DOI: https://doi.org/10.14710/jksa.22.6.242-249

Effect of Sodium Periodate on the Adsorption Capacity of Silica-Lignin from Rice Husk on Chromium(VI)

Chemistry Department, Faculty of Mathematics and Science, Universitas Padjadjaran, Indonesia

Received: 6 Aug 2019; Revised: 15 Oct 2019; Accepted: 17 Oct 2019; Available online: 30 Nov 2019; Published: 30 Nov 2019.
Open Access Copyright 2019 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

Citation Format:
Cover Image
Abstract

Reactive groups such as silanol, hydroxyl, and carbonyl groups in silica-lignin composites play a role in binding to chromium(VI) ions. The activation of functional groups in silica-lignin can be increased by the addition of an activator such as sodium periodate, which can also oxidize the lignin monomer (guaiasil) to ortho-quinone. This study aimed to obtain silica-lignin composites from rice husks activated by sodium periodate with a high surface area. Composite absorption was tested on chromium(VI) adsorption. Silica-lignin isolation was carried out by using the sol-gel method at concentrations of sodium hydroxide 5, 10, 15, and 20% (b/b). Silica-lignin activated with sodium periodate 10% (b/b) had the smallest particle size of about 8μm, with a surface area of 14.0888 m2.g-1 and followed Halsey isotherm adsorption model, with an adsorption capacity of 0.3054 mg.g-1.

Fulltext View|Download
Keywords: Adsorption; Chromium(VI); Halsey equation; Rice husk; Silica-lignin activation.
Funding: DRPMI Unpad through the Fundamental Grant Program for financial support, no contract 2373/UN6.D/KS/2018

Article Metrics:

Article Info
Section: Research Articles
Language : EN
Recent articles
Potential Adsorption of Heavy Metal Ions by Eugenol Compounds and Derivatives through Ion Imprinted Polymer Preparation and Validation of Fe2O3 Modified Carbon Paste Electrode for Measurement of Dopamine by Voltammetry Method Green synthesis of Ag/TiO2 Nanocomposite Assisted by Gambier Leaf (Uncaria gambir Roxb) Extract More recent articles
Most cited articles
Sintesis Metil Eugenol dan Benzil Eugenol dari Minyak Daun Cengkeh Sintesis Zeolit A dan Kemungkinan Penggunaannya Sebagai Penukar Kation Chitosan succinate/PVA-PEG Membrane: Preparation, Characterization and Permeation Ability Test on Creatinine Activity of Actinomycetes Isolated from Mangrove Segara Anakan Cilacap toward Methicillin-resistant Staphylococcus aureus (MRSA) Sintesis dan Karakterisasi Zeolit Y More cited articles
  1. Nassima Tazerouti and Moussa Amrani, Chromium (VI) Adsorption on Activated Lignin, Chemical Product and Process Modeling, 4, 1, (2009) https://doi.org/10.2202/1934-2659.1339
  2. Tamara A. Kravchenko, Leo L. Polyanskiy, Vyacheslav A. Krysanov, Evgeniy S. Zelensky, Anatolyi I. Kalinitchev and Wolfgang H. Hoell, Chemical precipitation of copper from copper–zinc solutions onto selective sorbents, Hydrometallurgy, 95, 1, (2009) 141-144 https://doi.org/10.1016/j.hydromet.2008.05.027
  3. S. Donegan, Direct solvent extraction of nickel at Bulong operations, Minerals Engineering, 19, 12, (2006) 1234-1245 https://doi.org/10.1016/j.mineng.2006.03.003
  4. A. Da̧browski, Z. Hubicki, P. Podkościelny and E. Robens, Selective removal of the heavy metal ions from waters and industrial wastewaters by ion-exchange method, Chemosphere, 56, 2, (2004) 91-106 https://doi.org/10.1016/j.chemosphere.2004.03.006
  5. Gábor Borbély and Endre Nagy, Removal of zinc and nickel ions by complexation–membrane filtration process from industrial wastewater, Desalination, 240, 1, (2009) 218-226 https://doi.org/10.1016/j.desal.2007.11.073
  6. S. Yu Bratskaya, A. V. Pestov, Yu G. Yatluk and V. A. Avramenko, Heavy metals removal by flocculation/precipitation using N-(2-carboxyethyl)chitosans, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 339, 1, (2009) 140-144 https://doi.org/10.1016/j.colsurfa.2009.02.013
  7. M. Mohsen-Nia, P. Montazeri and H. Modarress, Removal of Cu2+ and Ni2+ from wastewater with a chelating agent and reverse osmosis processes, Desalination, 217, 1, (2007) 276-281 https://doi.org/10.1016/j.desal.2006.01.043
  8. Qingxin Yao, Jianjun Xie, Junxia Liu, Hongmei Kang and Yuan Liu, Adsorption of lead ions using a modified lignin hydrogel, Journal of Polymer Research, 21, 6, (2014) 465 https://doi.org/10.1007/s10965-014-0465-9
  9. Yuning Qu, Yumei Tian, Bo Zou, Jian Zhang, Yunhui Zheng, Lili Wang, Ying Li, Chunguang Rong and Zichen Wang, A novel mesoporous lignin/silica hybrid from rice husk produced by a sol–gel method, Bioresource Technology, 101, 21, (2010) 8402-8405 https://doi.org/10.1016/j.biortech.2010.05.067
  10. Yati B. Yuliyati, Seli Listiani, Solihudin Solihudin and Atiek Rostika Noviyanti, Isolation of Silica-Lignin Composites from Rice Husk and Their Adsorption to Cr(VI), ALCHEMY Jurnal Penelitian Kimia, 14, 2, (2018) 267-275 http://dx.doi.org/10.20961/alchemy.14.2.19818.267-276
  11. A. Yu Kozhevnikov, S. L. Ul’yanovskaya, M. P. Semushina, S. A. Pokryshkin, A. V. Ladesov, I. I. Pikovskoi and D. S. Kosyakov, Modification of sulfate lignin with sodium periodate to obtain sorbent of 1,1-dimethylhydrazine, Russian Journal of Applied Chemistry, 90, 4, (2017) 516-521 https://doi.org/10.1134/S1070427217040048
  12. Łukasz Klapiszewski, Przemysław Bartczak, Marcin Wysokowski, Marta Jankowska, Katarzyna Kabat and Teofil Jesionowski, Silica conjugated with kraft lignin and its use as a novel ‘green’ sorbent for hazardous metal ions removal, Chemical Engineering Journal, 260, (2015) 684-693 https://doi.org/10.1016/j.cej.2014.09.054
  13. Jinlong Cui, Hongliang Sun, Xing Wang, Juncai Sun, Meihong Niu and Zhongsheng Wen, Preparation of siliceous lignin microparticles from wheat husks with a facile method, Industrial Crops and Products, 74, (2015) 689-696 https://doi.org/10.1016/j.indcrop.2015.05.061
  14. Suhas, P. J. M. Carrott and M. M. L. Ribeiro Carrott, Lignin – from natural adsorbent to activated carbon: A review, Bioresource Technology, 98, 12, (2007) 2301-2312 https://doi.org/10.1016/j.biortech.2006.08.008
  15. Erich Adler and Josef Gierer, The Alkylation of Lignin with Alcoholic Hydrochloric Acid, Acta Chemica Scandinavica, 9, 1, (1955) 84-93 https://doi.org/10.3891/acta.chem.scand.09-0084
  16. J. A. Gosselink Richard, E. G. van Dam Jan, Ed de Jong, Göran Gellerstedt, L. Scott Elinor and P. M. Sanders Johan, Effect of periodate on lignin for wood adhesive application, in: Holzforschung, 2011, pp. 155-162
  17. S. Chandrasekhar, P. N. Pramada and L. Praveen, Effect of organic acid treatment on the properties of rice husk silica, Journal of Materials Science, 40, 24, (2005) 6535-6544 https://doi.org/10.1007/s10853-005-1816-z
  18. Junsheng Liu and Xin Wang, Novel Silica-Based Hybrid Adsorbents: Lead(II) Adsorption Isotherms, The Scientific World Journal, 2013, Article ID 897159, (2013) 6 https://doi.org/10.1155/2013/897159
  19. Reyhaneh Saadi, Zahra Saadi, Reza Fazaeli and Narges Elmi Fard, Monolayer and multilayer adsorption isotherm models for sorption from aqueous media, Korean Journal of Chemical Engineering, 32, 5, (2015) 787-799 https://doi.org/10.1007/s11814-015-0053-7
  20. Ajay K. Agarwal, Mahendra S. Kadu, Chandrashekhar P. Pandhurnekar and Ishwardas L. Muthreja, Langmuir, Freundlich and BET Adsorption Isotherm Studies for Zinc ions onto coal fly ash, International Journal of Application or Innovation in Engineering & Management (IJAIEM), 3, 1, (2014) 64-71
  21. Beata Strzemiecka, Łukasz Klapiszewski, Artur Jamrozik, Tadeusz J. Szalaty, Danuta Matykiewicz, Tomasz Sterzyński, Adam Voelkel and Teofil Jesionowski, Physicochemical Characterization of Functional Lignin–Silica Hybrid Fillers for Potential Application in Abrasive Tools, Materials, 9, 7, (2016) 517 https://doi.org/10.3390/ma9070517
  22. Karol Bula, Łukasz Klapiszewski and Teofil Jesionowski, Effect of processing conditions and functional silica/lignin content on the properties of bio-based composite thin sheet films, Polymer Testing, 77, (2019) 105911 https://doi.org/10.1016/j.polymertesting.2019.105911
  23. Łukasz Klapiszewski, Przemysław Bartczak, Tomasz Szatkowski and Teofil Jesionowski, Removal of lead (II) ions by an adsorption process with the use of an advanced SiO2/lignin biosorbent, Polish Journal of Chemical Technology, 19, 1, (2017) 48-53 https://doi.org/10.1515/pjct-2017-0007

Last update:

  1. Development of Green and Sustainable Cellulose Acetate/Graphene Oxide Nanocomposite Films as Efficient Adsorbents for Wastewater Treatment

    Ali Aldalbahi, Mehrez El-Naggar, Tawfik Khattab, Meram Abdelrahman, Mostafizur Rahaman, Abdulaziz Alrehaili, Mohamed El-Newehy. Polymers, 12 (11), 2020. doi: 10.3390/polym12112501

  2. Utilization of Jengkol Peel (Pithecellobium jiringa (Jack) Prain) as Lead (II) Ions Bio-sorbent with Column Method

    Gatut Ari Wardani, Lia Nuramalia, Winda Trisna Wulandari, Estin Nofiyanti. Jurnal Kimia Sains dan Aplikasi, 23 (5), 2020. doi: 10.14710/jksa.23.5.160-166

  3. A Silica–Lignin Hybrid Filler in a Natural Rubber Foam Composite as a Green Oil Spill Absorbent

    Yati Mardiyati, Anna Niska Fauza, Onny Aulia Rachman, Steven Steven, Sigit Puji Santosa. Polymers, 14 (14), 2022. doi: 10.3390/polym14142930

Last update: 2024-11-20 22:46:24

No citation recorded.