skip to main content

Pre-treatment of Used-Cooking Oil as Feed Stocks of Biodiesel Production by Using Activated Carbon and Clay Minerals

1Department of Chemistry, Faculty of Mathematics and Natural Sciences , Islamic University of Indonesia, , Indonesia

2Jl. Kaliurang Km 14.5, Yogyakarta 55584, Indonesia

Published: 15 Feb 2014.
Editor(s):

Citation Format:
Cover Image
Abstract

Many low-cost feedstock i.e. used-cooking oil (UCO) for the production of biodiesel fuel (BDF) has contained a large amount of water and high proportion of free fatty acids (FFAs). Therefore, a pre-treatment process to reduce the water content (<0.1 wt.%) and FFAs (<2.0 wt.%) were necessary in order to avoid an undesirable side reactions, such as saponification, which could lead to serious problem of product separation and low fatty acid methyl ester (FAME) yield. . In this study, a pre-treatment process of used cooking oil as a feedstock for the production of BDF by using various adsorbents such as Activated Carbon (AC) and various clay minerals, for example Smectite (S), Bentonite (B), Kaolinite (K), and Powdered Earthenware (PE) were evaluated. The oil obtained from pre-treatment was compared with oil without pre-treatment process. In this study, we reported a basic difference in material ability to the oil, depending on the adsorption condition with respect to the physico-chemical parameters, e.g. refractive index (R), density (ρ), FFAs, and water content (W). The results showed that the water content and FFAs in the oil has decreased when using AC as an adsorbent compared with clay minerals. However, the refractive index of oil has similar with the oil without pre-treatment process as well; meanwhile, the density of oil has increased after the pre-treatment process by using clay minerals.

Fulltext View|Download
Keywords: used cooking oil; activated carbon, clay minerals; adsorbent; physico-chemical properties

Article Metrics:

  1. Encinar, J.M., Gonza´ lez, J.F., and Rodrı´guez-Reinares, A., (2005) Biodiesel from used frying oil. variables affecting the yields and characteristics of the biodiesel, Industrial Engineering Chemical Research, 44, pages 5491 – 5499
  2. Faccini, C.S., Espinosa da Cunha, M., Moraes, M.S.A., Krause, L.C., Manique, M.C., Rodrigues, M.R.A., Benvenutti, E.V., and Caramão, E.B., (2011) Dry washing in biodiesel purification: a comparative study of adsorbents, Journal of Brazilian Chemical Society, Vol. 22, No. 3, pages 558-563
  3. Freedman, B., Pryde, E.H., Mounts, T.L. (1984) Variables affecting the yields of fatty esters from transesterfied vegetable oils, Journal of the American Oil Chemists Society, 61 (10), page 1638-1643
  4. Guan, G., and Kusakabe, K. (2009) Synthesis of biodiesel fuel using an electrolysis method, Chemical Engineering Journal, 153, pages 159-163
  5. Leung D.Y.C., Wu X., and Weung M.K.H. (2010) A review on biodiesel production using catalyzed transesterification, Applied Energy, 87, pages 1083-1095
  6. Mittelbach, M., (1996) Diesel fuel derived from vegetable oils, VI: Specifications and quality control of biodiesel, Bioresource Technology, 56, pages 7-11
  7. Indexmundi (2013) Indonesia Palm Oi Domestic Comsumption per Year. http://indexmundi.com/agriculture/ (accessible 6 Januari 2014)

Last update:

  1. Influence of Physical and Chemical Activation of Coconut Shell Applied to Reduce Free Fatty Acids of Used Cooking Oil in Biodiesel Plant

    Fandi Angga Prasetya, Mikrimah Belva Areta, Ervan Arjani, Johan Prasetyo, Yuni Kurniati. Advanced Materials Research, 1179 , 2024. doi: 10.4028/p-0Ev4BT
  2. Insight on açaí seed biomass economy and waste cooking oil: Eco-sorbent castor oil-based

    Larissa S. Martins, Nycolle G.S. Silva, Amanda Maria Claro, Nayara C. Amaral, Hernane S. Barud, Daniella R. Mulinari. Journal of Environmental Management, 293 , 2021. doi: 10.1016/j.jenvman.2021.112803
  3. Development of high free fatty acid crude palm oil as a biodegradable electrical liquid insulator as an alternative to mineral oil-based insulators

    Muhamad Mustangin, Bambang Purwantana, Chusnul Hidayat, Radi. Cleaner Engineering and Technology, 18 , 2024. doi: 10.1016/j.clet.2023.100712
  4. Pre-treatment of waste cooking oil by combined activated carbon adsorption and acid esterification for biodiesel synthesis via two-stage transesterification

    Siew Fan Wong, Angnes Ngieng Tze Tiong, Yun Huang Chin. Biofuels, 14 (9), 2023. doi: 10.1080/17597269.2023.2196804
  5. Technological Advancement for Efficiency Enhancement of Biodiesel and Residual Glycerol Refining: A Mini Review

    Nurhani Fatihah Jariah, Mohd Ali Hassan, Yun Hin Taufiq-Yap, Ahmad Muhaimin Roslan. Processes, 9 (7), 2021. doi: 10.3390/pr9071198
  6. Enzymes, In Vivo Biocatalysis, and Metabolic Engineering for Enabling a Circular Economy and Sustainability

    Pattarawan Intasian, Kridsadakorn Prakinee, Aisaraphon Phintha, Duangthip Trisrivirat, Nopphon Weeranoppanant, Thanyaporn Wongnate, Pimchai Chaiyen. Chemical Reviews, 121 (17), 2021. doi: 10.1021/acs.chemrev.1c00121
  7. PALM KERNEL SHELL ASH: THE EFFECT OF WEIGHT AND STIRRING DURATION ON WASTE PALM COOKING OIL QUALITY

    Lidya Novita, Yuliana Arsil, Iswadi Idris. Jurnal Kimia Riset, 8 (1), 2023. doi: 10.20473/jkr.v8i1.40817
  8. Carbon material@Chitosan composite as catalyst on the synthesis of FAME from used-cooking oil with electrocatalytic process

    Rudy Syah Putra, Yudi Antono, Kharis Pratama. Journal of Physics: Conference Series, 877 , 2017. doi: 10.1088/1742-6596/877/1/012063
  9. A physics constrained methodology for the life cycle assessment of sustainable aviation fuel production

    Liam Anthony Mannion, Aron Bell, Tiarnán Watson-Murphy, Mark Kelly, Mohammad Reza Ghaani, Stephen Dooley. Biomass and Bioenergy, 185 , 2024. doi: 10.1016/j.biombioe.2024.107169
  10. Used cooking oil catalytic cracking using Cr-charcoal ion-exchanged catalyst

    Nazarudin, Ulyarti, O Alfernando, S Fitri. Journal of Physics: Conference Series, 1567 (2), 2020. doi: 10.1088/1742-6596/1567/2/022031
  11. Assessment of degumming and bleaching processes for used cooking oils upgrading into oleochemical feedstocks

    Luz Angela Rincón, Juliana Cárdenas Ramírez, Alvaro Orjuela. Journal of Environmental Chemical Engineering, 9 (1), 2021. doi: 10.1016/j.jece.2020.104610
  12. The effect of used cooking oil composition on the specific CO2e emissions embodied in HEFA‐SPK production

    Liam A. Mannion, Conor Redington, Mark Kelly, Aron Bell, Stephen Dooley. Biofuels, Bioproducts and Biorefining, 18 (4), 2024. doi: 10.1002/bbb.2653
  13. Catalytic cracking of used cooking oil using Chromium impregnated charcoal (Cr-charcoal) catalyst

    Nazarudin, I G Prabasari, Ulyarti, Susilawati, A Oktadio. Journal of Physics: Conference Series, 1567 (2), 2020. doi: 10.1088/1742-6596/1567/2/022021
  14. Generating Organic Liquid Products from Catalytic Cracking of Used Cooking Oil over Mechanically Mixed Catalysts

    Khajornsak Onlamnao, Sanphawat Phromphithak, Nakorn Tippayawong. International Journal of Renewable Energy Development, 9 (2), 2020. doi: 10.14710/ijred.9.2.159-166
  15. Purification of Biodiesel Using Activated Carbon Produced from Cocoa Pod Husk

    Devita Rachmat, Aprillia D. Agustin, Doty D. Risanti, Ir. Sunarno, Agus Pulung Sasmito, Liem Peng Hong. E3S Web of Conferences, 42 , 2018. doi: 10.1051/e3sconf/20184201012
  16. A promising nanostructured bimetallic catalyst for the production of second‐generation biodiesel: reuse and stability study

    Edgar M. Sánchez Faba, Gabriel O. Ferrero, Griselda A. Eimer. Chemistry – An Asian Journal, 17 (22), 2022. doi: 10.1002/asia.202200755
  17. Waste cooking oil transesterification by sulfonated polyphenylsulfone catalytic membrane: Characterization and biodiesel production yield

    Emmanuelle Gómez-Trejo-López, María Ortencia González-Díaz, Manuel Aguilar-Vega. Renewable Energy, 182 , 2022. doi: 10.1016/j.renene.2021.11.003
  18. Waste Cooking Oil as Eco-Friendly Rejuvenator for Reclaimed Asphalt Pavement

    Noemi Bardella, Manuela Facchin, Eleonora Fabris, Matteo Baldan, Valentina Beghetto. Materials, 17 (7), 2024. doi: 10.3390/ma17071477
  19. Bioenergy knowledge, perception and attitude among students at Jambi state senior high school

    Nazarudin, M P H Hasibuan, B Haryadi, Nurhayati, Ulyarti, Hadiyanto. Journal of Physics: Conference Series, 1816 (1), 2021. doi: 10.1088/1742-6596/1816/1/012117

Last update: 2024-12-02 09:34:20

  1. Carbon material@Chitosan composite as catalyst on the synthesis of FAME from used-cooking oil with electrocatalytic process

    Rudy Syah Putra, Yudi Antono, Kharis Pratama. Journal of Physics: Conference Series, 877 , 2017. doi: 10.1088/1742-6596/877/1/012063
  2. Used cooking oil catalytic cracking using Cr-charcoal ion-exchanged catalyst

    Nazarudin, Ulyarti, O Alfernando, S Fitri. Journal of Physics: Conference Series, 1567 (2), 2020. doi: 10.1088/1742-6596/1567/2/022031
  3. Assessment of degumming and bleaching processes for used cooking oils upgrading into oleochemical feedstocks

    Luz Angela Rincón, Juliana Cárdenas Ramírez, Alvaro Orjuela. Journal of Environmental Chemical Engineering, 9 (1), 2021. doi: 10.1016/j.jece.2020.104610
  4. Catalytic cracking of used cooking oil using Chromium impregnated charcoal (Cr-charcoal) catalyst

    Nazarudin, I G Prabasari, Ulyarti, Susilawati, A Oktadio. Journal of Physics: Conference Series, 1567 (2), 2020. doi: 10.1088/1742-6596/1567/2/022021
  5. Generating Organic Liquid Products from Catalytic Cracking of Used Cooking Oil over Mechanically Mixed Catalysts

    Khajornsak Onlamnao, Sanphawat Phromphithak, Nakorn Tippayawong. International Journal of Renewable Energy Development, 9 (2), 2020. doi: 10.14710/ijred.9.2.159-166
  6. Purification of Biodiesel Using Activated Carbon Produced from Cocoa Pod Husk

    Devita Rachmat, Aprillia D. Agustin, Doty D. Risanti, Ir. Sunarno, Agus Pulung Sasmito, Liem Peng Hong. E3S Web of Conferences, 42 , 2018. doi: 10.1051/e3sconf/20184201012
  7. Utilization of cacao peel waste to K 2 O heterogeneous catalyst in biodiesel synthesis by waste cooking oil: Effect of catalyst calcination temperature

    Sinaga M.. IOP Conference Series: Earth and Environmental Science, 127 (1), 2018. doi: 10.1088/1755-1315/205/1/012031