DOI: https://doi.org/10.14710/jksa.22.6.263-268

Potential Adsorption of Heavy Metal Ions by Eugenol Compounds and Derivatives through Ion Imprinted Polymer

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Jl. Prof. Soedarto, SH., Tembalang, Semarang, Indonesia

Received: 27 Feb 2019; Revised: 2 Oct 2019; Accepted: 21 Oct 2019; Available online: 30 Nov 2019; Published: 30 Nov 2019.
Open Access Copyright 2019 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

Citation Format:
Cover Image
Abstract

Research on the potential of Ion Imprinted Polymer (IIP) selective adsorption of heavy metals using eugenol compounds and their derivatives has been carried out. Isolation and synthesis of eugenol derivatives with metal selective active groups and their use as selective metal carriers have been carried out with satisfactory results. Carrier effectiveness can still be improved by methods that focus on the target molecule recognition model. This adsorption method is called Ion Imprinted Polymer (IIP). The main components of IIP are functional monomers, crosslinkers, and target molecules. The use of acrylamide and its derivatives as functional monomers is useful with a lot of success achieved but also invites danger because it includes carcinogenic substances, a nerve poison, and so on. Moreover, the N group, which is an active acrylamide group, and its derivatives are only selective towards borderline metals (HSAB theory). Alternatives that are safe and can increase their selectivity are therefore needed. Eugenol, with its three potential functional groups, is believed to be able to replace the function of acrylamide and its derivatives that can even increase the effectiveness of IIP. The purpose of this study is to determine the potential of eugenol derivatives as selective adsorbents through the IIP method. This synthesis of IIP involved the use of basic ingredients of eugenol and its derivatives (polyeugenol, EOA, polyacetate). Each base material is contacted with a metal template then crosslinked with three kinds of crosslinking agents, namely EGDMA, DVB, and bisphenol. IIP is formed after the metal template is released using acid/HCl. The outcomes obtained demonstrate that the IIP method is able to increase the metal adsorption capacity and that the IIP method for metals is largely determined by the release of metals, which will form a hole for metal entry through adsorption. Poly-Cd-DVB, Eug-Cr-DVB, Poly-Cu-bisphenol, Polyacetate -Cr-DVB are polymer materials that have the potential to make up an IIP.

Fulltext View|Download
Keywords: selective adsorption; Ion Imprinted Polymer; eugenol
Funding: Ministry of Research and Technology of Higher Education, Republic of Indonesia

Article Metrics:

Article Info
Section: Research Articles
Language : EN
Recent articles
Study of Equilibrium and Kinetics of Pb(II) in Solution Using Persimmon Tannin Gel as an Adsorbent Use of Microwave Radiation for Activating Carbon from Rice Husk Using ZnCl2 Activator Effect of Sodium Periodate on the Adsorption Capacity of Silica-Lignin from Rice Husk on Chromium(VI) More recent articles
Most cited articles
Synthesis of 4-Hydroxy-2-Methylchalcone from meta-Cresol Formilation Product and Its Activities as an Antibacteria Isolasi, Identifikasi Minyak Atsiri Fuli Pala (Myristica fragrans) dan Uji Aktivitas Sebagai Larvasida Analisis Pangan: Penentuan Angka Peroksida dan Asam Lemak Bebas pada Minyak Kedelai dengan Variasi Menggoreng Profil Kandungan Protein dan Tekstur Tahu Akibat Penambahan Fitat pada Proses Pembuatan Tahu Studi Filogeni dan Uji Potensi Bioremediasi serta Enzim Termostabil Ekstraseluler Isolat Geobacillus sp. dari Sumber Air Panas Gedong Songo More cited articles
  1. Chairil Anwar and Warsito Hardjosoedirdjo, The Conversion of Eugenol into More Valuable Substances, Chemistry Department, Gadjah Mada University, Yogyakarta
  2. Ernest Guenther, The Essential Oils: Volume One : History, Origin in Plants, Production, Read Books, 2007
  3. Ngadiwiyana Ngadiwiyana, Polimerisasi Eugenol Dengan Katalis Asam Sulfat Pekat, Jurnal Kimia Sains dan Aplikasi, 8, 2, (2005) 43-47 https://doi.org/10.14710/jksa.8.2.43-47
  4. Desi Suci Handayani, Sintesis Poli (Eugenol Sulfonat) dan Aplikasinya Sebagai Katalis Asam Reaksi Siklisasi Sitronelal, Chemistry Department, Gadjah Mada University, Yogyakarta
  5. M. Cholid Djunaidi, Retno A. Lusiana, Pratama J. Wibawa, Dwi Siswanta and Jumina Jumina, Sintesis Turunan Polieugenol Sebagai Carrier Bagi Recovery Logam Berat Dengan Teknik Membran Cair, Reaktor, 13, 1, (2010) 16-23 https://doi.org/10.14710/reaktor.13.1.16-23
  6. Retno Ariadi Lusiana and Dwi Siswanta, Pemanfaatan Oktil Eugeniloksi Etanoat Hasil Sintesis sebagai Plasticizer Membran Polimer Cair Elektroda Selektif Ion, Jurnal Kimia Sains dan Aplikasi, 5, 3, (2002) 11-14 https://doi.org/10.14710/jksa.5.3.11-14
  7. Muhammad Cholid Djunaidi, Pratama Jujur Wibawa and Ratna Hari Murti, Synthesis of A Novel Carrier Compound Thiazoethyl Methyl Eugenoxyacetate from Eugenol and Its Use in the Bulk Liquid Membrane Technique, Indonesian Journal of Chemistry, 18, 1, (2018) 121-126 https://doi.org/10.22146/ijc.25075
  8. F. G. Tamayo, E. Turiel and A. Martín-Esteban, Molecularly imprinted polymers for solid-phase extraction and solid-phase microextraction: Recent developments and future trends, Journal of Chromatography A, 1152, 1, (2007) 32-40 https://doi.org/10.1016/j.chroma.2006.08.095
  9. Paraskevi Parmpi and Peter Kofinas, Biomimetic glucose recognition using molecularly imprinted polymer hydrogels, Biomaterials, 25, 10, (2004) 1969-1973 https://doi.org/10.1016/j.biomaterials.2003.08.025
  10. Furqan M. Fazal and David E. Hansen, Glucose-specific poly(allylamine) hydrogels—A reassessment, Bioorganic & Medicinal Chemistry Letters, 17, 1, (2007) 235-238 https://doi.org/10.1016/j.bmcl.2006.09.054
  11. Tian-Ying Guo, Yong-Qing Xia, Guang-Jie Hao, Bang-Hua Zhang, Guo-Qi Fu, Zhi Yuan, Bing-Lin He and John F. Kennedy, Chemically modified chitosan beads as matrices for adsorptive separation of proteins by molecularly imprinted polymer, Carbohydrate Polymers, 62, 3, (2005) 214-221 https://doi.org/10.1016/j.carbpol.2005.03.012
  12. T. Y. Guo, Y. Q. Xia, G. J. Hao, M. D. Song and B. H. Zhang, Adsorptive separation of hemoglobin by molecularly imprinted chitosan beads, Biomaterials, 25, 27, (2004) 5905-5912 https://doi.org/10.1016/j.biomaterials.2004.01.032
  13. Prasad Taranekar, Chengyu Huang and Rigoberto C. Advincula, Pinacolyl methyl phosphonate (PMP) detection by molecularly imprinted polymers (MIP): A labile covalent bonding approach, Polymer, 47, 19, (2006) 6485-6490 https://doi.org/10.1016/j.polymer.2006.07.025
  14. Haruyo Sambe, Kaori Hoshina and Jun Haginaka, Molecularly imprinted polymers for triazine herbicides prepared by multi-step swelling and polymerization method: Their application to the determination of methylthiotriazine herbicides in river water, Journal of Chromatography A, 1152, 1, (2007) 130-137 https://doi.org/10.1016/j.chroma.2006.09.003
  15. M. N. Mohamad Ibrahim, C. S. Sipaut and N. N. Mohamad Yusof, Purification of vanillin by a molecular imprinting polymer technique, Separation and Purification Technology, 66, 3, (2009) 450-456 https://doi.org/10.1016/j.seppur.2009.02.010
  16. Mark E. Byrne and Vishal Salian, Molecular imprinting within hydrogels II: Progress and analysis of the field, International Journal of Pharmaceutics, 364, 2, (2008) 188-212 https://doi.org/10.1016/j.ijpharm.2008.09.002
  17. Dipali Rahangdale and Anupama Kumar, Acrylamide grafted chitosan based ion imprinted polymer for the recovery of cadmium from nickel-cadmium battery waste, Journal of Environmental Chemical Engineering, 6, 2, (2018) 1828-1839 https://doi.org/10.1016/j.jece.2018.02.027
  18. Long Xu, Yun-An Huang, Qiu-Jin Zhu and Chun Ye, Chitosan in Molecularly-Imprinted Polymers: Current and Future Prospects, International Journal of Molecular Sciences, 16, 8, (2015) 18328-18347 https://doi.org/10.3390/ijms160818328
  19. Ahmad Reza Bagheri, Maryam Arabi, Mehrorang Ghaedi, Abbas Ostovan, Xiaoyan Wang, Jinhua Li and Lingxin Chen, Dummy molecularly imprinted polymers based on a green synthesis strategy for magnetic solid-phase extraction of acrylamide in food samples, Talanta, 195, (2019) 390-400 https://doi.org/10.1016/j.talanta.2018.11.065
  20. Gengliang Yang, Haiyan Liu, Manman Wang, Shubin Liu and Yi Chen, Chromatographic characterization and solid-phase extraction on diniconazole-imprinted polymers stationary phase, Reactive and Functional Polymers, 66, 5, (2006) 579-583 https://doi.org/10.1016/j.reactfunctpolym.2005.10.029
  21. Teguh Wirawan, Ganden Supriyanto and Agoes Soegianto, Preparation of a New Cd(II)-Imprinted Polymer and Its Application to Preconcentration and Determination of Cd(II) Ion from Aqueous Solution by SPE-FAAS, Indonesian Journal of Chemistry, 19, 1, (2019) 97-105 https://doi.org/10.22146/ijc.27703
  22. Agung Abadi Kiswandono, Dwi Siswanta, Nurul Hidayat Aprilita and Sri Juari Santosa, Transport of Phenol Through Inclusion Polymer Membrane (PIM) Using Copoly(Eugenol-DVB) as Membrane Carriers, Indonesian Journal of Chemistry, 12, 2, (2012) 105-112 https://doi.org/10.22146/ijc.21348
  23. Abu Masykur, Sri Juari Santosa, Dwi Siswanta and Jumina Jumina, Synthesis of Pb(II) Imprinted Carboxymethyl Chitosan and the Application as Sorbent for Pb(II) Ion, Indonesian Journal of Chemistry, 14, 2, (2014) 152-159 https://doi.org/10.22146/ijc.21252
  24. S. K. Bajpai and Shatrudhan Jhariya, Selective removal of amikacin from simulated polluted water using molecularly imprinting polymer: A column study, Journal of Macromolecular Science, Part A, 53, 9, (2016) 579-584 https://doi.org/10.1080/10601325.2016.1201754
  25. Muhammad Cholid Djunaidi, Jumina Jumina, Dwi Siswanta and Mathias Ulbricht, Synthesis of Fe Ionic-Imprinted Polyeugenol Using Polyethylene Glycol Diglycidilether as Cross-Linking Agent for Sorption of Fe(III), Indonesian Journal of Chemistry, 15, 3, (2015) 305-314 https://doi.org/10.22146/ijc.21200

Last update:

  1. Gold (Au) selective adsorption using polyeugenol based ionic imprinted polymer with ethylene glycol dimethacrylate crosslink

    M. Cholid Djunaidi, Nor Basid Adiwibawa Prasetya, Didik Setiyo Widodo, Retno Ariadi Lusiana, Pardoyo. THE 14TH JOINT CONFERENCE ON CHEMISTRY 2019, 2237 , 2020. doi: 10.1063/5.0005546

Last update: 2024-04-26 01:31:42

No citation recorded.