Sintesis dan Karakterisasi Senyawa Kompleks Zn(II)-8-Hidroksikuinolin

Eka Sulistya Hermawati; Suhartana Suhartana; Taslimah Taslimah

doi:10.14710/jksa.19.3.94-98

DOI: https://doi.org/10.14710/jksa.19.3.94-98

Sintesis dan Karakterisasi Senyawa Kompleks Zn(II)-8-Hidroksikuinolin

Eka Sulistya Hermawati, Suhartana Suhartana

, Taslimah Taslimah

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Indonesia

Published: 1 Dec 2016.

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Abstract

Senyawa koordinasi adalah senyawa yang terbentuk karena adanya ikatan antara ligan dengan ion pusat. Penelitian ini dilakukan dengan tujuan memperoleh senyawa kompleks Zn(II)-8-Hidroksikuinolin dengan pelarut asetonitril, metanol dan etanol serta menentukan karakteristik dari produk yang diperoleh. Metode penelitian ini dilakukan dengan mencampurkan larutan ZnCl₂dan larutan 8-Hidroksikuinolin disertai pengadukan dengan menggunakan magnetik stirrer selama 60 menit. Karakterisasi uji dilakukan dengan menggunakan UV-Vis, FTIR dan AAS. Dari sintesis kompleks Zn(II)-8-Hidroksikuinolin dalam pelarut asetonitril, metanol dan etanol, diperoleh rendemen sebesar 73,07 % ; 63,46% ; dan 48,67%, dengan panjang gelombang maksimum berturut-turut sebesar 319,5 nm ; 313 nm ; and 320 nm. Adanya ikatan Zn-N teridentifikasi pada pita serapan pada kisaran 439,79 cm^-1 hingga 513,09 cm^-1, sedangkan ikatan Zn-O teridentifikasi pada pita serapan pada kisaran 542,98 cm^-1 hingga 543,95 cm^-1. Dapat disimpulkan bahwa Zn(II) terkoordinasi dengan ligan 8-Hidroksikuinolin membentuk endapan senyawa kompleks Zn(II)-8-Hidroksikuinolin berwarna kuning.

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Keywords: Sintesis; Senyawa kompleks; 8-Hidroksikuinolin

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Section: Research Articles

Language : ID

In Vol 19, No 3 (2016): Volume 19 Issue 3 Year 2016

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