DOI: https://doi.org/10.14710/ijred.4.1.32-38

Characterization and Performance Test of Palm Oil Based Bio-Fuel Produced Via Ni/Zeolite-Catalyzed Cracking Process

1Department of Chemistry, Semarang State University Bld. D6 level 2 Kampus Sekaran Gunungpati Semarang 50229, Indonesia

2Phone: +61452491411, Indonesia

Published: 15 Feb 2015.
Editor(s):

Citation Format:
Abstract
Catalytic cracking process of palm oil into bio-fuel using Ni/zeolite catalysts (2-10% wt. Ni) at various reaction temperatures (400-500oC) in a flow-fixed bed reactor system has been carried out. Palm oil was pre-treated to produce methyl ester of palm oil as feedstock in the catalytic cracking reactions. The Ni/zeolite catalysts were prepared by wetness impregnation method using Ni(NO3)2.6H2O as the precursor. The products were collected and analysed using GC, GC-MS, and calorimeter. The effects of process temperatures and Ni content in Ni/zeolite have been studied. The results showed that Ni-2/zeolite could give a yield of 99.0% at 500oC but only produced gasoline fraction of 18.35%. The physical properties of bio-fuel produced in this condition in terms of density, viscosity, flash point, and specific gravity were less than but similar to commercial fuel. The results of performance test in a 4-strike engine showed that the mixture of commercial gasoline (petrol) and bio-fuel with a ratio of 9:1 gave similar performance to fossil-based gasoline with much lower CO and O2 emissions and more efficient combustion
Fulltext View|Download
Keywords: bio-fuel, characterization, Ni/zeolite, palm oil, performance

Article Metrics:

Article Info
Section: Original Research Article
Language : EN
Recent articles
Direct Ethanol Production from Breadfruit Starch (Artocarpus communis Forst.) by Engineered Simultaneous Saccharification and Fermentation (ESSF) using Microbes Consortium Performance and Feasibility Analysis of a Grid Interactive Large Scale Wind/PV Hybrid System based on Smart Grid Methodology Case Study South Part – Jordan Potential of Wind Energy in Albania and Kosovo: Equity Payback and GHG Reduction of Wind Turbine Installation More recent articles
Most cited articles
Phase Change Material on Augmentation of Fresh Water Production Using Pyramid Solar Still Wind Resource Assessment in Abadan Airport in Iran Effects of turbulence models and grid densities on computational accuracy of flows over a vertical axis wind turbine Enhancement and Optimization Mechanisms of Biogas Production for Rural Household Energy in Developing Countries: A review The Social Aspects and Public Acceptance of Biomass Giving the Example of a Hungarian Region More cited articles
  1. Choo, Y.M., Ma, A.N., (1996), Production technology of methyl esters from palm and palm kernel oils, PORIM Technology Bulletin 18
  2. Demirbas, A., (2003), Fuel Conversional Aspect of Palm Oil and Sunflower, Energy Sources Journal, 25(5): 457-466
  3. Handoko, D.S.P., (2006), Mekanisme Reaksi Konversi Katalitik Jelantah menjadi Senyawa Fraksi Bahan Bakar Cair dengan Katalis Ni/H5-NZA dan Reaktor Flow-Fixed Bed, Jurnal Ilmu Dasar, 7(1): 42-51
  4. Idem, R.O., Katikaneni, S.P.R. dan Bakhsi, N.N., (1997), Catalytic Conversion of Canola oil to Fuels and Chemicals: Role of Catalyst Acidity, Basicity and Shape Selectivity on Product Distribution, Fuel ProcessTech., 51: 101-125
  5. Kadarwati, S. dan Wahyuni, S., (2011), Preparasi, Karakterisasi, dan Uji Performa Katalis Ni/Zeolit dalam Proses Catalytic Cracking Minyak Sawit menjadi Bio-fuel, Proceeding Seminar Nasional Kimia dan Pendidikan Kimia III, ISBN 978-979-1533-85-0, p. 297-308
  6. Kloprogge, J.T., Doung Loc V., dan Frost, R.L., (2005), A Review of The Synthesis and Characterization of Pillared Clays and Related Porous Material for Cracking of Vegetable Oil to Produce Biofuel, Environmental Geology, 47(7): 967-981
  7. Leng, T.Y., Mohamed, A.R., Bhatia, S., (1999), Catalytic Conversion of Palm Oil to Fuels and Chemicals, The Canadian Journal of Chemical Engineering, 77: 156-162
  8. Nasikin, M., Susanto, B.H., Hirsaman, M.A., dan Wijanarko, A., (2009), Bio-gasoline from Palm Oil by Simultaneous Cracking and Hydrogenation Reaction over NiMo/zeolite Catalyst, World Applied Sciences Journal, 5 (Special Issue for Environment): 74-79
  9. Sang, O.Y., (2003), Biofuel Production From Catalytic Cracking of Palm Oil, Energy Sources Journal, (25)9, pp. 859-869
  10. Siregar, T.B. dan Amin, N.A.S., (2006), Catalytic Cracking Of Palm Oil To Gasoline Over Pretreated Cu-ZSM-5, Jurnal Teknologi, 44(F): 69–82
  11. Siswanto, D.Y., Salim, G.W., Wibisono, N., Hindarso, H., Sudaryanto, Y., dan Ismadji, S., (2008), Gasoline Production From Palm Oil Via Catalytic Cracking Using MCM-41: Determination Of Optimum Condition, ARPN Journal of Engineering and Applied Sciences, 3(6): 42-46
  12. Twaiq, F.A., Zabidi, N.A.M. dan Bhatia, S., (1999), Catalytic Conversion of Palm Oil to Hydrocarbons: Performance of Various Zeolite Catalysts, Industrial and Engineering Chemistry Research, 38(9): 3230-3237
  13. Twaiq, F.A., Zabidi, N.A.M. dan Bhatia, S., (2003), Liquid Hydrocarbon Fuels From Palm Oil By Catalytic Cracking over Aluminosilicate Mesoporous Catalyst With Various Si/Al Ratios, Microporous and Mesoporous Materials,64(1-3): 95-108
  14. Twaiq, F.A., Zabidi, N.A.M. Mohamed, A.R. dan Bhatia, S., (2003), Catalytic Conversion of Palm Oil Over Meso Porous Aluminosilicate MCM 41 for The Production of Liquid Hydrocarbon Fuel, Fuel Processing Technology, 84(1-3): 105–120
  15. Wijanarko, A., Mawardi, D.A., dan Nasikin, M., (2006), Produksi Bio-gasoline dari Minyak Sawit melalui Reaksi Perengkahan Katalitik dengan Katalis γ-Alumina, Makara Teknologi, 10(2), pp. 51-60
  16. Yakovlev, V.A., Khromova, S.A., Sherstyuk, O.V., Dundich, V.O., Ermakov, D.Y., Novopashina, V.M., Lebedev, M.Y., Bulavchenko, O., Parmon, V.N., 2009, Development of new catalytic systems for upgraded bio-fules production from bio-crude-oil and biodiesel, Catal. Today, 144: 362-366

Last update:

  1. Catalytic cracking of jatropha oil into biofuel over hierarchical zeolite supported NiMo catalyst

    Isalmi Aziz, Tri Retnaningsih, Dhika Gustama, Nanda Saridewi, Lisa Adhani, Adip A. Dwiatmoko. 4TH INTERNATIONAL SEMINAR ON CHEMISTRY, 2349 , 2021. doi: 10.1063/5.0051737

  2. Hydrocracking of Crude Palm Oil over Bimetallic Oxide NiO-CdO/biochar Catalyst

    Allwar Allwar, Rina Maulina, Tatang Shabur Julianto, Annisa Ayu Widyaningtyas. Bulletin of Chemical Reaction Engineering & Catalysis, 17 (2), 2022. doi: 10.9767/bcrec.17.2.14074.476-485

  3. Esterification of Bio-Oil Produced from Sengon (Paraserianthes falcataria) Wood Using Indonesian Natural Zeolites

    Sri Kadarwati, Evalisa Apriliani, Riska Nurfirda Annisa, Jumaeri Jumaeri, Edy Cahyono, Sri Wahyuni. International Journal of Renewable Energy Development, 10 (4), 2021. doi: 10.14710/ijred.2021.35970

  4. Catalytic Cracking of Crude Biodiesel into Biohydrocarbon Using Natural Zeolite Impregnated Nickel Oxide Catalyst

    Isalmi Aziz, Edra Aditya Fhilipia Ardine, Nanda Saridewi, Lisa Adhani. Jurnal Kimia Sains dan Aplikasi, 24 (7), 2021. doi: 10.14710/jksa.24.7.222-227

  5. Generating Organic Liquid Products from Catalytic Cracking of Used Cooking Oil over Mechanically Mixed Catalysts

    Khajornsak Onlamnao, Sanphawat Phromphithak, Nakorn Tippayawong. International Journal of Renewable Energy Development, 9 (2), 2020. doi: 10.14710/ijred.9.2.159-166

  6. Processing of Used Beveraged Waste for Production of Hydroge Gas with Electrolysis Process Using NaOH Catalyst

    Widayat, Mochammad Faiq Yumna, Muhammad Hilmazar, Hantoro satriadi, Aji Prasetyaningrum, B. Warsito, Sudarno, T. Triadi Putranto. E3S Web of Conferences, 202 , 2020. doi: 10.1051/e3sconf/202020208001

Last update: 2024-11-05 11:17:49

  1. Pyrolysis of palm oil using zeolite catalyst and characterization of the boil-oil

    Abdullah, Meileni Apriyanti, Sunardi, Uripto Trisno Santoso, Ahmad Budi Junaidi, Dessy Aditiya, Utami Irawati. Green Processing and Synthesis, 8 (1), 2019. doi: 10.1515/gps-2019-0035

  2. Generating Organic Liquid Products from Catalytic Cracking of Used Cooking Oil over Mechanically Mixed Catalysts

    Khajornsak Onlamnao, Sanphawat Phromphithak, Nakorn Tippayawong. International Journal of Renewable Energy Development, 9 (2), 2020. doi: 10.14710/ijred.9.2.159-166

  3. Processing of Used Beveraged Waste for Production of Hydroge Gas with Electrolysis Process Using NaOH Catalyst

    Widayat, Mochammad Faiq Yumna, Muhammad Hilmazar, Hantoro satriadi, Aji Prasetyaningrum, B. Warsito, Sudarno, T. Triadi Putranto. E3S Web of Conferences, 202 , 2020. doi: 10.1051/e3sconf/202020208001

  4. Hycrodracking of coconut oil into gasoline fraction using Ni/modified natural zeolite catalyst

    Salim I.. International Journal of ChemTech Research, 9 (4), 2016.