DOI: https://doi.org/10.14710/ijred.3.3.188-192

Synthesis of Trimethylolpropane Esters of Calophyllum Methyl Esters : Effect of Temperature and Molar Ratio

1Department of Chemical Engineering , Indonesia

2Jayabaya University, Indonesia

3Departemen of Agroindustrial Technology, Faculty of Agriculture Engineering and Technology, Bogor Agricultural University, Bogor, Indonesia, Indonesia

Published: 15 Oct 2014.
Editor(s):

Citation Format:
Abstract

Trimethylolpropane esters were synthesized by transesterification of calophyllum methyl esters and trimethylolpropane using a calcium oxide as the catalyst. The results showed that the optimal reaction conditions (temperature: 130 0C, reaction time: 5 h, reactant molar ratio: 3.9:1, catalyst amount 3%w/w, and formed  trimethylolpropane ester of 79.0% were obtained. The basic physicochemical properties of the trimethylolpropane esters were the following : kinematic viscosities of 56.40 cSt and 8.8 cSt at 40 0C and 100 0C,  viscosity index 193, flash point 218 0C and pour point -3 0C. So Methyl esters of fatty acids of would callophylum  methyl ester is good raw material for the synthesis of lubricating oils.

Fulltext View|Download
Keywords: callophylum methyl ester, transesterification; calcium oxide; trimethylolpropane esters

Article Metrics:

Article Info
Section: Original Research Article
Language : EN
Recent articles
Synthesis of Trimethylolpropane Esters of Calophyllum Methyl Esters : Effect of Temperature and Molar Ratio Thermo-economic Optimization of Solar Assisted Heating and Cooling (SAHC) System Thermal effects investigation on electrical properties of silicon solar cells treated by laser irradiation More recent articles
Most cited articles
Determinants of CO2 Emissions in Emerging Markets: An Empirical Evidence from MINT Economies Energy Efficient Dryer with Rice Husk Fuel for Agriculture Drying Modeling and Design of Azimuth-Altitude Dual Axis Solar Tracker for Maximum Solar Energy Generation On the Eddy Current Losses in Metallic Towers Ultrasound Assisted Esterification of Rubber Seed Oil for Biodiesel Production More cited articles
  1. Castro, W., Perez, J.M., Erhan, S.Z., Caputo, F. (2006) A study of the oxidation and wear properties of vegetable oils: soybean oil without additives. J. Am. Oil Chem. Soc. 83, 47–52
  2. Doll, K.M., Sharma, B.K., Erhan, S.Z. (2007) Synthesis of branched methyl hydroxyl strearates including an ester from bio-based levulinic acid. Ind. Eng. Chem. Res. 46, 3513–3519
  3. Lathi, S.P. & Mattiason, B. (2006) Green Approach for the Preparation of Biodegradable Lubricant Base Stock from Epoxidized Vegetable Oil. Journal of Applied Catalysis B: Environmental 69: 207-212
  4. Leung, D.Y.C., Wu, X., Leung, M.K.H. (2010) A review of biodiesel production usingcatalyzed transesterification. Appl. Energy 87, 1083–1095
  5. Gryglewicz, S., Piechocki, W., Gryglewicz, G. (2003) Preparation of polyol esters based on vegetable and animal fats. Bioresour. Technol. 87, 35–39
  6. Phani K. Sripada, Rajesh V. Sharma, Ajay K. Dalai. (2013) Comparative study of tribological properties oftrimethylolpropane-based biolubricants derived frommethyl oleate and canola biodiesel, Journal Industrial Crops and Products 50, 95– 103
  7. Salimon J, N. Salih, E. Yousif (2010) Improvement of pour point and oxidative stability of synthetic ester basestocks for biolubricant applications, Arab. J. Chem. 5, 193–200
  8. Metzger, J.O. (2009) Fats and oils as renewable feedstock for chemistry. Eur. Lipid Sci. Technol. 111, 865–876
  9. Nagendramma, P., Kaul, S. (2012) Development of ecofriendly/biodegradable lubri-cants: an overview. Renew. Sustain. Energy Rev. 16, 764–774
  10. Uosukainen, E., Linko, Y.-Y., Lamsa, M., Tervakangas, T., Linko, P. (1998) Transesterifi-cation of trimethylolpropane and rapeseed oil methyl ester to environmentallyacceptable lubricants. J. Am. Oil Chem. Soc. 75, 1557–1563
  11. Willing A. (2001) Lubricants based on renewable resources – an environmentally compatible alternative to mineral oil products. Chemosphere ;43:89–98
  12. Robiah, Y., Fakhru’l-Razi, A., Ooi, T.L., Iyuke, S.E dan Idris, A. 2003a. Development of Optimum Synthesis Method for Transesterification of Palm Oil Methyl Esters and Trimethylolpropane to Environmentally Acceptable Palm Oil- Based Lubricant. Journal of Oil Palm Research 15 (2): 35-41
  13. Robiah, Y., Fakhru’l-Razi, A., Ooi, T.L., Iyuke, S.E dan Idris, A. 2003b. Preparation and Characterization of Trimethylolpropane Esters from Palm Kernel Methyl Esters. Journal of Oil Palm Research 15 (2): 42-49

Last update:

  1. Kinetics and parametric study of transesterification synthesis of biolubricant from melon-based methyl esters

    M.C. Menkiti, H.C. Anaehobi, O.D. Onukwuli. Biofuels, 7 (5), 2016. doi: 10.1080/17597269.2016.1163212

  2. An environmentally friendly production ofester‐biolubricantfrom oleic acid

    F. Javier Ramos, Juan Carlos de Haro, Juan Francisco Rodríguez, Ángel Pérez, Manuel Carmona. Biofuels, Bioproducts and Biorefining, 16 (6), 2022. doi: 10.1002/bbb.2401

  3. Intensification of biolubricant synthesis from waste cooking oil using tetrahydrofuran as co-solvent

    T W Putra, R Hardiansyah, M R Lubis, M D Supardan. IOP Conference Series: Materials Science and Engineering, 845 (1), 2020. doi: 10.1088/1757-899X/845/1/012009

Last update: 2025-07-14 07:32:15

  1. Kinetics and parametric study of transesterification synthesis of biolubricant from melon-based methyl esters

    M.C. Menkiti, H.C. Anaehobi, O.D. Onukwuli. Biofuels, 7 (5), 2016. doi: 10.1080/17597269.2016.1163212

  2. Intensification of biolubricant synthesis from waste cooking oil using tetrahydrofuran as co-solvent

    T W Putra, R Hardiansyah, M R Lubis, M D Supardan. IOP Conference Series: Materials Science and Engineering, 845 (1), 2020. doi: 10.1088/1757-899X/845/1/012009