DOI: https://doi.org/10.14710/jksa.23.5.167-176

Electrocoating Polypyrrole on Gold-Wire Electrode as Potential Mediator Membrane Candidate for Anionic Surfactant Electrode Sensor

1Department of Chemistry, Faculty of Mathematics and Natural Sciences, Halu Oleo University, Indonesia

2Department of Chemistry, Faculty of Mathematics and Natural Sciences, Bandung Institute of Technology, Indonesia

Received: 6 Feb 2020; Revised: 6 May 2020; Accepted: 7 May 2020; Published: 31 May 2020.
Open Access Copyright 2020 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract

The development of polypyrrole as a potential mediator membrane candidate for sodium dodecyl sulfate (SDS) sensor electrode has been investigated. The polypyrrole membrane was synthesized electrochemically from the pyrrole and coated at the surface of a 1.0 mm diameter of the gold-wire electrode. Electropolymerization of pyrrole and coating of the polypyrrole produced was performed by cyclic voltammetry technique in the electrochemical cell containing supporting electrolyte of 0.01 M NaClO4 with an optimum potential range of -0.9 V–1.0 V, the scanning rate of 100 mV/s, an electric current of 2 mA, and running of potential scanning of 10 cycles. By using the similar optimal parameters of cyclic voltammetry, electropolymerization of 0.01 M pyrrole solution containing 0.001 M SDS also produces a polypyrrole membrane coated at the gold-wire electrode surface. These coated electrodes have the potential response-ability toward DS- anions in the concentration range of 10-7 M–10-5 M with a limit of detection of 10-7 M and sensitivity of electrode of 9.9 mV/decade. This finding shows that the SDS solution’s role is as supporting electrolyte and also as a source of DS- dopant during the pyrrole electropolymerization processes. Dopants are trapped in the polymer membrane during the electrochemical formation of polypyrrole and role as ionophores for DS- anion in the analyte solution. A potential response to the electrode phenomena is excellent basic scientific information for further synthesis of conducting polymer and development of conducting polymer-coated wire electrode model, especially in the construction of ion-selective electrode (ISE) for the determination of anionic surfactants with those models.

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Keywords: polypyrrole; electropolymerization; coated wire electrode; anionic surfactant ISE
Funding: Halu Oleo University

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Section: Research Articles
Language : EN
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  1. M. S. Bhende, R. S. Bobade, S. P. Yawale and S. S. Yawale, Synthesis and DC Conductivity of Polypyrrole/SnO2 Nanocomposites, Scientific Reviews and Chemical Communications, 2, 3, (2012), 413-418
  2. Alen Shahbazian, Amir H. Navarchian and Mahdi Pourmehr, Application of Taguchi method to investigate the effects of process factors on the performance of batch emulsion polymerization of vinyl chloride, Journal of Applied Polymer Science, 113, 5, (2009), 2739-2746 https://doi.org/10.1002/app.30194
  3. Ahmed A Al-Dulaimi, Shahrir Hashim and MI Khan, Corrosion protection of carbon steel using polyaniline composite with inorganic pigments, Sains Malaysiana, 40, 7, (2011), 757-763
  4. Izura Izzuddin, Mohammad Hafizuddin Haji Jumali, Muhammad Yahaya and Muhamad Mat Salleh, New hybridization approach of titanium organometallic: PANi thin films as room temperature gas sensors, Sains Malaysiana, 41, 8, (2012), 1017-1021
  5. Mohammad Hafizuddin Haji Jumali, Norhashimah Ramli, Izura Izzuddin, Muhamad Mat Salleh and Muhammad Yahaya, Influence of PANI additions on methanol sensing properties of ZnO thin films, Sains Malaysiana, 40, 3, (2011), 203-208
  6. Asif Ali Khan and Leena Paquiza, Electrical behavior of conducting polymer based ‘polymeric–inorganic’nanocomposite: Polyaniline and polypyrrole zirconium titanium phosphate, Synthetic metals, 161, 9-10, (2011), 899-905 https://doi.org/10.1016/j.synthmet.2011.02.022
  7. Kai Qi, Yubing Qiu, Zhenyu Chen and Xingpeng Guo, Corrosion of conductive polypyrrole: Effects of environmental factors, electrochemical stimulation, and doping anions, Corrosion science, 60, (2012), 50-58 https://doi.org/10.1016/j.corsci.2012.04.013
  8. Fouad Ghamouss, Aymeric Brugère, Amarnath Chellachamy Anbalagan, Bruno Schmaltz, Erwann Luais and François Tran-Van, Novel glycerol assisted synthesis of polypyrrole nanospheres and its electrochemical properties, Synthetic metals, 168, (2013), 9-15 https://doi.org/10.1016/j.synthmet.2013.02.005
  9. Duk Ki Kim, Kyung Wha Oh, Hee Jun Ahn and Seong Hun Kim, Synthesis and characterization of polypyrrole rod doped with p-toluenesulfonic acid via micelle formation, Journal of Applied Polymer Science, 107, 6, (2008), 3925-3932 https://doi.org/10.1002/app.27509
  10. Erhan Karaca, Nuran Özçiçek Pekmez and Kadir Pekmez, Galvanostatic deposition of polypyrrole in the presence of tartaric acid for electrochemical supercapacitor, Electrochimica Acta, 147, (2014), 545-556 https://doi.org/10.1016/j.electacta.2014.09.136
  11. Xianxia Yuan, Xin-Long Ding, Chao-Yang Wang and Zi-Feng Ma, Use of polypyrrole in catalysts for low temperature fuel cells, Energy & Environmental Science, 6, 4, (2013), 1105-1124 https://doi.org/10.1039/C3EE23520C
  12. Cristina Della Pina, Ermelinda Falletta, Massimiliano Lo Faro, Mauro Pasta and Michele Rossi, Gold-catalysed synthesis of polypyrrole, Gold Bulletin, 42, 1, (2009), 27-33 https://doi.org/10.1007/BF03214903
  13. Morteza Hajian, Gholam Ali Koohmareh and Mahdi Rastgoo, Investigation of factors affecting synthesis of polyvinyl butyral by Taguchi method, Journal of Applied Polymer Science, 115, 6, (2010), 3592-3597 https://doi.org/10.1002/app.30603
  14. Helen J. James, Gary Carmack and Henry Freiser, Coated wire ion-selective electrodes, Analytical Chemistry, 44, 4, (1972), 856-857 https://doi.org/10.1021/ac60312a046
  15. Do P. Quan, Trevor W. Lewis, Gordon G. Wallace and Pham H. Viet, A Conductive Polypyrrole Modified Microelectrode for Selective Amperometric Detection of Nitrate in a Flow Injection System, Analytical Sciences/Supplements Proceedings of IUPAC International Congress on Analytical Sciences 2001 (ICAS 2001), (2002) https://doi.org/10.14891/analscisp.17icas.0.i745.0
  16. Gamal A. E. Mostafa, PVC matrix membrane sensor for potentiometric determination of cetylpyridinium chloride, Analytical sciences, 17, 9, (2001), 1043-1047 https://doi.org/10.2116/analsci.17.1043
  17. Manik A. Chougule, Shailesh G. Pawar, Prasad R. Godse, Ramesh N. Mulik, Shashwati Sen and Vikas B. Patil, Synthesis and Characterization of Polypyrrole (PPy) Thin Films, Soft Nanoscience Letters, 1, 1, (2011), 6-10 http://dx.doi.org/10.4236/snl.2011.11002
  18. Mostafizur Rahaman, Ali Aldalbahi, Mohammed Almoiqli and Shaykha Alzahly, Chemical and electrochemical synthesis of polypyrrole using carrageenan as a dopant: Polypyrrole/multi-walled carbon nanotube nanocomposites, Polymers, 10, 6, (2018), 632 https://doi.org/10.3390/polym10060632
  19. Saïd Sadki, Philippe Schottland, Nancy Brodie and Guillaume Sabouraud, The mechanisms of pyrrole electropolymerization, Chemical Society Reviews, 29, 5, (2000), 283-293 https://doi.org/10.1039/A807124A
  20. Radko Volf, Vladimı́r Král, Jan Hrdlička, Tatiana V. Shishkanova, Gabriela Broncová, Martin Krondak, Sylvie Grötschelová, Miloslav Št'astný, Jiřı́ Kroulı́k, Martin Valı́k, Pavel Matějka and Karel Volka, Preparation, characterization and analytical application of electropolymerized films, Solid State Ionics, 154-155, (2002), 57-63 https://doi.org/10.1016/S0167-2738(02)00464-2
  21. Agata Michalska, Ari Ivaska and Andrzej Lewenstam, Modeling Potentiometric Sensitivity of Conducting Polymers, Analytical Chemistry, 69, 19, (1997), 4060-4064 https://doi.org/10.1021/ac970227l
  22. Richard S. Hutchins and Leonidas G. Bachas, Nitrate-Selective Electrode Developed by Electrochemically Mediated Imprinting/Doping of Polypyrrole, Analytical Chemistry, 67, 10, (1995), 1654-1660 https://doi.org/10.1021/ac00106a002
  23. Mária Omastová, Miroslava Trchová, Jana Kovářová and Jaroslav Stejskal, Synthesis and structural study of polypyrroles prepared in the presence of surfactants, Synthetic Metals, 138, 3, (2003), 447-455 https://doi.org/10.1016/S0379-6779(02)00498-8
  24. Olivera Galović, Mirela Samardžić, Sanja Petrušić and Milan Sak-Bosnar, Application of a new potentiometric sensor for determination of anionic surfactants in wastewater, Chemical and biochemical engineering quarterly, 29, 3, (2015), 307-313 https://doi.org/10.15255/CABEQ.2014.2164
  25. Joseph Wang, Analytical Electrochemistry, 2nd ed., John Wiley & Sons, New York, 2001
  26. M. D. Imisides, R. John and G. G. Wallace, Microsensors based on conducting polymers, Chemtech, 26, 5, (1996), 19-25
  27. Ming Zhou and Jürgen Heinze, Electropolymerization of pyrrole and electrochemical study of polypyrrole: 1. Evidence for structural diversity of polypyrrole, Electrochimica Acta, 44, 11, (1999), 1733-1748 https://doi.org/10.1016/S0013-4686(98)00293-X
  28. Yongfang Li and Renyuan Qian, Electrochemical overoxidation of conducting polypyrrole nitrate film in aqueous solutions, Electrochimica Acta, 45, 11, (2000), 1727-1731 https://doi.org/10.1016/S0013-4686(99)00392-8
  29. Reza Ansari, Polypyrrole conducting electroactive polymers: synthesis and stability studies, Journal of Chemistry, 3, 4, (2006), 186-201 https://doi.org/10.1155/2006/860413
  30. Yongfang Li, On the large overpotential of the first reduction of polypyrrole perchlorate films in organic solutions, Electrochimica Acta, 42, 2, (1997), 203-210 https://doi.org/10.1016/0013-4686(96)00145-4
  31. Paul M.S. Monk, Fundamentals of Electroanalytical Chemistry, Wiley, 2008
  32. K. Bouzek, K. M. Mangold and K. Jüttner, Platinum distribution and electrocatalytic properties of modified polypyrrole films, Electrochimica Acta, 46, 5, (2001), 661-670 https://doi.org/10.1016/S0013-4686(00)00659-9
  33. Jennifer M. Pringle, John Efthimiadis, Patrick C. Howlett, Jim Efthimiadis, Douglas R. MacFarlane, Adrian B. Chaplin, Simon B. Hall, David L. Officer, Gordon G. Wallace and Maria Forsyth, Electrochemical synthesis of polypyrrole in ionic liquids, Polymer, 45, 5, (2004), 1447-1453 https://doi.org/10.1016/j.polymer.2004.01.006
  34. Peter T. Kissinger and William R. Heineman, Cyclic voltammetry, Journal of Chemical Education, 60, 9, (1983), 702 https://doi.org/10.1021/ed060p702
  35. J. Tamm, A. Alumaa, A. Hallik, T. Silk and V. Sammelselg, Nature of ion sensitivity of polypyrrole electrodes, Journal of Electroanalytical Chemistry, 414, 2, (1996), 149-158 https://doi.org/10.1016/0022-0728(96)04663-3
  36. A. Alumaa, A. Hallik, U. Mäeorg, V. Sammelselg and J. Tamm, Potentiometric properties of polypyrrole bilayers, Electrochimica Acta, 49, 11, (2004), 1767-1774 https://doi.org/10.1016/j.electacta.2003.12.008

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