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Sintesis Nanopartikel Perak (NPAg) Menggunakan Ekstrak Air Buah Andaliman (Zanthoxylum acanthopodium DC.) dan Aplikasinya pada Fotodegradasi Indigosol Blue

Synthesis of Silver Nanoparticles (NPAg) using Andaliman (Zanthoxylum acanthopodium DC.) Fruit Water Extract and Its Application in Indigosol Blue Photodegradation

1Sekolah Tinggi Farmasi Mahaganesha, Indonesia

2Chemistry Department, Udayana University, Indonesia

Received: 18 Jun 2019; Revised: 26 Jul 2019; Accepted: 12 Aug 2019; Published: 30 Sep 2019.
Open Access Copyright 2019 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract
Silver nanoparticles (NPAg) are silver metal particles that are less than 100 nm in size. NPAg has several advantages, one of which is as a catalyst in the process of photodegradation. NPAg was obtained by reducing AgNO3 using andaliman fruit water extract (Zanthoxylum acanthopodium DC.). This synthesis method is very effective because it is fast, non-toxic and environmentally friendly technology. This research aims to synthesize optimum NPAg and its application in the photodegradation process of Indigosol Blue in the form of volume, irradiation time, and optimum pH. NPAg synthesis was observed using a UV-VIS spectrophotometer while its size was observed using PSA (Particle Size Analyzer). The results showed the best NPAg synthesized using 1x10-3 M AgNO3 at 60°C with average NPAg size of 9.04 nm. NPAg which is formed is stable for ± 35 days. The optimum condition for the photodegradation process was achieved by using 2 mL NPAg 4 hour irradiation at pH 3. From the results of this study it can be concluded that NPAg can to reduce the concentration of Indigosol Blue dye by up to 94.75%.
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Keywords: Zanthoxylum acanthopodium DC; Silver Nanoparticles; Indigosol Blue; Photodegradation

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  1. Abdullah Alqudami, S. Annapoorni, Fluorescence From Metallic Silver and Iron Nanoparticles Prepared by Exploding Wire Technique, Plasmonics, 2, 1, (2007) 5-13 https://doi.org/10.1007/s11468-006-9019-2
  2. Kumari Jyoti, Mamta Baunthiyal, Ajeet Singh, Characterization of silver nanoparticles synthesized using Urtica dioica Linn. leaves and their synergistic effects with antibiotics, Journal of Radiation Research and Applied Sciences, 9, 3, (2016) 217-227 https://doi.org/10.1016/j.jrras.2015.10.002
  3. U. K. Parashar, Preeti Saxena, Anchal Srivastava, Bioinspired synthesis of silver nanoparticles, Digest Journal of Nanomaterials and Biostructures, 4, (2009) 159-166
  4. Mohd Sayeed Akhtar, Jitendra Panwar, Yeoung-Sang Yun, Biogenic Synthesis of Metallic Nanoparticles by Plant Extracts, ACS Sustainable Chemistry & Engineering, 1, 6, (2013) 591-602 https://doi.org/10.1021/sc300118u
  5. B. L. Siregar, Andaliman (Zanthoxylum Acanthapodium DC.) di Sumatera Utara; Deskripsi dan Perkecambahan, Hayati, Journal of Biosciences, (2002) 38-40
  6. A. Michalak, Phenolic Compounds and Their Antioxidant Activity in Plants Growing under Heavy Metal Stress, Polish Journal of Environmental Studies, 15, 4, (2006) 523-530
  7. V. V. Makarov, A. J. Love, O. V. Sinitsyna, S. S. Makarova, I. V. Yaminsky, M. E. Taliansky, N. O. Kalinina, "Green" nanotechnologies: synthesis of metal nanoparticles using plants, Acta Naturae, 6, 1, (2014) 35-44
  8. Mohammad Hossein Habibi, Elham Askari, Photocatalytic Degradation of an Azo Textile Dye with Manganese-Doped ZnO Nanoparticles Coated on Glass, Iranian Journal of Catalysis, 1, 1, (2011) 41-44
  9. Kumari Jyoti, Ajeet Singh, Green synthesis of nanostructured silver particles and their catalytic application in dye degradation, Journal of Genetic Engineering and Biotechnology, 14, 2, (2016) 311-317 https://doi.org/10.1016/j.jgeb.2016.09.005
  10. Andra Predescu, Avram Nicolae, Adsorption of Zn, Cu and Cd from Waste Waters by Means of Maghemite Nanoparticles, UPB Scientific Bulletin, Series B: Chemistry and Materials, 74, 1, (2012) 255-264
  11. Mojtaba Amini, Hadi Naslhajian, S. Morteza F. Farnia, V-doped titanium mixed oxides as efficient catalysts for oxidation of alcohols and olefins, New Journal of Chemistry, 38, 4, (2014) 1581-1586 https://doi.org/10.1039/C4NJ00066H
  12. Mohammad Mahdi Najafpour, Fahimeh Rahimi, Mojtaba Amini, Sara Nayeri, Mojtaba Bagherzadeh, A very simple method to synthesize nano-sized manganese oxide: an efficient catalyst for water oxidation and epoxidation of olefins, Dalton Transactions, 41, 36, (2012) 11026-11031 https://doi.org/10.1039/C2DT30553D
  13. Jae Yong Song, Hyeon-Kyeong Jang, Beom Soo Kim, Biological synthesis of gold nanoparticles using Magnolia kobus and Diopyros kaki leaf extracts, Process Biochemistry, 44, 10, (2009) 1133-1138 https://doi.org/10.1016/j.procbio.2009.06.005
  14. Anna Zielińska, Ewa Skwarek, Adriana Zaleska, Maria Gazda, Jan Hupka, Preparation of silver nanoparticles with controlled particle size, Procedia Chemistry, 1, 2, (2009) 1560-1566 https://doi.org/10.1016/j.proche.2009.11.004
  15. Dhimas Setiawan, Biosintesis Nanopartikel Perak dengan Reduktor Ekstrak Kulit Pisang Kepok (Musa paradisiaca Linn.) dan Laju Pembentukannya, Universitas Negeri Semarang, Semarang
  16. Lorraine Mulfinger, Sally D. Solomon, Mozghan Bahadory, Aravindan V. Jeyarajasingam, Susan A. Rutkowsky, Charles Boritz, Synthesis and Study of Silver Nanoparticles, Journal of Chemical Education, 84, 2, (2007) 322 https://doi.org/10.1021/ed084p322
  17. Irfa Apriliyanti Payapo, M. Zakir, Nunuk Hariani Soekamto, Sintesis Nanopartikel Perak Menggunakan Bioreduktor Ekstrak Daun Ketapang (Terminalia catappa) dan Potensinya sebagai Tabir Surya Jurusan Kimia, Universitas Hasanuddin, Makassar
  18. X. C. Jiang, W. M. Chen, C. Y. Chen, S. X. Xiong, A. B. Yu, Role of Temperature in the Growth of Silver Nanoparticles Through a Synergetic Reduction Approach, Nanoscale Res Lett, 6, 1, (2010) 32 https://doi.org/10.1007/s11671-010-9780-1
  19. Jae Yong Song, Beom Soo Kim, Rapid biological synthesis of silver nanoparticles using plant leaf extracts, Bioprocess and Biosystems Engineering, 32, 1, (2008) 79 https://doi.org/10.1007/s00449-008-0224-6
  20. Morteza Yousefzadi, Zohreh Rahimi, Vahid Ghafori, The green synthesis, characterization and antimicrobial activities of silver nanoparticles synthesized from green alga Enteromorpha flexuosa (wulfen) J. Agardh, Materials Letters, 137, (2014) 1-4 https://doi.org/10.1016/j.matlet.2014.08.110
  21. Mila Tejamaya, Synthesis, characterization, and stability test of silver nanoparticles in ecotoxicology media, University of Birmingham, Birmingham, UK
  22. Rania E. Adam, Gallia Pozina, Magnus Willander, Omer Nur, Synthesis of ZnO nanoparticles by co-precipitation method for solar driven photodegradation of Congo red dye at different pH, Photonics and Nanostructures - Fundamentals and Applications, 32, (2018) 11-18 https://doi.org/10.1016/j.photonics.2018.08.005
  23. Elias E. Elemike, Damian C. Onwudiwe, Anthony C. Ekennia, Richard C. Ehiri, Nnaemeka J. Nnaji, Phytosynthesis of silver nanoparticles using aqueous leaf extracts of Lippia citriodora: Antimicrobial, larvicidal and photocatalytic evaluations, Materials Science and Engineering: C, 75, (2017) 980-989 https://doi.org/10.1016/j.msec.2017.02.161

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