skip to main content

The Effect of Adding Pine Tar Oil and Petrosin as Tackifier Ingredients on The Quality of Liquid Rubber Compound-based Adhesives

Department of Chemistry, Faculty of Sciences and Mathematics, Bengkulu University, Bengkulu, Indonesia

Received: 15 Jun 2023; Revised: 29 Sep 2023; Accepted: 11 Oct 2023; Published: 5 Nov 2023.
Open Access Copyright 2023 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

Citation Format:
Cover Image
Abstract

This research is focused on the development of adhesives through the utilization of different types of tackifiers. The primary raw materials employed comprise 60% concentrated latex, which is subsequently blended with additives that have been dispersed, including KOH as a stabilizing agent, stearic acid and ZnO as activators, BHT as an antioxidant, CaCO3 as a filler, MBTS (Mercaptobenzothiazole disulfide) and TMTD (Tetramethyl Thiuram Disulphide) as accelerators, and sulfur as a vulcanizing agent. This research explored two specific variations of tackifiers: pine tar oil and petrosin. The characterization of the adhesives encompasses an analysis of acidity (pH), viscosity, adhesive strength, functional group analysis using FTIR, thermal properties, and XRD. The research findings showed that the optimal conditions were achieved in the third variation of the adhesive, with the same ratio of pine tar oil tackifier and petrosin of 4 grams each. In this particular variation, adhesives conforming to the SNI 12- 7195-2006 standards were produced, displaying an adhesion strength of 1.506 N/mm, a viscosity of 1075 cP, and a pH level of 4.6. Furthermore, thermal testing results reveal that the adhesive created with tackifier (V3) exhibits thermal resistance up to 350°C, a glass transition temperature of 354°C, and a melting point of 378°C.

Note: This article has supplementary file(s).

Fulltext View|Download |  Copyright Transfer Agreement
PENGARUH PENAMBAHAN MINYAK TAR PINUS DAN PETROSIN SEBAGAI BAHAN TACKIFIER TERHADAP KUALITAS PEREKAT BERBASIS KOMPON KARET CAIR
Subject
Type Copyright Transfer Agreement
  Download (380KB)    Indexing metadata
Keywords: Tackifier; Liquid Rubber Compound; Adhesive
Funding: Universitas Bengkulu

Article Metrics:

  1. Direktorat Jenderal Perkebunan, Statistik Perkebunan Karet Indonesia 2017-2021, Ditjebun, Jakarta, Indonesia, 2022
  2. Fery Setyo Darmono, Study Eksperimental Pengolahan Karet Alam untuk Bahan Ebonit, Univerversitas Muhammadiyah Surakarta, Surakarta, 2009
  3. A. S. Hashim, B. Azahari, Y. Ikeda, S. Kohjiya, The Effect of Bis(3-Triethoxysilylpropyl) Tetrasulfide on Silica Reinforcement of Styrene-Butadiene Rubber, Rubber Chemistry and Technology, 71, 2, (1998), 289-299 https://doi.org/10.5254/1.3538485
  4. C. S. S. R. Kumar, Avinash M. Nijasure, Vulcanization of rubber, Resonance, 2, (1997), 55-59 https://doi.org/10.1007/BF02919629
  5. Lin Chen, Xing-long Gong, Wan-quan Jiang, Jing-jing Yao, Hua-xia Deng, Wei-hua Li, Investigation on magnetorheological elastomers based on natural rubber, Journal of Materials Science, 42, (2007), 5483-5489 https://doi.org/10.1007/s10853-006-0975-x
  6. Herminiwati Herminiwati, Arum Yuniari, R. Jaka Susila, Lem kompon karet untuk sepatu kulit yang dibuat dengan proses vulkanisasi, Majalah Kulit, Karet, dan Plastik, 24, 1, (2008), 14-18 http://dx.doi.org/10.20543/mkkp.v24i1.319
  7. P. Raethong, K. Boonkerd, Effect of type and content of tackifier on adhesion of natural rubber and reclaimed natural rubber based sealant, IOP Conference Series: Materials Science and Engineering, 2017 https://doi.org/10.1088/1757- 899X/223/1/012011
  8. Santi Puspitasari, Norma Arisanti Kinasih, Adi Cifriadi, Arief Ramadhan, Zahra Krishna Hadi, Novita Putri Wahyuni, Mochamad Chalid, Seleksi resin dan rubber processing oil (RPO) dalam pembuatan cushion gum sebagai perekat ban vulkanisir, Majalah Kulit, Karet, dan Plastik, 36, 1, (2020), 9-16 http://dx.doi.org/10.20543/mkkp.v36i1.6105
  9. Bireswar Banerjee, Tyre Retreading, De Gruyter, Boston, 2019, ^ https://doi.org/10.1515/9783110643893
  10. Imran Khan, B. T. Poh, Natural Rubber-Based Pressure-Sensitive Adhesives: A Review, Journal of Polymers and the Environment, 19, (2011), 793-811 https://doi.org/10.1007/s10924-011-0299-z
  11. Teja Dwi Sutanto, Pembuatan dan Karakterisasi Kompon Karet Cair Berbasis Lateks Pekat dan Asap Cair Tempurung Kelapa, Kimia, Universitas Gadjah Mada, Yogyakarta, 2015
  12. Edo Prabawandwika Sulistyanto, Yudhomenggolo Sastro Darmanto, Ulfah Amalia, Karakteristik Lem Ikan dari Tiga Jenis Ikan Laut yang Berbeda, Jurnal Ilmu dan Teknologi Kelautan Tropis, 7, 1, 23-31
  13. C. C. Ho, M. C. Khew, Surface Morphology of Prevulcanized Natural Rubber Latex Films by Atomic Force Microscopy: New Insight into the Prevulcanization Mechanism, Langmuir, 15, 19, (1999), 6208-6219 https://doi.org/10.1021/la981601v
  14. Ary Widiyanto, Kualitas papan partikel kayu karet (Hevea brasiliensis Muell. Arg) dan bambu tali (Gigantochloa apus Kurz) dengan perekat likuida kayu, Jurnal Penelitian Hasil Hutan, 29, 4, (2011), 301-311 https://doi.org/10.20886/jphh.2011.29.4.301-311
  15. Mohammad Saleh, Ratna Sari Embun, Soesarsono Wijandi, Ninuk Indriati, Nurul Haq, Ekstraksi Lem Ikan dari Tulang Ikan Pari, Jurnal Penelitian Perikanan Indonesia, 1, 2, (1995), 28-38 http://dx.doi.org/10.15578/jppi.1.2.1995.28-38
  16. Adi Cifriadi, Purwantiningsih Sugita, Tetty Kemala, Siti Nikmatin, Kajian Penggunaan Carbon Black N990 sebagai Bahan Pengisi Kompon Karet Alam: Sifat Dinamik, Kestabilan Termal, dan Ketahanan Panas, Jurnal Riset Kimia, 14, 1, (2023), 25-34
  17. Jaqueline Alves Ribeiro, Suelia Rodrigues Fleury Rosa, Cicilia Raquel Maia Leite, Claudio Lopes Vasconcelos, João Maria Soares, Development Assessment of Natural Latex Membranes: A New Proposal for the Treatment of Amblyopia, Materials Research, 20, 3, (2017), 653-660 https://doi.org/10.1590/1980-5373-MR-2016-0355
  18. Sudirman Sudirman, Ridwan Ridwan, Mujamilah Mujamilah, Waluyo Trijono, Analisis Termal dan Struktur Mikro Magnet Komposit Berbasis Heksaferit dengan Matriks Karet Alam, Jurnal Sains Materi Indonesia, 2, 1, (2018), 13-17
  19. David J. Kind, T. Richard Hull, A review of candidate fire retardants for polyisoprene, Polymer Degradation and Stability, 97, 3, (2012), 201-213 https://doi.org/10.1016/j.polymdegradstab.2011.12.008
  20. Sirilak Phomrak, Muenduen Phisalaphong, Reinforcement of Natural Rubber with Bacterial Cellulose via a Latex Aqueous Microdispersion Process, Journal of Nanomaterials, 2017, (2017), 4739793 https://doi.org/10.1155/2017/4739793

Last update:

No citation recorded.

Last update: 2024-05-08 00:08:40

No citation recorded.