Pengaruh Penambahan Natrium Tripolifosfat dan pH terhadap Detergensi Surfaktan Hasil Sublasi

Chandra Ady Nugroho; Arnelli Arnelli; Ahmad Suseno

doi:10.14710/jksa.12.2.61-65

DOI: https://doi.org/10.14710/jksa.12.2.61-65

Pengaruh Penambahan Natrium Tripolifosfat dan pH terhadap Detergensi Surfaktan Hasil Sublasi

Chandra Ady Nugroho, Arnelli Arnelli

, Ahmad Suseno

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Indonesia

Published: 1 Aug 2009.

BibTex Citation Data :

@article{JKSA15212,
    author = {Chandra Nugroho and Arnelli Arnelli and Ahmad Suseno},
    title = {Pengaruh Penambahan Natrium Tripolifosfat dan pH terhadap Detergensi Surfaktan Hasil Sublasi},
    journal = {Jurnal Kimia Sains dan Aplikasi},
  volume = {12},
    number = {2},
    year = {2009},
    keywords = {Sublasi; detergensi; STPP; Surfaktan; LAS; ABS},
    abstract = {Telah dilakukan penelitian tentang pengaruh penambahan natrium tripolifosfat dan pH terhadap detergensi surfaktan hasil sublasi limbah cair cucian. Bahan utama penyusun detergen adalah surfaktan yang dapat mencemari lingkungan, antara lain branched-alkilbenzen sulfonat (ABS) dan linier-alkilbenzen sulfonat (LAS). Surfaktan ABS dengan rantai alkil bercabang, bersifat tidak terbiodegradasi, yaitu tidak dapat diurai oleh mikroorganisme dan menyebabkan polusi pada perairan di lingkungan. Metode pengambilan surfaktan salah satunya dapat dilakukan dengan metode sublasi yang dapat mengurangi pencemaran lingkungan. Penelitian dilakukan melalui tiga tahap yaitu sublasi limbah cair cucian, karakterisasi surfaktan hasil sublasi dan detergensi surfaktan hasil sublasi. Sublasi limbah cair cucian dilakukan dengan penambahan garam NaCl dan NaHCO3. Karakterisasi surfaktan hasil sublasi menggunakan metode FTIR (Fourier Transform Infra Red). Detergensi surfaktan hasil sublasi dengan menggunakan builder Natrium Tripolifosfat (STPP) dan pengaturan pH. Hasil penelitian menunjukkan surfaktan yang diperoleh dari hasil sublasi berwarna putih keabu-abuan. Spektra FTIR menunjukkan adanya gugus alkil, terdapat pada bilangan gelombang 2931,80 cm-1,sulfonat pada 1411,89 cm-1, cincin aromatis pada 1573,91 cm-1 dan benzena pada 1118,71cm-1 yang menunjukkan hasil sublasi adalah surfaktan LAS. Hasil detergensi diperoleh detergensi optimum 74,51 % pada konsentrasi surfaktan 23 %, konsentrasi STPP sebesar 60 % (b/b) dan pH sebesar 11,5.},
   issn = {2597-9914},   pages = {61--65}  doi = {10.14710/jksa.12.2.61-65},
    url = {https://ejournal.undip.ac.id/index.php/ksa/article/view/15212}
}

Citation Format:

Abstract

Telah dilakukan penelitian tentang pengaruh penambahan natrium tripolifosfat dan pH terhadap detergensi surfaktan hasil sublasi limbah cair cucian. Bahan utama penyusun detergen adalah surfaktan yang dapat mencemari lingkungan, antara lain branched-alkilbenzen sulfonat (ABS) dan linier-alkilbenzen sulfonat (LAS). Surfaktan ABS dengan rantai alkil bercabang, bersifat tidak terbiodegradasi, yaitu tidak dapat diurai oleh mikroorganisme dan menyebabkan polusi pada perairan di lingkungan. Metode pengambilan surfaktan salah satunya dapat dilakukan dengan metode sublasi yang dapat mengurangi pencemaran lingkungan. Penelitian dilakukan melalui tiga tahap yaitu sublasi limbah cair cucian, karakterisasi surfaktan hasil sublasi dan detergensi surfaktan hasil sublasi. Sublasi limbah cair cucian dilakukan dengan penambahan garam NaCl dan NaHCO3. Karakterisasi surfaktan hasil sublasi menggunakan metode FTIR (Fourier Transform Infra Red). Detergensi surfaktan hasil sublasi dengan menggunakan builder Natrium Tripolifosfat (STPP) dan pengaturan pH. Hasil penelitian menunjukkan surfaktan yang diperoleh dari hasil sublasi berwarna putih keabu-abuan. Spektra FTIR menunjukkan adanya gugus alkil, terdapat pada bilangan gelombang 2931,80 cm-1,sulfonat pada 1411,89 cm-1, cincin aromatis pada 1573,91 cm-1 dan benzena pada 1118,71cm-1 yang menunjukkan hasil sublasi adalah surfaktan LAS. Hasil detergensi diperoleh detergensi optimum 74,51 % pada konsentrasi surfaktan 23 %, konsentrasi STPP sebesar 60 % (b/b) dan pH sebesar 11,5.

Fulltext View|Download

Keywords: Sublasi; detergensi; STPP; Surfaktan; LAS; ABS

Article Metrics:

Article Info

Section: Research Articles

Language : ID

In Vol 12, No 2 (2009): Volume 12 Issue 2 Year 2009

Recent articles

Isolasi, Identifikasi dan Uji Aktivitas Antibakteri Minyak Atsiri Akar Sidaguri (Sida rhombifolia Linn) Pengaruh Penambahan Natrium Tripolifosfat dan pH terhadap Detergensi Surfaktan Hasil Sublasi Efek NaCl dan Anode Besi terhadap Rendemen Mg(OH)2 pada Elektrolisis Sistem Fe|MgSO4,NaCl||H2O|C More recent articles

Most cited articles

Profil Kandungan Protein dan Tekstur Tahu Akibat Penambahan Fitat pada Proses Pembuatan Tahu Studi Filogeni dan Uji Potensi Bioremediasi serta Enzim Termostabil Ekstraseluler Isolat Geobacillus sp. dari Sumber Air Panas Gedong Songo Pengolahan Limbah Cair Industri Batik dengan Metoda Elektrokoagulasi Menggunakan Besi Bekas Sebagai Elektroda Uji Aktivitas Antioksidan Senyawa Flavonoid dari Ekstrak Etanol Daun Johar (Senna siamea Lamk) Modifikasi Zeolit Alam Menggunakan TiO2 sebagai Fotokatalis Zat Pewarna Indigo Carmine More cited articles

Jesús Campos-García, Abraham Esteve, Rafael Vázquez-Duhalt, Juán Luis Ramos, Gloria Soberón-Chávez, The branched-chain dodecylbenzene sulfonate degradation pathway of Pseudomonas aeruginosa W51D involves a novel route for degradation of the surfactant lateral alkyl chain, Applied and environmental microbiology, 65 (1999) 3730-3734
R. A. Bailey, H. M. Clark, C. P. Feris, S. Krause, R. L. Strong, Chemistry of the Enviromental, in, Academic Press, New York, 1978
Pornsawan Visoottiviseth, Siwilai Ekachote, E. Suchart Upatham, Microbial Degradation of Anionic Detergent in Natural Water, Journal of The Science Society of Thailand, 14 (1988)
Lenore S Clesceri, American Public Health Association, Standard methods for the examination of water and wastewater, 17 ed., American Public Health Association Washington, DC, 1996
George Frederick Longman, Analysis of Detergents and Detergent Products, Wiley, 1976
S Pastewski, K Medrzycka, Monitoring surfactant concentrations in surface waters in Tricity agglomeration, Polish Journal of Environmental Studies, 12 (2003) 643-646
Mazen Ahmed Muherei, Radzuan Junin, Investigating synergism in critical micelle concentration of anionic-nonionic surfactant mixtures before and after equilibration with shale, Journal Of Applied Sciences Research, 5 (2009) 181-189
Parichat Tanthakit, Ampika Nakrachata-Amorn, John F Scamehorn, David A Sabatini, Chantra Tongcumpou, Sumaeth Chavadej, Microemulsion formation and detergency with oily soil: V. Effects of water hardness and builder, Journal of surfactants and detergents, 12 (2009) 173-183
Milton J. Rosen, Surfactants and interfacial phenomena, Wiley, 1978

Last update:

No citation recorded.

Last update: 2024-11-11 14:14:57

No citation recorded.

As an article writer, the author has the right to use their articles for various purposes, including use by institutions that employ authors or institutions that provide funding for research. Author rights are granted without special permission.

Author who publishes a paper at JKSA has the broad right to use their work for teaching and scientific purposes without the need to ask permission, including: used for (i) teaching in the author's class or institution, (ii) presentation at meetings or conferences and distributing copies to participants ; (iii) training conducted by the author or author's institution; (iv) distribution to colleagues for research use; (v) use in the compilation of subsequent authors' works; (vi) inclusion in a thesis or dissertation; (vi) reuse of part of the article in another work (with citation); (vii) preparation of derivative works (with citation); (viii) voluntary posting on open websites operated by authors or author institutions for scientific purposes (follow the CC BY-SA License).

Authors and readers can copy and redistribute material in any media or format, and mix, modify, and build material for any purpose but they must provide appropriate credit (provide article citation or content), providing links to the license, and indicate if there are changes.

The authors submitting a manuscript do so on the understanding that if accepted for publication, copyright of the article shall be assigned to Jurnal Kimia Sains dan Aplikasi (JKSA). Copyright encompasses rights to reproduce and deliver the article in all form and media, including reprints, photographs, microfilms and any other similar reproductions, as well as translations.

Reproduce any part of this journal, its storage in the database or its transmission by all forms or media is permitted does not need for written permission from JKSA. However, it should be cited as an honor in academic manners

JKSA and the Chemistry Department of Diponegoro University and the Editor make every effort to ensure that there are no data, opinions, or false or misleading statements published in JKSA. However, the content of the article is the sole and exclusive responsibility of each author.

The Copyright Transfer Form can be downloaded here: [Copyright Transfer Form - Indonesian] [Copyright Transfer Form - English]. The copyright form should be signed originally and send to the Editor in the form of printed letters, scanned documents sent via email or fax.

Adi Darmawan, Ph.D (Editor in Chief)

Editor in chief of Jurnal Kimia Sains dan Aplikasi (JKSA)

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University

Jl. Prof. Soedarto, Kampus Undip Tembalang, Semarang, Central Java, Indonesia 50275
Email: jksa@live.undip.ac.id