Effect of Acid on Natural Zeolite Dealumination on Indigo Carmine Adsorption Capability

Nanik Sulistyowati; Sriyanti Sriyanti; Adi Darmawan

doi:10.14710/jksa.21.2.102-106

DOI: https://doi.org/10.14710/jksa.21.2.102-106

Effect of Acid on Natural Zeolite Dealumination on Indigo Carmine Adsorption Capability

Nanik Sulistyowati, Sriyanti Sriyanti

, Adi Darmawan

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Indonesia

Published: 30 Apr 2018.

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Abstract

Modifying natural zeolite with dealumination using H₂SO₄ and HCl, and its application to adsorb indigo carmine has been performed. Dealumination was carried out by reacting a natural zeolite with a mixture of KMnO₄-H₂SO₄ and a mixture of KMnO₄-HCl then refluxed for 5 hours followed by washing with demineralized water until a neutral pH was obtained and dried for 12 hours at 80°C. Dealuminated zeolites were then characterized by XRD, FTIR and Si/Al ratio measurements. Dealuminated zeolite was then used to adsorb indigo carmine in a batch-shaker system for 30 min with concentration variation XRD diffraction shows that natural zeolite and dealuminated zeolite contain modernit minerals. Dealumination increased the Si/Al ratio from 0.935 to 2.075 and 7.912 which meant that dealumination was successful. The indigo carmine adsorption result showed that zeolite adsorption capacity II> zeolite I> natural zeolite. FTIR data showed that there was no change of zeolite structure before and after adsorption

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Keywords: zeolite; dealumination; H2SO4; HCl; adsorption; indigo carmine

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Section: Research Articles

Language : EN

In Vol 21, No 2 (2018): Volume 21 Issue 2 Year 2018

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