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Methylene Blue Adsorption by Activated Carbon and Nano–Activated Carbon from Biomass Waste: A Review

Mindriany Syafila  -  Institut Teknologi Bandung, Indonesia
Qomarudin Helmy  -  Institut Teknologi Bandung, Indonesia
*Akhmad Masykur Hadi Musthofa  -  Institut Teknologi Bandung, Indonesia

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Dyes are becoming increasingly prevalent in wastewater, and their presence caused serious threats to the environment. One of the most widely used dyes is methylene blue which has been used in the textile industry to dye cotton, wool, and silk. As a solution to this problem, using biomass (usually considered agricultural or plantation waste) as activated carbon is an important issue. Because based on previous studies, these materials are not only abundant and affordable but also have high efficiency in removing dye. Therefore, this paper will provide a further review of the latest research on the use of activated carbon from biomass as an adsorbent for methylene blue, which includes the conversion process of biomass into activated carbon, the mechanism of methylene blue adsorption, the factors that influence adsorption process, and the characteristics of activated carbon. In addition, it also reviewed the implementation of nanotechnology on activated carbon from biomass to adsorb with methylene blue.

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Keywords: Biomass; activated carbon; methylene blue; nano-activated carbon

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Section: Review Article
Language : EN
  1. Abdulhameed, A.S., Firdaus Hum, N.N.M., Rangabhashiyam, S., Jawad, A.H., Wilson, L.D., Yaseen, Z.M., Al-Kahtani, A.A., Alothman, Z.A., 2021. Statistical modeling and mechanistic pathway for methylene blue dye removal by high surface area and mesoporous grass-based activated carbon using K2CO3activator. Journal of Environmental Chemical Engineering 9
  2. Adedokun, O., Roy, A., Awodugba, A.O., Devi, P.S., 2017. Fluorescent carbon nanoparticles from Citrus sinensis as efficient sorbents for pollutant dyes. Luminescence 32, 62–70
  3. Ahmad, M.A., Eusoff, M.A., Oladoye, P.O., Adegoke, K.A., Bello, O.S., 2021. Optimization and batch studies on adsorption of Methylene blue dye using pomegranate fruit peel based adsorbent. Chemical Data Collections 32
  4. Ahmad, M.A., Mohamad Yusop, M.F., Zakaria, R., Karim, J., Yahaya, N.K.E.M., Mohamed Yusoff, M.A., Hashim, N.H.F., Abdullah, N.S., 2020. Adsorption of methylene blue from aqueous solution by peanut shell based activated carbon. In: Materials Today: Proceedings. Elsevier Ltd, pp. 1246–1251
  5. al Jebur, L.A., Alwan, L.H., 2022. Development of nano-activated carbon and apply it for dyes removal from water. Water Practice and Technology 17, 297–310
  6. Balapure, K., Bhatt, N., Madamwar, D., 2015. Mineralization of reactive azo dyes present in simulated textile waste water using down flow microaerophilic fixed film bioreactor. Bioresource Technology 175, 1–7
  7. Baloo, L., Isa, M.H., Sapari, N. bin, Jagaba, A.H., Wei, L.J., Yavari, S., Razali, R., Vasu, R., 2021. Adsorptive removal of methylene blue and acid orange 10 dyes from aqueous solutions using oil palm wastes-derived activated carbons. Alexandria Engineering Journal 60, 5611–5629
  8. Bedmohata MA, Chaudhari AR, Singh SP, Choudhary, 2015. Adsorption Capacity of Activated Carbon Prepared by Chemical Activation of Lignin for the Removal of Methylene Blue Dye. International Journal of Advanced Research in Chemical Science (IJARCS) 2, 1–13
  9. Bello, M.O., Abdus-Salam, N., Adekola, F.A., Pal, U., 2021. Isotherm and kinetic studies of adsorption of methylene blue using activated carbon from ackee apple pods. Chemical Data Collections 31
  10. Chang, B., Guan, D., Tian, Y., Yang, Z., Dong, X., 2013. Convenient synthesis of porous carbon nanospheres with tunable pore structure and excellent adsorption capacity. Journal of Hazardous Materials 262, 256–264
  11. Dao, M.U., Le, H.S., Hoang, H.Y., Tran, V.A., Doan, V.D., Le, T.T.N., Sirotkin, A., Le, V.T., 2021. Natural core-shell structure activated carbon beads derived from Litsea glutinosa seeds for removal of methylene blue: Facile preparation, characterization, and adsorption properties. Environmental Research 198
  12. de Souza, C.C., de Souza, L.Z.M., Yılmaz, M., de Oliveira, M.A., da Silva Bezerra, A.C., da Silva, E.F., Dumont, M.R., Machado, A.R.T., 2022. Activated carbon of Coriandrum sativum for adsorption of methylene blue: Equilibrium and kinetic modeling. Cleaner Materials 3, 100052
  13. Do, T.H., Nguyen, V.T., Dung, N.Q., Chu, M.N., van Kiet, D., Ngan, T.T.K., van Tan, L., 2020. Study on methylene blue adsorption of activated carbon made from Moringa oleifera leaf. In: Materials Today: Proceedings. Elsevier Ltd, pp. 3405–3413
  14. Dutta, S., Gupta, B., Srivastava, S.K., Gupta, A.K., 2021. Recent advances on the removal of dyes from wastewater using various adsorbents: A critical review. Materials Advances
  15. Farnane, M., Tounsadi, H., Machrouhi, A., Elhalil, A., Mahjoubi, F.Z., Sadiq, M., Abdennouri, M., Qourzal, S., Barka, N., 2018. Dye removal from aqueous solution by raw maize corncob and h3po4 activated maize corncob. Journal of Water Reuse and Desalination 8, 214–224
  16. Fatkhasari, Y., Rouf, N.A., Ermadayanti, W.A., Kurniawan, R.Y., Bagastyo, A.Y., 2019. Synthesis of TiO2/Zeolite-A Composite for the Removal of Methylene Blue on Direct Sunlight. JURNAL TEKNIK ITS 8, 115–120
  17. Gupta, S.A., Vishesh, Y., Sarvshrestha, N., Bhardwaj, A.S., Kumar, P.A., Topare, N.S., Raut-Jadhav, S., Bokil, S.A., Khan, A., 2022. Adsorption isotherm studies of Methylene blue using activated carbon of waste fruit peel as an adsorbent. Materials Today: Proceedings 57, 1500–1508
  18. Han, Q., Wang, J., Goodman, B.A., Xie, J., Liu, Z., 2020. High adsorption of methylene blue by activated carbon prepared from phosphoric acid treated eucalyptus residue. Powder Technology 366, 239–248
  19. Hien Tran, T., Le, A.H., Pham, T.H., Duong, L.D., Nguyen, X.C., Nadda, A.K., Chang, S.W., Chung, W.J., Nguyen, D.D., Nguyen, D.T., 2022. A sustainable, low-cost carbonaceous hydrochar adsorbent for methylene blue adsorption derived from corncobs. Environmental Research 212, 113178
  20. Huang, R., Liu, X., Qi, F., Jia, L., Xu, D., Wang, L., Ma, P., 2022. Efficient preparation of carbon nanospheres-anchored porous carbon materials and the investigation on pretreatment methods. Bioresource Technology 344
  21. Jawad, A.H., Saud Abdulhameed, A., Wilson, L.D., Syed-Hassan, S.S.A., ALOthman, Z.A., Rizwan Khan, M., 2021. High surface area and mesoporous activated carbon from KOH-activated dragon fruit peels for methylene blue dye adsorption: Optimization and mechanism study. Chinese Journal of Chemical Engineering
  22. Khalil, K.M.S., Elhamdy, W.A., Mohammed, K.M.H., Said, A.E.A.A., 2022. Nanostructured P-doped activated carbon with improved mesoporous texture derived from biomass for enhanced adsorption of industrial cationic dye contaminants. Materials Chemistry and Physics 282
  23. Li, Z., Hanafy, H., Zhang, L., Sellaoui, L., Schadeck Netto, M., Oliveira, M.L.S., Seliem, M.K., Luiz Dotto, G., Bonilla-Petriciolet, A., Li, Q., 2020. Adsorption of congo red and methylene blue dyes on an ashitaba waste and a walnut shell-based activated carbon from aqueous solutions: Experiments, characterization and physical interpretations. Chemical Engineering Journal 388
  24. Mariana, M., Mistar, E.M., Alfatah, T., Supardan, M.D., 2021. High-porous activated carbon derived from Myristica fragrans shell using one-step KOH activation for methylene blue adsorption. Bioresource Technology Reports 16
  25. Mbarki, F., Selmi, T., Kesraoui, A., Seffen, M., 2022. Low-cost activated carbon preparation from Corn stigmata fibers chemically activated using H3PO4, ZnCl2 and KOH: Study of methylene blue adsorption, stochastic isotherm and fractal kinetic. Industrial Crops and Products 178
  26. Medhat, A., El-Maghrabi, H.H., Abdelghany, A., Abdel Menem, N.M., Raynaud, P., Moustafa, Y.M., Elsayed, M.A., Nada, A.A., 2021. Efficiently activated carbons from corn cob for methylene blue adsorption. Applied Surface Science Advances 3
  27. Misran, E., Bani, O., Situmeang, E.M., Purba, A.S., 2022. Banana stem based activated carbon as a low-cost adsorbent for methylene blue removal: Isotherm, kinetics, and reusability. Alexandria Engineering Journal 61, 1946–1955
  28. Muniyandi, M., Govindaraj, P., Bharath Balji, G., 2021. Potential removal of Methylene Blue dye from synthetic textile effluent using activated carbon derived from Palmyra (Palm) shell. In: Materials Today: Proceedings. Elsevier Ltd, pp. 299–311
  29. Naser, J.A., Ahmed, Z.W., Ali, E.H., 2021. Nanomaterials usage as adsorbents for the pollutants removal from wastewater; A review. In: Materials Today: Proceedings. Elsevier Ltd, pp. 2590–2595
  30. Nazem, M.A., Zare, M.H., Shirazian, S., 2020. Preparation and optimization of activated nano-carbon production using physical activation by water steam from agricultural wastes. RSC Advances 10, 1463–1475
  31. Neha, R., Adithya, S., Jayaraman, R.S., Gopinath, K.P., M, P., L, P., Arun, J., 2021. Nano-adsorbents an effective candidate for removal of toxic pharmaceutical compounds from aqueous environment: A critical review on emerging trends. Chemosphere 272
  32. Nik-Abdul-Ghani, Jami, Alam, 2021. The role of nanoadsorbents and nanocomposite adsorbents in the removal of heavy metals from wastewater: A review and prospect. Pollution 7, 153–179
  33. Pandey, N., Shukla, S.K., Singh, N.B., 2017. Water purification by polymer nanocomposites: an overview. Nanocomposites
  34. Pathania, D., Bhat, V.S., Mannekote Shivanna, J., Sriram, G., Kurkuri, M., Hegde, G., 2022. Garlic peel based mesoporous carbon nanospheres for an effective removal of malachite green dye from aqueous solutions: Detailed isotherms and kinetics. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 276, 121197
  35. R Ananthashankar, A.G., 2013. Production, Characterization and Treatment of Textile Effluents: A Critical Review. Journal of Chemical Engineering & Process Technology 05
  36. Rahmawati, F., Ridassepri, A.F., Chairunnisa, Wijayanta, A.T., Nakabayashi, K., Miyawaki, J., Miyazaki, T., 2021. Carbon from bagasse activated with water vapor and its adsorption performance for methylene blue. Applied Sciences (Switzerland) 11, 1–16
  37. Rani, S., Chaudhary, S., 2022. Adsorption of methylene blue and crystal violet dye from waste water using Citrus limetta peel as an adsorbent. Materials Today: Proceedings
  38. Sahoo, T.R., Prelot, B., 2020. Adsorption processes for the removal of contaminants from wastewater: The perspective role of nanomaterials and nanotechnology. In: Nanomaterials for the Detection and Removal of Wastewater Pollutants. Elsevier, pp. 161–222
  39. Saratale, R.G., Saratale, G.D., Chang, J.S., Govindwar, S.P., 2011. Bacterial decolorization and degradation of azo dyes: A review. J Taiwan Inst Chem Eng
  40. Seto, C., Chang, B.P., Tzoganakis, C., Mekonnen, T.H., 2021. Lignin derived nano-biocarbon and its deposition on polyurethane foam for wastewater dye adsorption. International Journal of Biological Macromolecules 185, 629–643
  41. Shelke, B.N., Jopale, M.K., Kategaonkar, A.H., 2022. Exploration of biomass waste as low cost adsorbents for removal of methylene blue dye: A review. Journal of the Indian Chemical Society
  42. Shokry, H., Elkady, M., Hamad, H., 2019. Nano activated carbon from industrial mine coal as adsorbents for removal of dye from simulated textile wastewater: Operational parameters and mechanism study. Journal of Materials Research and Technology 8, 4477–4488
  43. Shrestha, L., Thapa, M., Shrestha, R., Maji, S., Pradhananga, R., Ariga, K., 2019. Rice Husk-Derived High Surface Area Nanoporous Carbon Materials with Excellent Iodine and Methylene Blue Adsorption Properties. C (Basel) 5, 10
  44. Song, X., Wang, Y., Wang, K., Xu, R., 2012. Low-cost carbon nanospheres for efficient removal of organic dyes from aqueous solutions. Industrial and Engineering Chemistry Research 51, 13438–13444
  45. Sultana, M., Rownok, M.H., Sabrin, M., Rahaman, M.H., Alam, S.M.N., 2022. A review on experimental chemically modified activated carbon to enhance dye and heavy metals adsorption. Cleaner Engineering and Technology
  46. Sulyman, M., Namiesnik, J., Gierak, A., 2017. Low-cost adsorbents derived from agricultural by-products/wastes for enhancing contaminant uptakes from wastewater: A review. Polish Journal of Environmental Studies
  47. Tuli, F.J., Hossain, A., Kibria, A.K.M.F., Tareq, A.R.M., Mamun, S.M.M.A., Ullah, A.K.M.A., 2020. Removal of methylene blue from water by low-cost activated carbon prepared from tea waste: A study of adsorption isotherm and kinetics. Environmental Nanotechnology, Monitoring and Management 14
  48. Velusamy, S., Roy, A., Sundaram, S., Kumar Mallick, T., 2021. A Review on Heavy Metal Ions and Containing Dyes Removal Through Graphene Oxide-Based Adsorption Strategies for Textile Wastewater Treatment. Chemical Record
  49. Xue, H., Wang, X., Xu, Q., Dhaouadi, F., Sellaoui, L., Seliem, M.K., ben Lamine, A., Belmabrouk, H., Bajahzar, A., Bonilla-Petriciolet, A., Li, Z., Li, Q., 2022. Adsorption of methylene blue from aqueous solution on activated carbons and composite prepared from an agricultural waste biomass: A comparative study by experimental and advanced modeling analysis. Chemical Engineering Journal 430
  50. Yao, X., Ji, L., Guo, J., Ge, S., Lu, W., Cai, L., Wang, Y., Song, W., Zhang, H., 2020. Magnetic activated biochar nanocomposites derived from wakame and its application in methylene blue adsorption. Bioresource Technology 302
  51. Yaseen, D.A., Scholz, M., 2019. Textile dye wastewater characteristics and constituents of synthetic effluents: a critical review. International Journal of Environmental Science and Technology
  52. Yusop, M.F.M., Ahmad, M.A., Rosli, N.A., Manaf, M.E.A., 2021. Adsorption of cationic methylene blue dye using microwave-assisted activated carbon derived from acacia wood: Optimization and batch studies. Arabian Journal of Chemistry 14
  53. Zakaria, R., Jamalluddin, N.A., Abu Bakar, M.Z., 2021. Effect of impregnation ratio and activation temperature on the yield and adsorption performance of mangrove based activated carbon for methylene blue removal. Results in Materials 10
  54. Zhang, Z., Xu, L., Liu, Y., Feng, R., Zou, T., Zhang, Y., Kang, Y., Zhou, P., 2021. Efficient removal of methylene blue using the mesoporous activated carbon obtained from mangosteen peel wastes: Kinetic, equilibrium, and thermodynamic studies. Microporous and Mesoporous Materials 315

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