Synthesis A Flexible Conductive Film of Poly 3,4-Ethylenedioxythiophene Polystyrene Sulfonate (PEDOT: PSS) Using Spray Pyrolysis Method

*Fadhil Muhammad Tarmidzi -  Department of Chemical Engineering, Faculty of Engineering, Universitas Diponegoro, Indonesia, Indonesia
Setia Budi Sasongko -  Department of Chemical Engineering, Faculty of Engineering, Universitas Diponegoro, Indonesia, Indonesia
Published: 10 Jul 2018.
Open Access Copyright (c) 2018 International Journal of Renewable Energy Development
Citation Format:
Article Info
Section: Original Research Article
Language: EN
Full Text:
In Vol 7, No 2 (2018): July 2018
Statistics: 719 340
Abstract

Popularity of conducting polymers are become widely known and researches for practical application also has been done. In order to developed a continuous process for industrial scale,  we have proposed a spray pyrolysis method to synthesis a flexible conductive film of Poly(3,4-ethylenedioxythiophene) poly(styrene sulfonate) (PEDOT:PSS) on poly(ethylene terephthalate) (PET) and annealed at different temperatures and spray distances. The optimum condition that resulting a best morphology was anneal at 90oC and 20 cm distance with electrical conductivity 4.5 S/cm. It was found that annealing at temperature higher than 90oC will resulting a stress to a film and formed crack due to a different thermal expansion, while at the distance higher than 20 cm resulting a loss of PEDOT:PSS droplets. IR spectra shows that there is no any sign of PEDOT:PSS degradation even at 110oC. SEM analysis also show that the thickness is well distributed and there is no any sign of crack formed

Article History: Received February 24th 2017; Received in revised form May 16th 2018; Accepted May 20th 2018; Available online

How to Cite This Article: Tarmidzi, F.M. and Sasongko, S.B. (2018) Synthesis A Flexible Conductive Film of Poly 3,4-Ethylenedioxythiophene Polystyrene Sulfonate (PEDOT:PSS) Using Spray Pyrolysis Method. Int. Journal of Renewable Energy Development, 7(2), 159-162.

https://doi.org/10.14710/ijred.7.2.159-162

Keywords
PEDOT:PSS; PET; Conductive polymer; Spray pyrolysis; flexible film

Article Metrics:

  1. Al-Ibrahim, M., Roth, H. K., Schroedner, M., Konkin, A., Zhokhavets, U., Gobsch, G., Scharff, S., & Sensfuss, S. (2005). The influence of the optoelectronic properties of poly(3-alkylthiophenes) on the device parameters in flexible polymer solar cells. Organic Electronics: Physics, Materials, Applications, 6(2), 65-77.
  2. Braun, D., & Hegger, A. J. (1991). Visible light emission from semiconducting polymer diodes. Appl. Phys. Lett. 58, 1982
  3. Goodfellow. (2003). Polyethylene Terephthalate Polyester (PET, PETP) - Properties and Applications - Supplier Data.
  4. Hutchinson, J. W., & Jensen, H. M. (1996). Stresses and Failure Modes in Thin Films and Multilayers. Division of Engineering and Applied Sciences. Harvard University.
  5. Im, S. G., Kusters, D., Choi, W., Baxamusa, S. H., van de Sanden, M. C. M., & Gleason, K. K. (2008). Conformal coverage of poly(3,4-ethylenedioxythiophene) films with tunable nanoporosity via oxidative chemical vapor deposition. ACS Nano. 2 (9), 1959–1967
  6. Khan, N. Z., & Brunswick, N. (2017). Modeling and Simulation of Organic MEM Relay for Estimating the Coefficient of Thermal Expansion of PEDOT:PSS. The State of University of New Jersey.
  7. Lang, U., Naujoks, N., & Dual, J. (2009). Mechanical characterization of PEDOT : PSS thin films. Synthetic Metals, 159(5-6), 473-479.
  8. Louwet, F., Groenendaal, L., Dhaen, J., Manca, J., Van Luppen, J., Verdonck, E., & Leenders, L. (2003). PEDOT/PSS: synthesis, characterization, properties and applications. Synthetic Metals, 135-136, 115-117.
  9. Na, S., Wang, G., Kim, S., Kim, T., Oh, S., Yu, B., Lee, T., & Kim, D. (2009). Evolution of nanomorphology and anisotropic conductivity in solvent-modified PEDOT : PSS films for polymeric anodes of polymer solar cells. Journal of Materials Chemistry, 19, 9045-9053.
  10. Perednis, D. (2003). Thin Film Deposition by Spray Pyrolysis and the Application in Solid Oxide Fuel Cells. ETH Zurich. https://doi.org/10.3929/ethz-a-004637544.
  11. Saran, N., Parikh, K., Suh, D.-S., Muñoz, E., Kolla, H., & Manohar, S. K. (2004). Fabrication and Characterization of Thin Films of Single-Walled Carbon Nanotube Bundles on Flexible Plastic Substrates. Journal of the American Chemical Society. 26 (14), 4462–4463
  12. Sears, W. M., & Gee, M. A. (1988). Mechanics of film formation during the spray pyrolysis of tin oxide. Thin Solid Films., 165(1), 265-277
  13. Shi, X., Zhou, W., Ma, D., Ma, Q., Bridges, D., Ma, Y., & Hu, A. (2015). Electrospinning of Nanofibers and Their Applications for Energy Devices. Journal of Nanomaterials, 2015, Article ID 140716.
  14. Shinar, J. (2004). Organic Light-Emitting Devices: A Survey. Iowa State University.
  15. Vigui, J. C., & Spitz, J. (1975). Chemical vapor deposition at low temperatures. J. Electrochem. Soc.: SOLID-STATE SCIENCE AND TECHNOLOGY, 122(4), 585-588.
  16. Yu, H.-F., & Liao, W.-H. (1998). Evaporation of solution droplets in spray pyrolysis. International Journal of Heat and Mass Transfer, 41(8-9), 993-1001.
  17. Zhao, Q., Jamal, R., Zhang, L., Wang, M., & Abdiryim, T. (2014). The structure and properties of PEDOT synthesized by template-free solution method. Nanoscale Research Letters. 9(1): 557

The Authors submitting a manuscript do so on the understanding that if accepted for publication, copyright of the article shall be assigned to International Journal of Renewable Energy Development and Center of Biomass and Renewable Energy, Department of Chemical Engineering Diponegoro University as publisher of the journal.

Copyright encompasses exclusive rights to reproduce and deliver the article in all form and media, including reprints, photographs, microfilms and any other similar reproductions, as well as translations. The reproduction of any part of this journal, its storage in databases and its transmission by any form or media, such as electronic, electrostatic and mechanical copies, photocopies, recordings, magnetic media, etc. , will be allowed only with a written permission from International Journal of Renewable Energy Development and Center of Biomass and Renewable Energy, Department of Chemical Engineering Diponegoro University.

International Journal of Renewable Energy Development and Center of Biomass and Renewable Energy, Department of Chemical Engineering Diponegoro University, the Editors and the Advisory International Editorial Board make every effort to ensure that no wrong or misleading data, opinions or statements be published in the journal. In any way, the contents of the articles and advertisements published in the International Journal of Renewable Energy Development are sole and exclusive responsibility of their respective authors and advertisers.