DOI: https://doi.org/10.14710/jksa.22.6.220-226

Utilization of Rice Husk Cellulose as a Magnetic Nanoparticle Biocomposite Fiber Source for the Absorption of Manganese (Mn2+) Ions in Peat Water

Department of Chemical Engineering, Lambung Mangkurat University, Indonesia

Received: 3 Jul 2019; Revised: 17 Sep 2019; Accepted: 1 Oct 2019; Available online: 30 Nov 2019; Published: 30 Nov 2019.
Open Access Copyright 2019 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract
Rice husk (RH) is an agricultural waste that contains cellulose. Rice husk fiber (RHF) can be used as a source of fiber in the manufacture of magnetic nanoparticle biocomposite. The purpose of this study is to synthesize and characterize magnetic nanoparticle biocomposite used as an adsorbent and evaluate its performance on the adsorption of  Mn2+ ions and Total Suspended Solid (TSS) in peat water. Rice husk fiber was delignified to eliminate lignin levels. Furthermore, the biocomposite was made through the solvothermal method with and without the addition of hexanediamine. The products produced are two types of adsorbents, namely magnetic nanoparticle biocomposite with an amino group (RHB-MH) and rice husk fiber biocomposite without an amino group (RHB-M). These biocomposites were used to adsorb Mn2+ ions in peat water. Evaluations were carried out at pH 5, 6, 7, and 8 with an optimum adsorption time of 60 minutes. The solutions at the time of adsorption were evaluated to determine the optimum conditions of the adsorption process carried out. The observation of magnetic nanoparticle biocomposite based on the analysis of Scanning Electron Microscopy (SEM) shows magnetic nanoparticles formed on the surface of rice husk fiber with a diameter of 30-50 nm. X-Ray Diffraction (XRD) analysis showed that the delignification of rice husk increased Crystallinity Index (CrI) by 64.98% and reduced silica content by 78%. Fourier Transform Infra-Red (FT-IR) spectrometer show absorption peak at 570 cm-1 for Fe-O bonds and Fe3O4 peak around 1627 cm−1, indicating the presence of N-H bending. The optimum condition for Mn2+ adsorption was achieved at pH 5 and 60-minutes duration with an adsorption capacity of 54.7 mg/g and 190.78 mg/g for RHB-M and RHB-MH. The TSS reduction achieved the effectiveness of 60.2% and 90.3% for BSP-M and BSP-MH, respectively.
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Keywords: rise husk fiber; adsorbent; biocomposite; Mn2+ ion

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Section: Research Articles
Language : EN
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  1. James C. Williams and Edgar A. Starke, Progress in structural materials for aerospace systems11The Golden Jubilee Issue—Selected topics in Materials Science and Engineering: Past, Present and Future, edited by S. Suresh, Acta Materialia, 51, 19, (2003) 5775-5799 https://doi.org/10.1016/j.actamat.2003.08.023
  2. J. W. Kaczmar, K. Pietrzak and W. Włosiński, The production and application of metal matrix composite materials, Journal of Materials Processing Technology, 106, 1, (2000) 58-67 https://doi.org/10.1016/S0924-0136(00)00639-7
  3. Flake C. Campbell, Structural Composite Materials, ASM International, 2010
  4. Arsalan Hekmati and Rasoul Hekmati, Double pancake superconducting coil design for maximum magnetic energy storage in small scale SMES systems, Cryogenics, 80, (2016) 74-81 https://doi.org/10.1016/j.cryogenics.2016.09.009
  5. Yunfei Zhao, Mingfeng Cao, John F. McClelland, Zengyi Shao and Meng Lu, A photoacoustic immunoassay for biomarker detection, Biosensors and Bioelectronics, 85, (2016) 261-266 https://doi.org/10.1016/j.bios.2016.05.028
  6. Desiana Wuryanti and Edi Suharyadi, Studi Adsorpsi Logam Co(II), Cu(II), dan Ni(II) dalam Limbah Cair Buatan Menggunakan Adsorben Nanopartikel Magnetik Fe3O4 dan ZnFe2O4, Jurnal Fisika Indonesia, 20, 2, (2016) 28-35
  7. Iryanti F. Nata, Nermeen S. El-Safory and Cheng-Kang Lee, Carbonaceous Materials Passivation on Amine Functionalized Magnetic Nanoparticles and Its Application for Metal Affinity Isolation of Recombinant Protein, ACS Applied Materials & Interfaces, 3, 9, (2011) 3342-3349 https://doi.org/10.1021/am200453e
  8. Leyu Wang, Jie Bao, Lun Wang, Fang Zhang and Yadong Li, One-Pot Synthesis and Bioapplication of Amine-Functionalized Magnetite Nanoparticles and Hollow Nanospheres, Chemistry – A European Journal, 12, 24, (2006) 6341-6347 https://doi.org/10.1002/chem.200501334
  9. B. H. Hameed and A. A. Ahmad, Batch adsorption of methylene blue from aqueous solution by garlic peel, an agricultural waste biomass, Journal of Hazardous Materials, 164, 2, (2009) 870-875 https://doi.org/10.1016/j.jhazmat.2008.08.084
  10. I. A. W. Tan, A. L. Ahmad and B. H. Hameed, Adsorption isotherms, kinetics, thermodynamics and desorption studies of 2,4,6-trichlorophenol on oil palm empty fruit bunch-based activated carbon, Journal of Hazardous Materials, 164, 2, (2009) 473-482 https://doi.org/10.1016/j.jhazmat.2008.08.025
  11. Hala Ahmed Hegazi, Removal of heavy metals from wastewater using agricultural and industrial wastes as adsorbents, HBRC Journal, 9, 3, (2013) 276-282 https://doi.org/10.1016/j.hbrcj.2013.08.004
  12. Emiliano M. Ciannamea, Pablo M. Stefani and Roxana A. Ruseckaite, Medium-density particleboards from modified rice husks and soybean protein concentrate-based adhesives, Bioresource Technology, 101, 2, (2010) 818-825 https://doi.org/10.1016/j.biortech.2009.08.084
  13. Iryanti Fatyasari Nata, Giyanto Wijaya Salim and Cheng-Kang Lee, Facile preparation of magnetic carbonaceous nanoparticles for Pb2+ ions removal, Journal of Hazardous Materials, 183, 1, (2010) 853-858 https://doi.org/10.1016/j.jhazmat.2010.07.105
  14. Iryanti Fatyasari Nata, Manthiriyappan Sureshkumar and Cheng-Kang Lee, One-pot preparation of amine-rich magnetite/bacterial cellulose nanocomposite and its application for arsenate removal, RSC Advances, 1, 4, (2011) 625-631 https://doi.org/10.1039/C1RA00153A
  15. Saeedeh Hashemian, Seyed Hossein Hosseini, Hamila Salehifar and Khaterah Salari, Adsorption of Fe(III) from Aqueous Solution by Linde Type-A Zeolite, American Journal of Analytical Chemistry, 4, 7A, (2013) 123-126 https://doi.org/10.4236/ajac.2013.47A017
  16. Risfidian Mohadi, Nurlisa Hidayati and Aldes Lesbani, Adsorption Desorption of Chromium (III) Ion on Cellulose from Wood Powder, International Journal of Science and Engineering, 7, 1, (2014) 77-80 https://doi.org/10.12777/ijse.7.1.77-80
  17. L. Ghali, S. Msahli, M. Zidi and F. Sakli, Effect of pre-treatment of Luffa fibres on the structural properties, Materials Letters, 63, 1, (2009) 61-63 https://doi.org/10.1016/j.matlet.2008.09.008
  18. I. F. Nata, M. D. Putra, D. Nurandini, C. Irawan, R. Fitriani and M. D. Isnaini, Rice Husk Fiber Magnetic Nanoparticle Biocomposites: Preparation and Characterization, IOP Conference Series: Earth and Environmental Science, 175, (2018) 012005 https://doi.org/10.1088/1755-1315/175/1/012005
  19. P. Waranusantigul, P. Pokethitiyook, M. Kruatrachue and E. S. Upatham, Kinetics of basic dye (methylene blue) biosorption by giant duckweed (Spirodela polyrrhiza), Environmental Pollution, 125, 3, (2003) 385-392 https://doi.org/10.1016/S0269-7491(03)00107-6
  20. Wei Wu, Quanguo He and Changzhong Jiang, Magnetic Iron Oxide Nanoparticles: Synthesis and Surface Functionalization Strategies, Nanoscale Research Letters, 3, 11, (2008) 397 https://doi.org/10.1007/s11671-008-9174-9
  21. Soodamani Periyasamy, Venkatrajan Gopalakannan and Natrayasamy Viswanathan, Fabrication of magnetic particles imprinted cellulose based biocomposites for chromium(VI) removal, Carbohydrate Polymers, 174, (2017) 352-359 https://doi.org/10.1016/j.carbpol.2017.06.029
  22. Ying Zhang, Jiaying Zhao, Zhao Jiang, Dexin Shan and Yan Lu, Biosorption of Fe(II) and Mn(II) Ions from Aqueous Solution by Rice Husk Ash, BioMed Research International, 2014, (2014) 10 https://doi.org/10.1155/2014/973095
  23. Yao-Hui Huang, Yu-Jen Shih and Chia-Chi Chang, Adsorption of fluoride by waste iron oxide: The effects of solution pH, major coexisting anions, and adsorbent calcination temperature, Journal of Hazardous Materials, 186, 2, (2011) 1355-1359 https://doi.org/10.1016/j.jhazmat.2010.12.025
  24. An-Hui Lu, E. L Salabas and Ferdi Schüth, Magnetic Nanoparticles: Synthesis, Protection, Functionalization, and Application, Angewandte Chemie International Edition, 46, 8, (2007) 1222-1244 https://doi.org/10.1002/anie.200602866

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