Pengaruh Penambahan Surfaktan pada Sintesis Zeolit Y Menggunakan Tetraethyl Orthosilicate (TEOS) sebagai Sumber Silika

Alfi Nurlaela; Sriatun Sriatun; Pardoyo Pardoyo

doi:10.14710/jksa.14.2.32-36

DOI: https://doi.org/10.14710/jksa.14.2.32-36

Pengaruh Penambahan Surfaktan pada Sintesis Zeolit Y Menggunakan Tetraethyl Orthosilicate (TEOS) sebagai Sumber Silika

Alfi Nurlaela, Sriatun Sriatun

, Pardoyo Pardoyo

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Indonesia

Published: 1 Aug 2011.

BibTex Citation Data :

@article{JKSA17418,
    author = {Alfi Nurlaela and Sriatun Sriatun and Pardoyo Pardoyo},
    title = {Pengaruh Penambahan Surfaktan pada Sintesis Zeolit Y Menggunakan Tetraethyl Orthosilicate (TEOS) sebagai Sumber Silika},
    journal = {Jurnal Kimia Sains dan Aplikasi},
  volume = {14},
    number = {2},
    year = {2011},
    keywords = {Zeolit Y; Surfaktan; CTAB; TMACl; TEOS},
    abstract = {Zeolit alam mempunyai ukuran pori yang beragam antara 3 Å hingga 8 Å, sehingga tidak efektif untuk mengadsorpsi senyawa yang berukuran besar. Zeolit sintetik (zeolit Y) dikembangkan untuk mengatasi kelemahan dari zeolit alam. Zeolit Y dapat disintesis dengan  Tetraethyl orthosilicate  (TEOS) sebagai sumber silika dan surfaktan sebagai pencetak pori. Surfaktan dapat mengarahkan struktur zeolit menjadi pori yang lebih besar. Penelitian ini bertujuan memperoleh zeolit Y sintetik dan mengkaji pengaruh surfaktan  Cetyltrimethylammonium Bromide  (CTAB) dan  Trimethylammonium Chloride  (TMACl) terhadap kristanilitas dan ukuran pori zeolit Y. Sintesis zeolit Y dilakukan dengan mencampurkan natrium aluminat, surfaktan dan TEOS. Perbandingan mol natrium aluminat:TEOS adalah 1:1 sedangkan konsentrasi surfaktan 1 M. Struktur dan kristalinitas zeolit Y dianalisis menggunakan FTIR ( Fourier Transform Infra Red ) dan XRD ( X-Ray Diffraction ). Sedangkan morfologi pori zeolit Y dianalisis menggunakan adsorpsi gas N 2  dengan persamaan BET. Hasil karakterisasi XRD dan FTIR menunjukkan sampel MC (tanpa penambahan surfaktan) merupakan zeolit Y, sedangkan sampel MA (penambahan surfaktan CTAB) dan MB (penambahan surfaktan TMACl) merupakan campuran zeolit HS dan NAS. Sampel MC memiliki kristalinitas tertinggi sedangkan sampel MB paling rendah. Radius pori rata-rata sampel MA, MB dan MC berturut-turut adalah 13,770 Å; 14,029 Å dan 12,962 Å. Sehingga disimpulkan bawah penambahan surfaktan tidak berpengaruh signifikan terhadap ukuran pori.},
   issn = {2597-9914},   pages = {32--36}  doi = {10.14710/jksa.14.2.32-36},
    url = {https://ejournal.undip.ac.id/index.php/ksa/article/view/17418}
}

Citation Format:

Abstract

Zeolit alam mempunyai ukuran pori yang beragam antara 3 Å hingga 8 Å, sehingga tidak efektif untuk mengadsorpsi senyawa yang berukuran besar. Zeolit sintetik (zeolit Y) dikembangkan untuk mengatasi kelemahan dari zeolit alam. Zeolit Y dapat disintesis dengan Tetraethyl orthosilicate (TEOS) sebagai sumber silika dan surfaktan sebagai pencetak pori. Surfaktan dapat mengarahkan struktur zeolit menjadi pori yang lebih besar. Penelitian ini bertujuan memperoleh zeolit Y sintetik dan mengkaji pengaruh surfaktan Cetyltrimethylammonium Bromide (CTAB) dan Trimethylammonium Chloride (TMACl) terhadap kristanilitas dan ukuran pori zeolit Y. Sintesis zeolit Y dilakukan dengan mencampurkan natrium aluminat, surfaktan dan TEOS. Perbandingan mol natrium aluminat:TEOS adalah 1:1 sedangkan konsentrasi surfaktan 1 M. Struktur dan kristalinitas zeolit Y dianalisis menggunakan FTIR (Fourier Transform Infra Red) dan XRD (X-Ray Diffraction). Sedangkan morfologi pori zeolit Y dianalisis menggunakan adsorpsi gas N₂ dengan persamaan BET. Hasil karakterisasi XRD dan FTIR menunjukkan sampel MC (tanpa penambahan surfaktan) merupakan zeolit Y, sedangkan sampel MA (penambahan surfaktan CTAB) dan MB (penambahan surfaktan TMACl) merupakan campuran zeolit HS dan NAS. Sampel MC memiliki kristalinitas tertinggi sedangkan sampel MB paling rendah. Radius pori rata-rata sampel MA, MB dan MC berturut-turut adalah 13,770 Å; 14,029 Å dan 12,962 Å. Sehingga disimpulkan bawah penambahan surfaktan tidak berpengaruh signifikan terhadap ukuran pori.

Fulltext View|Download Email colleagues

Keywords: Zeolit Y; Surfaktan; CTAB; TMACl; TEOS

Article Metrics:

Article Info

Section: Research Articles

Language : ID

In Vol 14, No 2 (2011): Volume 14 Issue 2 Year 2011

Most cited articles

Pengaruh Serbuk Kaca dan Variasi Suhu Pembakaran pada Pembuatan Genteng Lempung Sedimentasi Banjir Kanal Timur Kota Semarang terhadap Kuat Tekan serta Daya Serapnya terhadap Air Conversion of Wood Waste to be a Source of Alternative Liquid Fuel Using Low Temperature Pyrolysis Method Pemanfaatan Limbah Penyulingan Bunga Kenanga sebagai Kompos dan Pengaruh Penambahan Zeolit terhadap Ketersediaan Nitrogen Tanah Analisis Pangan: Penentuan Angka Peroksida dan Asam Lemak Bebas pada Minyak Kedelai dengan Variasi Menggoreng Biolubrication Synthesis Made from Used Cooking Oil and Bayah Natural Zeolite Catalyst More cited articles

Jens Weitkamp, Lothar Puppe, Catalysis and Zeolites, Fundamentals and Applications, Springer-Verlag Berlin Heidelberg, Berlin, 1999
Ying Zhang, Chao Jin, Yuguo Shen, Ying Cao, Wei Gao, Lishan Cui, Nonionic emulsion-mediated synthesis and characterization of Zeolite Y, Journal of Sol-Gel Science and Technology, 54, 2, (2010) 212-219 http://dx.doi.org/10.1007/s10971-010-2185-x
H Faghihian, N Godazandeha, Synthesis of nano crystalline zeolite Y from bentonite, Journal of Porous Materials, 16, 3, (2009) 331-335 https://doi.org/10.1007/s10934-008-9204-0
Yang Sian Chen, Jing Nang Lee, Sheng You Tsai, Chen Ching Ting, Manufacture of dye-sensitized nano solar cells and their IV curve measurements, Materials Science Forum, (2008)
Yuhong Wang, Son-Ki Ihm, Guanzhong Lu, The studies of hydrodesulfurization activity over molybdenum catalysts supported on Al-MCM-41 modified by lanthanum, Reaction Kinetics and Catalysis Letters, 92, 1, (2007) 165-173 https://doi.org/10.1007/s11144-007-5061-0
George G. Odian, Principles of Polymerization, 3 ed., Wiley-Interscience publication, 1991
Milton J Rosen, Joy T Kunjappu, Surfactants and interfacial phenomena, John Wiley & Sons, 2012

Last update:

Effect of silica precursors on silica-alumina catalyst synthesis for hydrocracking reactions
Sriatun Sriatun, Nanda A. N. Qori’ah, Ahmad Suseno, Sriyanti Sriyanti, Adi Darmawan. 12TH INTERNATIONAL SEMINAR ON NEW PARADIGM AND INNOVATION ON NATURAL SCIENCES AND ITS APPLICATIONS (12TH ISNPINSA): Contribution of Science and Technology in the Changing World, 3165 , 2024. doi: 10.1063/5.0216893
The effect of methyltriethoxysilane (MTES) concentration on hydrophobic properties of silica thin layer
Lucky Diana Mustika, Choiril Azmiyawati, Adi Darmawan. THE 14TH JOINT CONFERENCE ON CHEMISTRY 2019, 2237 , 2020. doi: 10.1063/5.0005240

Last update: 2026-09-15 13:17:06

No citation recorded.

As an article writer, the author has the right to use their article for various purposes, including use by institutions that employ the author or institutions that provide funding for the research. These author rights are granted without special permission.

Authors who publish a paper in JKSA have broad rights to use their work for teaching and scientific purposes without the need to request permission, including: (i) teaching in the author's class or institution; (ii) presenting the work at meetings or conferences and distributing copies to participants; (iii) using the work in training conducted by the author or the author's institution; (iv) distributing copies to colleagues for research purposes; (v) using the work in the compilation of subsequent works by the author; (vi) including the work in a thesis or dissertation; (vii) reusing part of the article in another work, with appropriate citation; (viii) preparing derivative works, with appropriate citation; and (ix) voluntarily posting the work on open websites operated by the author or the author's institution for scientific purposes, in accordance with the CC BY-SA License.

Authors and readers may copy and redistribute the material in any medium or format, and may remix, transform, and build upon the material for any purpose, provided that they give appropriate credit by citing the article or its content, provide a link to the license, and indicate if changes were made.

The authors submitting a manuscript do so on the understanding that, if accepted for publication, the copyright of the article shall be assigned to Jurnal Kimia Sains dan Aplikasi (JKSA). Copyright encompasses the rights to reproduce and distribute the article in all forms and media, including reprints, photographs, microfilms, and any other similar reproductions, as well as translations.

Reproducing any part of this journal, storing it in a database, or transmitting it in any form or medium is permitted without written permission from JKSA. However, the original source must be properly cited in accordance with academic conventions.

JKSA, the Chemistry Department of Diponegoro University, and the Editor make every effort to ensure that no inaccurate, false, or misleading data, opinions, or statements are published in JKSA. However, the content of each article is the sole and exclusive responsibility of its authors.

The Copyright Transfer Form can be downloaded here: [Copyright Transfer Form - Indonesian] [Copyright Transfer Form - English]. The copyright form should bear the authors' original signatures and be sent to the Editor as a printed document, a scanned document sent via email, or by fax.

Prof. Adi Darmawan, Ph.D (Editor in Chief)

Editor in chief of Jurnal Kimia Sains dan Aplikasi (JKSA)

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University

Jl. Prof. Soedarto, Kampus Undip Tembalang, Semarang, Central Java, Indonesia 50275
Email: jksa@live.undip.ac.id