DOI: https://doi.org/10.14710/ijred.7.2.159-162

Synthesis A Flexible Conductive Film of Poly 3,4-Ethylenedioxythiophene Polystyrene Sulfonate (PEDOT: PSS) Using Spray Pyrolysis Method

Department of Chemical Engineering, Faculty of Engineering, Universitas Diponegoro, Indonesia, Indonesia

Published: 10 Jul 2018.
Editor(s): H Hadiyanto

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Abstract

Popularity of conducting polymers are become widely known and researches for practical application also has been done. In order to developed a continuous process for industrial scale,  we have proposed a spray pyrolysis method to synthesis a flexible conductive film of Poly(3,4-ethylenedioxythiophene) poly(styrene sulfonate) (PEDOT:PSS) on poly(ethylene terephthalate) (PET) and annealed at different temperatures and spray distances. The optimum condition that resulting a best morphology was anneal at 90oC and 20 cm distance with electrical conductivity 4.5 S/cm. It was found that annealing at temperature higher than 90oC will resulting a stress to a film and formed crack due to a different thermal expansion, while at the distance higher than 20 cm resulting a loss of PEDOT:PSS droplets. IR spectra shows that there is no any sign of PEDOT:PSS degradation even at 110oC. SEM analysis also show that the thickness is well distributed and there is no any sign of crack formed

Article History: Received February 24th 2017; Received in revised form May 16th 2018; Accepted May 20th 2018; Available online

How to Cite This Article: Tarmidzi, F.M. and Sasongko, S.B. (2018) Synthesis A Flexible Conductive Film of Poly 3,4-Ethylenedioxythiophene Polystyrene Sulfonate (PEDOT:PSS) Using Spray Pyrolysis Method. Int. Journal of Renewable Energy Development, 7(2), 159-162.

https://doi.org/10.14710/ijred.7.2.159-162

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Keywords: PEDOT:PSS; PET; Conductive polymer; Spray pyrolysis; flexible film

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Section: Original Research Article
Language : EN
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  1. Al-Ibrahim, M., Roth, H. K., Schroedner, M., Konkin, A., Zhokhavets, U., Gobsch, G., Scharff, S., & Sensfuss, S. (2005). The influence of the optoelectronic properties of poly(3-alkylthiophenes) on the device parameters in flexible polymer solar cells. Organic Electronics: Physics, Materials, Applications, 6(2), 65-77
  2. Braun, D., & Hegger, A. J. (1991). Visible light emission from semiconducting polymer diodes. Appl. Phys. Lett. 58, 1982
  3. Goodfellow. (2003). Polyethylene Terephthalate Polyester (PET, PETP) - Properties and Applications - Supplier Data
  4. Hutchinson, J. W., & Jensen, H. M. (1996). Stresses and Failure Modes in Thin Films and Multilayers. Division of Engineering and Applied Sciences. Harvard University
  5. Im, S. G., Kusters, D., Choi, W., Baxamusa, S. H., van de Sanden, M. C. M., & Gleason, K. K. (2008). Conformal coverage of poly(3,4-ethylenedioxythiophene) films with tunable nanoporosity via oxidative chemical vapor deposition. ACS Nano. 2 (9), 1959–1967
  6. Khan, N. Z., & Brunswick, N. (2017). Modeling and Simulation of Organic MEM Relay for Estimating the Coefficient of Thermal Expansion of PEDOT:PSS. The State of University of New Jersey
  7. Lang, U., Naujoks, N., & Dual, J. (2009). Mechanical characterization of PEDOT : PSS thin films. Synthetic Metals, 159(5-6), 473-479
  8. Louwet, F., Groenendaal, L., Dhaen, J., Manca, J., Van Luppen, J., Verdonck, E., & Leenders, L. (2003). PEDOT/PSS: synthesis, characterization, properties and applications. Synthetic Metals, 135-136, 115-117
  9. Na, S., Wang, G., Kim, S., Kim, T., Oh, S., Yu, B., Lee, T., & Kim, D. (2009). Evolution of nanomorphology and anisotropic conductivity in solvent-modified PEDOT : PSS films for polymeric anodes of polymer solar cells. Journal of Materials Chemistry, 19, 9045-9053
  10. Perednis, D. (2003). Thin Film Deposition by Spray Pyrolysis and the Application in Solid Oxide Fuel Cells. ETH Zurich. https://doi.org/10.3929/ethz-a-004637544
  11. Saran, N., Parikh, K., Suh, D.-S., Muñoz, E., Kolla, H., & Manohar, S. K. (2004). Fabrication and Characterization of Thin Films of Single-Walled Carbon Nanotube Bundles on Flexible Plastic Substrates. Journal of the American Chemical Society. 26 (14), 4462–4463
  12. Sears, W. M., & Gee, M. A. (1988). Mechanics of film formation during the spray pyrolysis of tin oxide. Thin Solid Films., 165(1), 265-277
  13. Shi, X., Zhou, W., Ma, D., Ma, Q., Bridges, D., Ma, Y., & Hu, A. (2015). Electrospinning of Nanofibers and Their Applications for Energy Devices. Journal of Nanomaterials, 2015, Article ID 140716
  14. Shinar, J. (2004). Organic Light-Emitting Devices: A Survey. Iowa State University
  15. Vigui, J. C., & Spitz, J. (1975). Chemical vapor deposition at low temperatures. J. Electrochem. Soc.: SOLID-STATE SCIENCE AND TECHNOLOGY, 122(4), 585-588
  16. Yu, H.-F., & Liao, W.-H. (1998). Evaporation of solution droplets in spray pyrolysis. International Journal of Heat and Mass Transfer, 41(8-9), 993-1001
  17. Zhao, Q., Jamal, R., Zhang, L., Wang, M., & Abdiryim, T. (2014). The structure and properties of PEDOT synthesized by template-free solution method. Nanoscale Research Letters. 9(1): 557

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