DOI: https://doi.org/10.14710/jksa.26.9.324-331

Optimization and Kinetics Extraction of Natural Dyes from Henna Leaves (Lawsonia inermis L.) with Ultrasonic Assistance

1Mineral Chemical Engineering Department, Politeknik ATI Makassar, Makassar 90211, Indonesia

2Chemical Engineering Department, Universitas Pembangunan Nasional Veteran Jawa Timur, Surabaya, Indonesia

3Chemical Engineering Department, Institut Teknologi Sepuluh Nopember, Surabaya, Jawa Timur, Indonesia

Received: 4 Sep 2023; Revised: 6 Nov 2023; Accepted: 22 Nov 2023; Published: 8 Dec 2023.
Open Access Copyright 2023 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

Citation Format:
Cover Image
Abstract
The Lawson dye contained in the leaves of Lawsonia inermis L. has a red-orange color, which can be used as a fabric dye. The solvent is ethanol because it can attract flavonoid compounds bound to Lawson. The ultrasonic-assisted extraction method is employed to enhance the extraction process by breaking down cell walls, thereby facilitating a more rapid extraction of the desired solute. This study investigated the effects of material-to-solvent ratio, ethanol concentration, and extraction time. The research results were analyzed using a UV-Visible spectrophotometer to determine the yield of Lawson extract. The Face-Centered Composite Design (FCCCD) method was applied to this study to obtain optimal analysis results and extraction conditions. The independent variables in this study were the ratio of ingredients to solvent (0.02-0.06 g/g), ethanol concentration (20-60%), and extraction time (5-15 minutes). The optimal extraction conditions were obtained at a ratio of 0.02 g/g, an ethanol concentration of 60%, and an extraction time of 15 minutes, with a predicted model yield of 15.417%. The actual yield under these conditions was found to be 15.4934%. Furthermore, the extraction kinetics model was analyzed to study and predict the optimal Lawson extraction results. Extraction kinetics calculations were carried out using first-order and second-order based on the Lagergren equation. The most suitable extraction kinetic model is second-order with a determinant coefficient value, or the value of R2 is 1, which indicates that the order kinetic model equation represents the actual conditions.
Fulltext View|Download
Keywords: Lawsonia inermis L.; Ultrasonic-assisted Extraction; Face-Centered Composite Design; Kinetics extraction; second-order

Article Metrics:

Article Info
Section: Research Articles
Language : EN
Recent articles
Development of Microfluidic Paper-Based Analytical Devices (µPADs) for Determination of Cd2+, Pb2+, and Cu2+ Ions in Mineral Water Modification and Application Study of Activated Natural Zeolite for the Treatment of Liquid Waste from Chemical Laboratory In vitro and In silico Studies of Kayu Raja (Cassia fistula L.) Leaves Extract as Potential Antifungal Agent Against Candida albicans More recent articles
Most cited articles
Impregnasi Nikel Klorida pada Zeolit-Y untuk Katalis Hidrorengkah Minyak Bumi Pengolahan Limbah Cair Industri Batik dengan Metoda Elektrokoagulasi Menggunakan Besi Bekas Sebagai Elektroda Pengaruh Penambahan Surfaktan Hexadecyltrimethyl-Ammonium (HDTMA) pada Zeolit Alam Terdealuminasi terhadap Kemampuan Mengadsorpsi Fenol Skrining Metabolit Sekunder Bakteri Endofit yang Berfungsi sebagai Antidiabetes dari Daun Mimba (Azadirachta Indica) Activity of Actinomycetes Isolated from Mangrove Segara Anakan Cilacap toward Methicillin-resistant Staphylococcus aureus (MRSA) More cited articles
  1. Ainur Rosyida, Anik Zulfiya, Pewarnaan Bahan Tekstil dengan Menggunakan Ekstrak Kayu Nangka dan Teknik Pewarnaannya untuk Mendapatkan Hasil yang Optimal, Jurnal Rekayasa Proses, 7, 2, (2014), 7
  2. L. Qadariyah, N. Azizah, A. Q. Syafa’atullah, D. S. Bhuana, M. Mahfud, The Extraction of Natural Dyes from Henna Leaves (Lawsonia Inermis L.) by Ultrasound-assisted Method, IOP Conference Series: Materials Science and Engineering, 543, (2019), 012082 https://doi.org/10.1088/1757-899X/543/1/012082
  3. Achmad Qodim Syafa’atullah, Arie Amira, Sonya Hidayati, Mahfud Mahfud, Anthocyanin from butterfly pea flowers (Clitoria ternatea) by ultrasonic-assisted extraction, AIP Conference Proceedings, 2237, 1, (2020), https://doi.org/10.1063/5.0005289
  4. Syafaatullah Achmad Qodim, Yeni Variyana, Rohmah Ni’matur, Mufaidah Iid, A’yun Ayu Qurota, Optimization of Ultrasound-Assisted Extraction Parameters from Indigofera Tinctoria L using Response Surface Methodology, Journal of Research and Technology, 7, 2, (2021), 175-186
  5. Achmad Qodim, Kinetika Ekstraksi Pacar Kuku Lawsonia Inermis L. Menggunakan Ultrasound-Assisted Extraction dengan Pelarut Air, Jurnal Teknologi Kimia Mineral, 1, 2, (2022), 47-51 https://doi.org/10.61844/jtkm.v1i2.125
  6. Haqqyana Haqqyana, Ali Altway, Mahfud Mahfud, Kinetic modeling for microwave-assisted green extraction: Effects of power on citronella oil from Cymbopogon nardus leaf, International Journal of Applied Science and Engineering, 19, 4, (2022), 1-9 https://doi.org/10.6703/IJASE.202212_19(4).007
  7. Achmad Qodim, Dwi Setyorini, Renova Panjaitan, Yeni Variana, Ansori, Optimasi Ekstraksi Minyak Biji Alpukat dengan Pelarut N-Hexana, Jurnal Teknologi Kimia Mineral, 2, 1, (2023), 53-59 https://doi.org/10.61844/jtkm.v2i1.452
  8. Achmad Qodim Syafaatullah, Mahfud Mahfud, Optimization Extraction of Indigofera tinctoria L. using Microwave-assisted Extraction, IOP Conference Series: Materials Science and Engineering, 1053, 1, (2021), 012131 https://doi.org/10.1088/1757-899x/1053/1/012131
  9. Ansori Ansori, Mahfud Mahfud, Ultrasound assisted interesterification for biodiesel production from palm oil and methyl acetate: Optimization using RSM, Journal of Physics: Conference Series, 1747, (2021), 012044 https://www.doi.org/10.1088/1742-6596/1747/1/012044
  10. Haqqyana Haqqyana, Ali Altway, Mahfud Mahfud, Microwave-Assisted Hydrodistillation of Clove (Syzgium aromaticum) Stem Oil: Optimization and Chemical Constituents Analysis, Indonesian Journal of Chemistry, 21, 6, (2021), 13 https://doi.org/10.22146/ijc.64521
  11. Yurie Nurmitasari, Mahfud Mahfud, Optimization of Essential Oil Extraction from Dried Clove Leaves (Syzgium aromaticum) using Solvent-Free Microwave Extraction by Face-Centered Central Composite Design, IOP Conference Series: Materials Science and Engineering, 1053, (2021), 012121 https://doi.org/10.1088/1757-899x/1053/1/012121
  12. Dwi Setyorini, Achmad Qodim Syafaatullah, Yeni Variyana, Pengaruh Waktu dan Suhu Maserasi Terhadap Strength Gel Karaginan Eucheuma Cottonii dengan NaOH sebagai Pelarut, Jurnal Teknologi Kimia Mineral, 1, 2, (2022), 65-69 https://doi.org/10.61844/jtkm.v1i2.268
  13. Yuyun Yuniati, Achmad Qodim Syafa'atullah, Lailatul Qadariyah, Mahfud Mahfud, Ekstraksi Zat Warna Antosianin dari Bunga Telang (Clitoria ternatea L.) dengan Metode Ekstraksi Berbantuan Ultrasonik dan Aplikasinya Untuk Minuman, Journal of Chemical Process Engineering, 7, 2, (2022), 79-84 https://doi.org/10.33536/jcpe.v7i2.1184
  14. Dianasri Widyapuri, Ike Sitoresmi Mulyo Purbowati, Condro Wibowo, Pengaruh waktu ekstraksi menggunakan ultrasonic assisted extraction terhadap antosianin jantung pisang (Musa spp), Agrointek: Jurnal Teknologi Industri Pertanian, 16, 2, (2022), 235-244 https://doi.org/10.21107/agrointek.v16i2.12559
  15. D. B. Uma, C. W. Ho, W. M. Wan Aida, Optimization of extraction parameters of total phenolic compounds from Henna (Lawsonia inermis) leaves, Sains Malaysiana, 39, 1, (2010), 119-128
  16. Zuhdi Ma’sum, Donny S. Bhuana, Mahfud Mahfud, Kinetics study of microwave hydrodestillation (MHD) fresh and dried Cymbopogon Nardus leaves, 4th International Seminar on Chemistry, 2021 https://doi.org/10.1063/5.0051768
  17. Heri Septya Kusuma, Prilia Dwi Amelia, Cininta Admiralia, Mahfud Mahfud, Kinetics study of oil extraction from Citrus auranticum L. by solvent-free microwave extraction, Communications in Science and Technology, 1, 1, (2016), https://doi.org/10.21924/cst.1.1.2016.3
  18. H. S. Kusuma, M. Mahfud, Preliminary study: kinetics of oil extraction from sandalwood by microwave-assisted hydrodistillation, IOP Conference Series: Materials Science and Engineering, 128, (2016), 012009 https://doi.org/10.1088/1757-899X/128/1/012009
  19. F. Zulkifli, Nora’aini Ali, M. Sukeri M. Yusof, Wan M. Khairul, Rafizah Rahamathullah, M. I. N. Isa, W. B. Wan Nik, The Effect of Concentration of Lawsonia inermis as a Corrosion Inhibitor for Aluminum Alloy in Seawater, Advances in Physical Chemistry, 2017, (2017), 8521623 https://doi.org/10.1155/2017/8521623
  20. W. B. Wan Nik, F. Zulkifli, O. Sulaiman, K. B. Samo, R. Rosliza, Study of Henna (Lawsonia inermis) as Natural Corrosion Inhibitor for Aluminum Alloy in Seawater, IOP Conference Series: Materials Science and Engineering, 36, (2012), 012043 https://doi.org/10.1088/1757-899X/36/1/012043
  21. T. Chandrakalavathi, V. Sudha, M. Sindhuja, S. Harinipriya, R. Jeyalakshmi, Photosonoelectrochemical analysis of Lawsonia inermis (henna) and artificial dye used in tattoo and dye industry, Journal of Photochemistry and Photobiology A: Chemistry, 360, (2018), 44-57 https://doi.org/10.1016/j.jphotochem.2018.04.026
  22. S. H. S. Dananjaya, R. M. C. Udayangani, Sang Yeop Shin, M. Edussuriya, Chamilani Nikapitiya, Jehee Lee, Mahanama De Zoysa, In vitro and in vivo antifungal efficacy of plant based lawsone against Fusarium oxysporum species complex, Microbiological Research, 201, (2017), 21-29 https://doi.org/10.1016/j.micres.2017.04.011
  23. Nur Hanis Khaleeda Mohd Jamka, Syahida Suhaimi, Siti Radhiah Omar, Optimization of Dye Extraction from Turmeric (Curcuma Longa L.) and Henna Leaves (Lawsonia Inermis L.) in Dye Sensitized Solar Cell, 3rd International Seminar on Islam and Science 2020 (SAIS 2020), Malaysia, 2020
  24. Silvana Petzel-Witt, Sylvia I. Meier, Manfred Schubert-Zsilavecz, Stefan W. Toennes, Detection of lawsone (2-hydroxy-1,4-naphthoquinone) in henna treated hair, Forensic Science International, 297, (2019), 184-188 https://doi.org/10.1016/j.forsciint.2019.01.037

Last update:

No citation recorded.

Last update: 2024-11-20 06:45:11

No citation recorded.