DOI: https://doi.org/10.14710/ijred.9.2.159-166

Generating Organic Liquid Products from Catalytic Cracking of Used Cooking Oil over Mechanically Mixed Catalysts

Department of Mechanical Engineering, Faculty of Engineering, Chiang Mai University, Chiang Mai 50200, Thailand

Received: 3 Jan 2020; Revised: 3 Mar 2020; Accepted: 5 Mar 2020; Available online: 2 May 2020; Published: 15 Jul 2020.
Editor(s): H Hadiyanto
Open Access Copyright (c) 2020 The Authors. Published by Centre of Biomass and Renewable Energy (CBIORE)
Creative Commons License This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

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Abstract
Used cooking oil is unsuitable to use again in the food process, but it may be harnessed as raw material in biofuel production. In this work, used palm oil was reactedvia cracking over mechanically mixed catalystsbetween ZSM-5 and Y-Re-16to generate organic liquid products (OLP). The catalysts used were known for highacidity and lowcost for decomposition, degradation,and deoxygenation of triglycerides. The cracking experiments were conducted in a flow reactor. The experimental variables included reaction temperature between 300-500°C, catalyst loading between 5-20 % w/w, and ratio of mixed catalyst between ZSM-5 and Y-Re-16 from 0-100 % w/w. They were setvia response surface methodology and central composite design of experiments. Both catalysts showed good cracking reaction. The optimum condition for generating the OLP of about 85 % w/w was found at 300°C, 5 % catalyst loading, 97 % ratio of mixed catalyst. The OLPs with different short-chain hydrocarbons between C7-C21 were identified. The main components were 71.43% of diesel, 12.11% of gasoline, and 8.95% of kerosene-like components.
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Keywords: Biomass; Biofuels; Organic liquid fuels; Renewable energy; Vegetable oils
Funding: Chiang Mai University

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Section: Original Research Article
Language : EN
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  1. Ahmad, M., Farhana, R., Raman, A.A.A., Bhargava, S.K., 2016. Synthesis and activity evaluation of heterometallic nano oxides integrated ZSM-5 catalysts for palm oil cracking to produce biogasoline. Energy Conversion and Management 119, 352–360. https://doi.org/10.1016/j.enconman.2016.04.069
  2. Al Sharifi, M., Znad, H., 2019. Transesterification of waste canola oil by lithium/zinc composite supported on waste chicken bone as an effective catalyst. Renewable Energy, https://doi.org/10.1016/j.renene.2019.11.071
  3. Anderson, M., Whitcomb, P., 2001. Design of Experiments: Statistical Principles of Research Design and Analysis. Technometrics 43, 236–237. https://doi.org/10.1198/tech.2001.s589
  4. Benavides, P.T., Cronauer, D.C., Adom, F., Wang, Z., Dunn, J.B., 2017. The influence of catalysts on biofuel life cycle analysis (LCA). Sustainable Materials and Technologies 11, 53–59. https://doi.org/10.1016/j.susmat.2017.01.002
  5. Cheng, J., Zhang, Z., Zhang, X., Liu, J., Zhou, J., Cen, K., 2019. Sulfonated mesoporous Y zeolite with nickel to catalyze hydrocracking of microalgae biodiesel into jet fuel range hydrocarbons. International Journal of Hydrogen Energy 44, 1650–1658. https://doi.org/10.1016/j.ijhydene.2018.11.110
  6. Corma, A., Huber, G., Sauvanaud, L., Oconnor, P., 2007. Processing biomass-derived oxygenates in the oil refinery: Catalytic cracking (FCC) reaction pathways and role of catalyst. Journal of Catalysis 247, 307–327. https://doi.org/10.1016/j.jcat.2007.01.023
  7. Crabbe, E., Nolasco-Hipolito, C., Kobayashi, G., Sonomoto, K., Ishizaki, A., 2001. Biodiesel production from crude palm oil and evaluation of butanol extraction and fuel properties. Process Biochemistry 37, 65–71. https://doi.org/10.1016/S0032-9592(01)00178-9
  8. Emori, E.Y., Hirashima, F.H., Zandonai, C.H., Ortiz-Bravo, C.A., Fernandes-Machado, N.R.C., Olsen-Scaliante, M.H.N., 2017. Catalytic cracking of soybean oil using ZSM5 zeolite. Catalysis Today 279, 168–176. https://doi.org/10.1016/j.cattod.2016.05.052
  9. Hosseinpour, N., Mortazavi, Y., Bazyari, A., Khodadadi, A.A., 2009. Synergetic effects of Y-zeolite and amorphous silica-alumina as main FCC catalyst components on triisopropylbenzene cracking and coke formation. Fuel Processing Technology 90, 171–179. https://doi.org/10.1016/j.fuproc.2008.08.013
  10. Ibrahim, S.H., Hamza, E., 2017. Optimization of lipid extraction from municipal scum sludge for biodiesel production using statistical approach. International Journal of Renewable Energy Development 6, 171. https://doi.org/10.14710/ijred.6.2.171-179
  11. Ibarra, Á., Hita, I., Azkoiti, M.J., Arandes, J.M., Bilbao, J., 2019. Catalytic cracking of raw bio-oil under FCC unit conditions over different zeolite-based catalysts. Journal of Industrial and Engineering Chemistry 78, 372–382. https://doi.org/10.1016/j.jiec.2019.05.032
  12. Jaroenkhasemmeesuk, C., Diego, M.E., Tippayawong, N., Ingham, D.B., Pourkashanian, M., 2018. Simulation analysis of the catalytic cracking process of biomass pyrolysis oil with mixed catalysts: Optimization using the simplex lattice design. Int J Energy Res 42, 2983–2996. https://doi.org/10.1002/er.4023
  13. Kadarwati, S., 2015. Polymerisation and coke formation during mild hydrotreatment of bio-oil over pre-sulphided co-Mo/γ-Al2O3 catalyst. International Journal of Renewable Energy Development 4, 32–38. https://doi.org/10.14710/ijred.4.1.32-38
  14. Karmaker, A.K., Rahman, Md.M., Hossain, Md.A., Ahmed, Md.R., 2020. Exploration and corrective measures of greenhouse gas emission from fossil fuel power stations for Bangladesh. Journal of Cleaner Production 244, 118645. https://doi.org/10.1016/j.jclepro.2019.118645
  15. Khammasan T., Tippayawong N., 2018, Light liquid fuel from catalytic cracking of beef tallow with ZSM-5, International Journal of Renewable Energy Research, 8, 407–413
  16. Khuenkaeo, N., Tippayawong, N., 2018. Bio-oil production from ablative pyrolysis of corncob pellets in a rotating Blade Reactor. IOP Conf. Ser.: Earth Environ. Sci. 159, 012037. https://doi.org/10.1088/1755-1315/159/1/012037
  17. Khuenkaeo, N., Tippayawong, N., 2020. Production and characterization of bio-oil and bio-char from ablative pyrolysis of lignocellulosic biomass residues. Chemical Engineering Communications, 207(2), 153-160
  18. Kim, S., Sasmaz, E., Pogaku, R., Lauterbach, J., 2020. Effects of reaction conditions and organic sulfur compounds on coke formation and HZSM-5 catalyst performance during jet propellant fuel (JP-8) cracking. Fuel 259, 116240. https://doi.org/10.1016/j.fuel.2019.116240
  19. Li, C., Ma, J., Xiao, Z., Hector, S.B., Liu, R., Zuo, S., Xie, X., Zhang, A., Wu, H., Liu, Q., 2018. Catalytic cracking of Swida wilsoniana oil for hydrocarbon biofuel over Cu-modified ZSM-5 zeolite. Fuel 218, 59–66. https://doi.org/10.1016/j.fuel.2018.01.026
  20. Li, L., Yuan, X., Wang, Y., Sun, B., Wu, D., 2019. A two-layer fuzzy synthetic strategy for operational performance assessment of an industrial hydrocracking process. Control Engineering Practice 93, 104187. https://doi.org/10.1016/j.conengprac.2019.104187
  21. Maher, K.D., Bressler, D.C., 2007. Pyrolysis of triglyceride materials for the production of renewable fuels and chemicals. Bioresource Technology 98, 2351–2368. https://doi.org/10.1016/j.biortech.2006.10.025
  22. Mante O.D., Agblevor F.A., Oyama S.T., McClung R., 2014, Catalytic pyrolysis with ZSM-5 based additive as co-catalyst to Y-zeolite in two reactor configurations, Fuel, 117, 649–659
  23. Nguyen, H.C., Nguyen, M.L., Wang, F.-M., Liang, S.-H., Bui, T.L., Ha, H.H., Su, C.-H., 2019. Using switchable solvent as a solvent and catalyst for in situ transesterification of spent coffee grounds for biodiesel synthesis. Bioresource Technology 289, 121770. https://doi.org/10.1016/j.biortech.2019.121770
  24. Pascoal, C.V.P., Oliveira, A.L.L., Figueiredo, D.D., Assunção, J.C.C., 2020. Optimization and kinetic study of ultrasonic-mediated in situ transesterification for biodiesel production from the almonds of Syagrus cearensis. Renewable Energy 147, 1815–1824. https://doi.org/10.1016/j.renene.2019.09.122
  25. Prasertpong, P., Tippayawong, N., 2019. Upgrading of biomass pyrolysis oil model compound via esterification: Kinetic study using heteropoly acid. Energy Procedia 160, 253–259. https://doi.org/10.1016/j.egypro.2019.02.144
  26. Prasertpong, P., Jaroenkhasemmeesuk, C., Regalbuto, J.R., Lipp, J., Tippayawong, N., 2020. Optimization of process variables for esterification of bio-oil model compounds by a heteropolyacid catalyst. Energy Reports 6, 1–9. https://doi.org/10.1016/j.egyr.2019.11.026
  27. Rathore, V., Newalkar, B.L., Badoni, R.P., 2016. Processing of vegetable oil for biofuel production through conventional and non-conventional routes. Energy for Sustainable Development 31, 24–49. https://doi.org/10.1016/j.esd.2015.11.003
  28. Rofiqulislam, M., Haniu, H., Rafiqulalambeg, M., 2008. Liquid fuels and chemicals from pyrolysis of motorcycle tire waste: Product yields, compositions and related properties. Fuel 87, 3112–3122. https://doi.org/10.1016/j.fuel.2008.04.036
  29. Schipper, P.H., Dwyer, F.G., Sparrell, P.T., Mizrahi, S., Herbst, J.A., 1988. Zeolite ZSM-5 in Fluid Catalytic Cracking: Performance, Benefits, and Applications, in: Occelli, M.L. (Ed.), Fluid Catalytic Cracking. American Chemical Society, Washington, DC, pp. 64–86. https://doi.org/10.1021/bk-1988-0375.ch005
  30. Suwannapa, P., Tippayawong, N., 2017. Optimization of two-step biodiesel production from beef tallow with microwave heating. Chemical Engineering Communications 204(5), 618-624
  31. Syah Putra, R., Shabur Juliantoa, T., Hartono, P., Dyah Puspitasaria, R., Kurniawan, A., 2014. Pre-treatment of used-cooking oil as feed stocks of biodiesel production by using activated carbon and clay minerals. International Journal of Renewable Energy Development 3, 33–35. https://doi.org/10.14710/ijred.3.1.33-35
  32. US EIA, 1997. Petroleum product supplied (consumption). Retrieved on November 11, 2019, from: https://www.eia.gov/dnav/pet/pet_cons_psup_dc_nus_mbblpd_a.htm
  33. Wu, Y., Wang, X., Song, Q., Zhao, L., Su, H., Li, H., Zeng, X., Zhao, D., Xu, J., 2018. The effect of temperature and pressure on n-heptane thermal cracking in regenerative cooling channel. Combustion and Flame 194, 233–244. https://doi.org/10.1016/j.combustflame.2018.04.036
  34. Zhao, X., Wei, L., Julson, J., Qiao, Q., Dubey, A., Anderson, G., 2015. Catalytic cracking of non-edible sunflower oil over ZSM-5 for hydrocarbon bio-jet fuel. New Biotechnology 32, 300–312. https://doi.org/10.1016/j.nbt.2015.01.004
  35. Zheng, Q., Huo, L., Li, H., Mi, S., Li, X., Zhu, X., Deng, X., Shen, B., 2017. Exploring structural features of USY zeolite in the catalytic cracking of Jatropha Curcas L. seed oil towards higher gasoline/diesel yield and lower CO2 emission. Fuel 202, 563–571. https://doi.org/10.1016/j.fuel.2017.04.073

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