DOI: https://doi.org/10.14710/jksa.22.4.112-122

Efek Temperatur, Tekanan dan Waktu Reaksi pada Hidrogenasi Asam Heksadekanoat Menjadi 1-Eksadekanol Menggunakan Katalis Ru-Sn(3,0)/C

Effect of Temperature, Pressure, and Reaction Time on Hydrogenation of Hexadecanoic Acid to 1-Hexadecanol Using a Ru-Sn(3.0)/C Catalyst

1Research Catalyst Group, Department of Chemistry, Lambung Mangkurat University, Indonesia

2Department of Chemistry, Faculty of Mathematics and Natural Sciences, Lambung Mangkurat University, Jl. A. Yani Km 36.0 Banjarbaru 70714, South Kalimantan, Indonesia

3Catalysis for Sustainable Energy and Environment (CATSuRe), Wetland-based Material Research Center, Lambung Mangkurat University, Banjarbaru 70714, South Kalimantan, Indonesia

Received: 11 Mar 2019; Revised: 2 May 2019; Accepted: 16 May 2019; Published: 31 Jul 2019.
Open Access Copyright 2019 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract
Effect of temperature, initial H2 pressure, and reaction time on the selective hydrogenation of hexadecanoate acid to 1-hexadecanol over bimetallic ruthenium-tin supported on carbon (denoted as Ru-Sn(3.0)/C; 3.0 is molar ratio Ru/Sn) has been systematically investigated. Ru-Sn(3.0)/C catalyst was synthesized using a simple hydrothermal method at temperature of 150oC for 24 h followed by reduction with hydrogen at at 400oC and 500°C for 1.5 h. The XRD patterns of reduced Ru-Sn(3.0)/C showed a series diffraction peaks of bimetallic alloy Ru3Sn7 at 2θ = 30.0°; 35.0°; and 41.3° which are recognized as (310), (321), and (411) reflection planes present. The N2-adsorpsion/desorption profiles confirmed that the catalyst structure was microporous and mesoporous sizes with specific surface area (SBET) of 207 m2/g, pore volume (VpBJH) 0.1015 cm3/g, and pore diameter (dpBJH) 1,21 nm. NH3-TPD profile shows that the desorption temperature of 157.1°C was a weak acidity (Bronsted acid site) with amount of acid sites was 0.117 mmol/g. Meanwhile, the desorption temperature of 660.3°C was a strong acidity (Lewis acid site) with amount of acid sites was 0.826 mmol/g. The highest conversion of hexadecanoic acid (86.24%) was achieved at reaction temperature180°C, initial H2 pressure of 5.0 MPa, a reaction time of 6 h in ethanol solvent and afforded yield of hexadecane (0.15%), 1-hexadecanol (4.27%), and ethyl hexadecanoate (81.82%). At reaction temperature of 150°C, H2 of 3.0 MPa, and a reaction time of 18 h, 73.27% of hexadecanoic acid was converted to 1-hexadecanol (0.24%) and ethyl hexadecanoate (73,03%).
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Keywords: Ru-Sn(3.0)/C catalyst; selective hydrogenation; hexadecanoic acid; 1-hexadecanol; ethyl hexadecanoate

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