mahdy, Ayman M. Atta, Hamad A. Al-Lohedan, Abdelrahman O. Ezzat, Influence of Green Corrosion Inhibitor based on Chitosan Ionic Liquid on the Steel Corrodibility in Chloride Solution, International Journal of Electrochemical Science, 10, 7, (2015), 5812-5826 https://doi.org/10.1016/S1452-3981(23)17297-X
Guo-Dong Cui, Yan-Ming Chen, Qi-Ming Zhang, Zheng Wang, Tian Tang, Qing Zhao, Yu Zhang, Li-Feng Zhang, Yuan-Qi Gu, Yang-Sheng Liu, Three novel dendritic chitosan derivatives for inhibiting acid corrosion of petroleum pipelines, Petroleum Science, 20, 6, (2023), 3918-3930 https://doi.org/10.1016/j.petsci.2023.08.010
Alice Osheiza Alao, Omotayo Sanni, Abimbola Patricia Popoola, Insight into the anti-corrosive performance of Persea Americana seed extract as a high-efficiency and sustainable corrosion inhibitor for API 5 L X65 pipeline steel in 1 M HCl solution, International Journal of Electrochemical Science, 18, 9, (2023), 100248 https://doi.org/10.1016/j.ijoes.2023.100248
Hemat M. Dardeer, Safaa A. Abbas, Mohamed Mohamady Ghobashy, Ghalia A. Gaber, Moustafa F. Aly, Synthesis and characterization of novel chitosan-sodium pyruvate polymer and its derivatives for corrosion feature evaluation of Cu-Ni alloy, Inorganic Chemistry Communications, 157, (2023), 111308 https://doi.org/10.1016/j.inoche.2023.111308
Meng Wang, Chengjuan Yang, Zhen Yang, Yanling Tian, The effects of carbon ion implantation on wettability, abrasion, thermal and anti-corrosion stabilities of laser ablated super-hydrophobic Nitinol surface, Journal of Materials Research and Technology, 28, (2024), 1784-1793 https://doi.org/10.1016/j.jmrt.2023.12.078
A. Zarrouk, B. Hammouti, H. Zarrok, S. S. Al-Deyab, M. Messali, Temperature Effect, Activation Energies and Thermodynamic Adsorption Studies of L-Cysteine Methyl Ester Hydrochloride As Copper Corrosion Inhibitor In Nitric Acid 2M, International Journal of Electrochemical Science, 6, 12, (2011), 6261-6274 https://doi.org/10.1016/S1452-3981(23)19679-9
Anton Kokalj, On the use of the Langmuir and other adsorption isotherms in corrosion inhibition, Corrosion Science, 217, (2023), 111112 https://doi.org/10.1016/j.corsci.2023.111112
M. Boudalia, R. M. Fernández-Domene, M. Tabyaoui, A. Bellaouchou, A. Guenbour, J. García-Antón, Green approach to corrosion inhibition of stainless steel in phosphoric acid of Artemesia herba alba medium using plant extract, Journal of Materials Research and Technology, 8, 6, (2019), 5763-5773 https://doi.org/10.1016/j.jmrt.2019.09.045
Ruza Gabriela Medeiros de Araújo Macedo, Nívia do Nascimento Marques, Josealdo Tonholo, Rosangela de Carvalho Balaban, Water-soluble carboxymethylchitosan used as corrosion inhibitor for carbon steel in saline medium, Carbohydrate Polymers, 205, (2019), 371-376 https://doi.org/10.1016/j.carbpol.2018.10.081
Olufemi Sylvester Bamisaye, Nthabiseng Maledi, Josias Van der Merwe, Michael Oluwatosin Bodunrin, Microstructure, hardness, oxidation, and corrosion behavior of TiNbTaVW refractory high entropy alloy in 3.5 wt% NaCl and 1 M H2SO4, Journal of Alloys and Compounds, 983, (2024), 173803 https://doi.org/10.1016/j.jallcom.2024.173803
Jwaher M. AlGhamdi, Shamsuddeen A. Haladu, Nuhu Dalhat Mu'azu, Hissah A. Alqahtani, Mukarram Zubair, Mohammad Saood Manzar, Fatimah Abdulmhsin Alkhowildi, Rola Zafer Mohammed Kuban, Norah Faisal AlSubaie, Polyethyleneglycol bisphenol A epichlorohydrin copolymer (PEG-BEC) as a highly efficient inhibitor for mild steel corrosion in 1M HCl solutions, South African Journal of Chemical Engineering, 49, (2024), 326-338 https://doi.org/10.1016/j.sajce.2024.05.008
Iman A. Annon, Ahmed S. Abbas, Waleed K. Al-Azzawi, Mahdi M. Hanoon, Ahmed A. Alamiery, Wan Nor Roslam Wan Isahak, Abdul Amir H. Kadhum, Corrosion inhibition of mild steel in hydrochloric acid environment using thiadiazole derivative: Weight loss, thermodynamics, adsorption and computational investigations, South African Journal of Chemical Engineering, 41, (2022), 244-252 https://doi.org/10.1016/j.sajce.2022.06.011
Jia-hao Zhu, Bi-lan Lin, Tian-hu Duan, Han-quan Lin, Guo-yu Zhang, Xin-xin Zhou, Yu-ye Xu, Zea mays bracts extract as an eco-friendly corrosion inhibitor for steel in HCl pickling solution: Experimental and simulation studies, Arabian Journal of Chemistry, 17, 9, (2024), 105895 https://doi.org/10.1016/j.arabjc.2024.105895

Last update:

No citation recorded.

Last update: 2025-01-21 11:50:03

No citation recorded.

As an article writer, the author has the right to use their articles for various purposes, including use by institutions that employ authors or institutions that provide funding for research. Author rights are granted without special permission.

Author who publishes a paper at JKSA has the broad right to use their work for teaching and scientific purposes without the need to ask permission, including: used for (i) teaching in the author's class or institution, (ii) presentation at meetings or conferences and distributing copies to participants ; (iii) training conducted by the author or author's institution; (iv) distribution to colleagues for research use; (v) use in the compilation of subsequent authors' works; (vi) inclusion in a thesis or dissertation; (vi) reuse of part of the article in another work (with citation); (vii) preparation of derivative works (with citation); (viii) voluntary posting on open websites operated by authors or author institutions for scientific purposes (follow the CC BY-SA License).

Authors and readers can copy and redistribute material in any media or format, and mix, modify, and build material for any purpose but they must provide appropriate credit (provide article citation or content), providing links to the license, and indicate if there are changes.

The authors submitting a manuscript do so on the understanding that if accepted for publication, copyright of the article shall be assigned to Jurnal Kimia Sains dan Aplikasi (JKSA). Copyright encompasses rights to reproduce and deliver the article in all form and media, including reprints, photographs, microfilms and any other similar reproductions, as well as translations.

Reproduce any part of this journal, its storage in the database or its transmission by all forms or media is permitted does not need for written permission from JKSA. However, it should be cited as an honor in academic manners

JKSA and the Chemistry Department of Diponegoro University and the Editor make every effort to ensure that there are no data, opinions, or false or misleading statements published in JKSA. However, the content of the article is the sole and exclusive responsibility of each author.

The Copyright Transfer Form can be downloaded here: [Copyright Transfer Form - Indonesian] [Copyright Transfer Form - English]. The copyright form should be signed originally and send to the Editor in the form of printed letters, scanned documents sent via email or fax.

Adi Darmawan, Ph.D (Editor in Chief)

Editor in chief of Jurnal Kimia Sains dan Aplikasi (JKSA)

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University

Jl. Prof. Soedarto, Kampus Undip Tembalang, Semarang, Central Java, Indonesia 50275
Email: jksa@live.undip.ac.id