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Preparation of Anode Material for Lithium Battery from Activated Carbon

1Chemistry Department, Faculty of Science, Naresuan University, Phitsanulok, Thailand

2School of Renewable Energy and Smart Grid Technology, Naresuan University, Phitsanulok, Thailand

Received: 10 Sep 2020; Revised: 18 Oct 2020; Accepted: 21 Oct 2020; Available online: 25 Oct 2020; Published: 1 Feb 2021.
Editor(s): H. Hadiyanto
Open Access Copyright (c) 2021 The Authors. Published by Centre of Biomass and Renewable Energy (CBIORE)
Creative Commons License This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

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Abstract

This research study describes the preparation of corncob derivedactivated carbon to be used as anodematerial for the preparation of lithium ion battery.The corncob was activated at 900 °C for 3 hours with KOH used in a 1:3 weight ratio.The final product was analyzed for chemical, physical, and electrical properties.The results show that the activated carbon is amorphous and contains some graphitic carbon with interconnected nano-channels. Furthermore,carboxyl functional groups were detected on the surface of the activated carbon product.The observed morphological characteristics in terms of surface area, total pore volume, micropore volume, and average pore size are 1367.4501 m²/g, 0.478390 cm³/g, 0.270916 cm³/g, and 2.10872 nm, respectively.In addition, the product also exhibits low electrical resistance in the range 0.706W-1.071W.Finally, the specific discharge capacities at the 1st and the 2nd cycles of the corncob derived activated carbon anode material were 488.67mA h/g and 241.45 mA h/g, respectively with an average of about 225 Ah/kg between the 3rd cycle and the 5th cycle. The averagespecific charge capacities/specific discharge capacities at increasing charging rate of 0.2C, 0.5C, 1C, 2C, and 5C were approximated 190 mAh/g, 155 mAh/g, 135 mAh/g, 120 mAh/g, and 75 mAh/g, respectively, with 100%Coulombic efficiency in all 5 cycles.It was shown that the corncob derived activated carbon anode material has a relatively high rate capability, high reversibility, and rapid and stable capacity when compared to the general of biomass-derived carbon

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Keywords: activated carbon, anode material, corncob, lithium ion battery
Funding: National Science and Technology Development Agency

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  1. Chen, F., Yang, J., Bai, T., Long, B., & Zhou, X. (2016). Biomass waste-derived honeycomb-like nitrogen and oxygen dual-doped porous carbon for high performance lithium-sulfur batteries. Electrochimica Acta, 192, 99-109. https://doi.org/10.1016/j.electacta.2016.01.192
  2. Gong, C., Xue, Z., Wen, S., Ye, Y., & Xie, X. (2016). Advanced carbon materials/olivine LiFePO4 composites cathode for lithium ion batteries. Journal of Power Sources, 318, 93-112. https://doi.org/10.1016/j.jpowsour.2016.04.008
  3. Han, S.-W., Jung, D.-W., Jeong, J.-H., & Oh, E.-S. (2014). Effect of pyrolysis temperature on carbon obtained from green tea biomass for superior lithium ion battery anodes. Chemical Engineering Journal, 254, 597-604. https://doi.org/10.1016/j.cej.2014.06.021
  4. Huang, Y., Lin, Z., Zheng, M., Wang, T., Yang, J., Yuan, F., Lu, X., Liu, L., & Sun, D. (2016). Amorphous Fe2O3 nanoshells coated on carbonized bacterial cellulose nanofibers as a flexible anode for high-performance lithium ion batteries. Journal of Power Sources, 307, 649-656. https://doi.org/10.1016/j.jpowsour.2016.01.026
  5. Iwai, K., Tamura, T., Nguyen, D.T., & Taguchi, K. (2019). The development of a flexible battery by using a stainless mesh anode. International Journal of Renewable Energy Development, 8(3), 225-229. https://doi.org/10.14710/ijred.8.3.225-229
  6. Pandolfo, A.G., & Hollenkamp, A.F. (2006) Carbon properties and their role in supercapacitors. Journal of Power Sources, 157, 11-27. https://doi.org/10.1016/j.jpowsour.2006.02.065
  7. Pode, R. (2016). Potential applications of rice husk ash waste from rice husk biomass power plant. Renewable and Sustainable Energy Reviews, 53, 1468-1485. https://doi.org/10.1016/j.rser.2015.09.051
  8. Rios, C.D.M.S., Simone, V., Simonin, L., Martinet, S., & Dupont, C. (2018). Biochars from various biomass types as precursors for hard carbon anodes in sodium-ion batteries. Biomass and Bioenergy, 117, 32-37. https://doi.org/10.1016/j.biombioe.2018.07.001
  9. Ru, H., Bai, N., Xiang, K., Zhou, W., Chen, H., & Zhao, X.S. (2016). Porous carbons derived from microalgae with enhanced electrochemical performance for lithium-ion batteries. Electrochimica Acta, 194, 10-16. https://doi.org/10.1016/j.electacta.2016.02.083
  10. Sharma, S., Panwar, A.K., & Tripathi, M.M. (2020). Investigation of electrochemical, thermal and electrical performance of 3D lithium-ion battery module in a high-temperature environment. International Journal of Renewable Energy Development, 9(2), 151-157. https://doi.org/10.14710/ijred.9.2.151-157
  11. Song, H., Fu, J., Ding, K., Huang, C., Wu, K., Zhang, X., Gao, B., Huo, K., Peng, X., & Chu, P.K. (2016). Flexible Nb2O5 nanowires/graphene film electrode for high performance hybrid Li-ion supercapacitors. Journal of Power Sources, 328, 599-606. https://doi.org/10.1016/j.jpowsour.2016.08.052
  12. Valentini, L. (2015). Bio-inspired materials and grapheme for electronic applications. Materials Letters, 148, 204-207. https://doi.org/10.1016/j.matlet.2015.02.072
  13. Wu, F., Huang, R., Mu, D., Wu, B., & Chen, Y. (2016). Controlled synthesis of graphitic carbon-encapsulated a-Fe2O3 nanocomposite via low-temperature catalytic graphitization of biomass and its lithium storage property. Electrochimica Acta, 187, 508-516. https://doi.org/10.1016/j.electacta.2015.11.108
  14. Xin, S., Yang, H., Chen, Y., Yang, M., Chen, L., Wang, X., & Chen, H. (2015). Chemical structure evolution of char during the pyrolysis of cellulose. Journal of Analytical and Applied Pyrolysis, 116, 263-271. https://doi.org/10.1016/j.jaap.2015.09.002
  15. Xing, B.-L., Guo, H., Chen, L.-J., Chen, Z.-F., Zhang, C.-X., Huang, G.-X., Xie, W., & Yu, J.-L. (2015). Lignite-derived high surface area mesoporous activated carbons for electrochemical capacitors. Fuel Processing Technology, 138, 734-742. https://doi.org/10.1016/j.fuproc.2015.07.017
  16. Zhang, K., Hu, Z., & Chen, J. (2013). Functional porous carbon-based composite electrode materials for lithium secondary batteries. Journal of Energy Chemistry, 22, 214-225. https://doi.org/10.1016/S2095-4956(13)60027-3
  17. Zhang, Y., Zhang, F., Li, G.D., & Chen, J.-S. (2007). Microporous carbon derived from pinecone hull as anode material for lithium secondary batteries. Materials Letters, 61, 5209-5212. https://doi.org/10.1016/j.matlet.2007.04.032
  18. Zhu, Y., Wang, S., Zhong, Y., Cai, R., Li, L., & Shao, Z. (2016). Facile synthesis of a MoO2-Mo2C-C composite and its application as favorable anode material for lithium-ion batteries. Journal of Power Sources, 307, 552-560. https://doi.org/10.1016/j.jpowsour.2016.01.014

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