DOI: https://doi.org/10.14710/jksa.22.6.292-298

Polyaniline Modified Natural Zeolite as Adsorbent for Chromium(III) Metal Ion

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Indonesia

Received: 18 Aug 2019; Revised: 7 Nov 2019; Accepted: 13 Nov 2019; Available online: 30 Nov 2019; Published: 30 Nov 2019.
Open Access Copyright 2019 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract
Zeolite is an inorganic material whose surface has a permanent negative charge in its crystal structure. This material consists of tetrahedral [SiO4]-4 and [AlO4]-5, which are connected by oxygen atoms in such a way as to form an open three-dimensional framework containing canals and cavities, as well as alkali or alkali metals for balancing the negative charge. This structure makes zeolites have the ability to adsorb. The ability of natural zeolite adsorption can improve by modifying the surface by adding polyaniline cationic compounds (PANI), which have an amine group (: NH2). Moreover, environmental pollution by metals is the biggest problem in daily life, one of which is the metal ion Cr(III), which is a waste from industrial processes. Therefore, it is necessary to have an effort to reduce waste. This study aims to determine the effect of the addition of polyaniline on the adsorption ability of natural zeolites to metal ions Cr(III). The research was carried out in several stages, namely activation of natural zeolite using HF 1%, modification with polymer from aniline monomers, and ammonium peroxidisulphate (APS), and testing the ability of adsorption on Cr(III) metal ions. The study on the ability to adsorb Cr(III) metal ions by PANI-modified zeolites was carried out on variations in the concentration of Cr(III) metal ions and the system pH. The results showed that natural zeolite successfully modified with PANI. The FTIR absorption band at wavenumber 1303 -1319 cm-1 and 1597 cm-1 indicated the presence of NH functional groups. Meanwhile, adsorption capability test data showed that the best adsorbent for adsorption of Cr(III) metal ions was zeolite-PANI 0.01M. The best pH was 4, the initial concentration of Cr(III) metal ions was 1000 ppm, and the percentage of absorption is 48.13%.
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Keywords: natural zeolite; polyaniline; adsorbent; Cr(III)

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Section: Research Articles
Language : EN
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  1. Balwinder Kaur and Rajendra Srivastava, Simultaneous determination of epinephrine, paracetamol, and folic acid using transition metal ion-exchanged polyaniline–zeolite organic–inorganic hybrid materials, Sensors and Actuators B: Chemical, 211, (2015) 476-488 https://doi.org/10.1016/j.snb.2015.01.081
  2. Anis Komariah, Sriatun Sriatun and Pardoyo Pardoyo, Adsorpsi Alkil Benzena Sulfonat Menggunakan Zeolit Termodifikasi Cetyltrimethylammonium, Jurnal Kimia Sains dan Aplikasi, 20, 1, (2017) 13-18 https://doi.org/10.14710/jksa.20.1.13-18
  3. Priyanka Jain, Shilpa Varshney and Shalini Srivastava, Site-specific functionalization for chemical speciation of Cr(III) and Cr(VI) using polyaniline impregnated nanocellulose composite: equilibrium, kinetic, and thermodynamic modeling, Applied Water Science, 7, 4, (2017) 1827-1839 https://doi.org/10.1007/s13201-015-0356-1
  4. Abdulsalam A. Shyaa, Omar A. Hasan and Ahmed M. Abbas, Synthesis and characterization of polyaniline/zeolite nanocomposite for the removal of chromium(VI) from aqueous solution, Journal of Saudi Chemical Society, 19, 1, (2015) 101-107 https://doi.org/10.1016/j.jscs.2012.01.001
  5. Muzzaffar Ahmad Mir, Muzzaffar Ahmad Bhat, Sheikh Abdul Majid, Shabir H. Lone, Manzoor Ahmad Malla, Kautily Rao Tiwari, Ashiq Hussain Pandit, Radha Tomar and Rayees Ahmad Bhat, Studies on the synthesis and characterization of polyaniline-zeolite nanostructures and their role in carbon monoxide sensing, Journal of Environmental Chemical Engineering, 6, 1, (2018) 1137-1146 https://doi.org/10.1016/j.jece.2018.01.027
  6. Mostafa R. Abukhadra, Mohamed Rabia, Mohamed Shaban and Francis Verpoort, Heulandite/polyaniline hybrid composite for efficient removal of acidic dye from water; kinetic, equilibrium studies and statistical optimization, Advanced Powder Technology, 29, 10, (2018) 2501-2511 https://doi.org/10.1016/j.apt.2018.06.030
  7. Anka Jevremović, Patrycja Bober, Matej Mičušík, Jaroslav Kuliček, Udit Acharya, Jiří Pfleger, Maja Milojević-Rakić, Danina Krajišnik, Miroslava Trchová, Jaroslav Stejskal and Gordana Ćirić-Marjanović, Synthesis and characterization of polyaniline/BEA zeolite composites and their application in nicosulfuron adsorption, Microporous and Mesoporous Materials, 287, (2019) 234-245 https://doi.org/10.1016/j.micromeso.2019.06.006
  8. Mohamed Adel Sayed, Mostafa R. Abukhadra, Mohamed Abdel Salam, Sobhy M. Yakout, Ahmed A. Abdeltawab and Ibrahim M. Aziz, Photocatalytic hydrogen generation from raw water using zeolite/polyaniline@Ni2O3 nanocomposite as a novel photo-electrode, Energy, 187, (2019) 115943 https://doi.org/10.1016/j.energy.2019.115943
  9. Afshin Maleki, Bagher Hayati, Maryam Naghizadeh and Sang W. Joo, Adsorption of hexavalent chromium by metal organic frameworks from aqueous solution, Journal of Industrial and Engineering Chemistry, 28, (2015) 211-216 https://doi.org/10.1016/j.jiec.2015.02.016
  10. Rania E. Morsi, E. A. Khamis and A. M. Al-Sabagh, Polyaniline nanotubes: Facile synthesis, electrochemical, quantum chemical characteristics and corrosion inhibition efficiency, Journal of the Taiwan Institute of Chemical Engineers, 60, (2016) 573-581 https://doi.org/10.1016/j.jtice.2015.10.028
  11. Nomcebo H. Mthombeni, Maurice S. Onyango and Ochieng Aoyi, Adsorption of hexavalent chromium onto magnetic natural zeolite-polymer composite, Journal of the Taiwan Institute of Chemical Engineers, 50, (2015) 242-251 https://doi.org/10.1016/j.jtice.2014.12.037
  12. Deyi Wu, Yanming Sui, Shengbing He, Xinze Wang, Chunjie Li and Hainan Kong, Removal of trivalent chromium from aqueous solution by zeolite synthesized from coal fly ash, Journal of Hazardous Materials, 155, 3, (2008) 415-423 https://doi.org/10.1016/j.jhazmat.2007.11.082
  13. Dewi Yuanita Lestari, Kajian modifikasi dan karakterisasi zeolit alam dari berbagai negara, Prosiding Seminar Nasional Kimia dan Pendidikan Kimia 2010, Yogyakarta, (2010)
  14. Sofian Ansori, Sriatun Sriatun and Pardoyo Pardoyo, Modifikasi Zeolit Alam Menggunakan TiO2 sebagai Fotokatalis Zat Pewarna Indigo Carmine, Jurnal Kimia Sains dan Aplikasi, 19, 2, (2016) 68-71 https://doi.org/10.14710/jksa.19.2.68-71
  15. Iman Rahayu, Annisa Wijayati and Sahrul Hidayat, Sintesis dan Karakterisasi Polianilina Doping Asam Klorida dengan Metode Interfasial, Jurnal Kimia VALENSI: Jurnal Penelitian dan Pengembangan Ilmu Kimia, 2, 1, (2015) 74-79 https://doi.org/10.15408/jkv.v0i0.3143
  16. Gordon G. Wallace, Peter R. Teasdale, Geoffrey M. Spinks and Leon A.P. Kane-Maguire, Conductive Electroactive Polymers: Intelligent Materials Systems, Second Edition, CRC Press, 2002
  17. Halimaton Hamdan, Introduction To Zeolites: Synthesis, Characterization, and Modification, Universiti Teknologi Malaysia, Kualalumpur, 1992
  18. A. Olad, M. Khatamian and B. Naseri, Removal of toxic hexavalent chromium by polyaniline modified clinoptilolite nanoparticles, Journal of the Iranian Chemical Society, 8, 1, (2011) S141-S151 https://doi.org/10.1007/BF03254291
  19. Silvio R. Taffarel and Jorge Rubio, Removal of Mn2+ from aqueous solution by manganese oxide coated zeolite, Minerals Engineering, 23, 14, (2010) 1131-1138 https://doi.org/10.1016/j.mineng.2010.07.007
  20. Siti Sulastri, Indriana Kartini Nuryono and Eko Sri Kunarti, Kinetika dan Keseimbangan Adsorpsi Ion Kromium (III) dalam Larutan pada Senyawa Silika dan Modifikasi Silika Hasil Sintesis dari Abu Sekam Padi, Jurnal Penelitian Saintek, 19, 2, (2014) 33-44
  21. Sriatun Sriatun, Dimas Buntarto and Adi Darmawan, Pengaruh Penambahan Surfaktan Hexadecyltrimethyl-Ammonium (HDTMA) pada Zeolit Alam Terdealuminasi terhadap Kemampuan Mengadsorpsi Fenol, Jurnal Kimia Sains dan Aplikasi, 11, 1, (2008) 11-14 https://doi.org/10.14710/jksa.11.1.11-14
  22. Tom Chih-Hung Wang, Polyelectrolyte multilayers as nanostructured templates for inorganic synthesis, Massachusetts Institute of Technology,
  23. Tan Chen, Zeyu Zhou, Sai Xu, Hongtao Wang and Wenjing Lu, Adsorption behavior comparison of trivalent and hexavalent chromium on biochar derived from municipal sludge, Bioresource Technology, 190, (2015) 388-394 https://doi.org/10.1016/j.biortech.2015.04.115
  24. G. Svehla, Vogel's Qualitative Inorganic Analysis, Pearson Education, 2008

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