Study of Equilibrium and Kinetics of Pb(II) in Solution Using Persimmon Tannin Gel as an Adsorbent

Thamrin Azis scopus  -  Department of Chemistry, Faculty of Mathematics and Natural Sciences, Halu Oleo University, Indonesia
La Ode Ahmad orcid scopus  -  Department of Chemistry, Faculty of Mathematics and Natural Sciences, Halu Oleo University, Indonesia
Fajrin E. Rosa  -  Department of Chemistry, Faculty of Mathematics and Natural Sciences, Halu Oleo University, Indonesia
*Laode Abdul Kadir scopus  -  Department of Chemistry, Faculty of Mathematics and Natural Sciences, Halu Oleo University, Indonesia
Received: 20 Aug 2019; Revised: 11 Nov 2019; Accepted: 13 Nov 2019; Published: 30 Nov 2019; Available online: 30 Nov 2019.
Open Access Copyright 2019 Jurnal Kimia Sains dan Aplikasi
License URL: http://creativecommons.org/licenses/by-sa/4.0

Citation Format:
Cover Image
Abstract
Heavy metals concentrations exceeding the recommended threshold are hazardous for the environment, so there is a need for handling it safely. The purpose of this research was to determine the adsorption capacity and kinetics of adsorption. This research uses an adsorption method in the process of removing Pb(II) heavy metal ions using persimmon tannin gel. Besides the influence of contact time, pH, and the concentration of Pb(II) metal ions on adsorption, a kinetics study was also carried out. The adsorption rate is obtained through the adsorption rate constant (K) and the reaction order generated from the kinetics model. Based on the results of the research, showed the optimum adsorption process, which is 20 minutes and at a pH of 5. The maximum adsorption capacity of 17.62 mg/g with the value of the standard energy changes of Gibbs adsorption (-ΔG° = -14.274 kJ/moll) indicates that the adsorption takes place through physical interaction. The kinetic adsorption gives the adsorption rates a constant of, k = 0.008231 g/mg.min.
Keywords: Heavy metal; Persimmon tannin; adsorption
Funding: the Chemistry Laboratory of the Faculty of Mathematics and Natural Sciences, the Halu Oleo University

Article Metrics:

  1. Westriani Prambaningrum, Khabibi Khabibi and Muhammad Cholid Djunaidi, Adsorpsi Ion Besi(III) dan Kadmium(II) Menggunakan Gel Kitosan, Jurnal Kimia Sains dan Aplikasi, 12, 2, (2009) 47-51 https://doi.org/10.14710/jksa.12.2.47-51
  2. Puji Rahayu and Khabibi Khabibi, Adsorpsi Ion Logam Nikel(II) oleh Kitosan Termodifikasi Tripolifosfat, Jurnal Kimia Sains dan Aplikasi, 19, 1, (2016) 21-26 https://doi.org/10.14710/jksa.19.1.21-26
  3. Munther Issa Kandah, Zinc and cadmium adsorption on low-grade phosphate, Separation and Purification Technology, 35, 1, (2004) 61-70 https://doi.org/10.1016/S1383-5866(03)00131-X
  4. L. L. Tavlarides, J. H. Bae and C. K. Lee, Solvent Extraction, Membranes, and Ion Exchange in Hydrometallurgical Dilute Metals Separation, Separation Science and Technology, 22, 2-3, (1987) 581-617 https://doi.org/10.1080/01496398708068970
  5. L.O Ahmad, D. A. Murguia Flores, H. Okumura, Y. Kaneki, M. Honda, M. Suda and K. K. Kunimoto, Application of Modified Persimmon Tannin Gels in the Removal of Dyes from Aqueous Solution, in: A. Bulucea (Ed.) Recent Advances on Environmental and Life Science, 2015
  6. Susmita Sen Gupta and Krishna G. Bhattacharyya, Adsorption of Ni(II) on clays, Journal of Colloid and Interface Science, 295, 1, (2006) 21-32 https://doi.org/10.1016/j.jcis.2005.07.073
  7. Fahmiati Fahmiati, Nuryono Nuryono and Narsito Narsito, Adsorption Thermodynamics of Cd(II), Ni(II), and Mg(II) on 3-Mercapto-1, 2, 4-Triazole Immobilized Silica Gel, Indonesian Journal of Chemistry, 6, 1, (2010) 52-55 https://doi.org/10.22146/ijc.21773
  8. Z. George Kyzas and Margaritis Kostoglou, Green Adsorbents for Wastewaters: A Critical Review, Materials, 7, 1, (2014) https://doi.org/10.3390/ma7010333
  9. Florent Carn, Sylvain Guyot, Alain Baron, Javier Pérez, Eric Buhler and Dražen Zanchi, Structural Properties of Colloidal Complexes between Condensed Tannins and Polysaccharide Hyaluronan, Biomacromolecules, 13, 3, (2012) 751-759 https://doi.org/10.1021/bm201674n
  10. Aurélien L. Furlan, Aurore Castets, Frédéric Nallet, Isabelle Pianet, Axelle Grélard, Erick J. Dufourc and Julie Géan, Red Wine Tannins Fluidify and Precipitate Lipid Liposomes and Bicelles. A Role for Lipids in Wine Tasting?, Langmuir, 30, 19, (2014) 5518-5526 https://doi.org/10.1021/la5005006
  11. Shu-fen Xu, Bo Zou, Jie Yang, Ping Yao and Chun-mei Li, Characterization of a highly polymeric proanthocyanidin fraction from persimmon pulp with strong Chinese cobra PLA2 inhibition effects, Fitoterapia, 83, 1, (2012) 153-160 https://doi.org/10.1016/j.fitote.2011.10.005
  12. La Ode Ahmad, Le Hoang My Linh, Mio Akimoto, Yusuke Kaneki, Mitsunori Honda, Mitsuhiro Suda and Ko-Ki Kunimoto, Persimmon Tannin Gel: Formation by Autoxidation and Caffeine Adsorption Properties, Food Science and Technology Research, 19, 4, (2013) 697-703 https://doi.org/10.3136/fstr.19.697
  13. Tushar Kanti Sen and Chi Khoo, Adsorption characteristics of zinc (Zn2+) from aqueous solution by natural bentonite and kaolin clay minerals: a comparative study, Computational Water, Energy, and Environmental Engineering, 2, (2013) 1-6 http://dx.doi.org/10.4236/cweee.2013.23B001
  14. Mega Dona Indriana, Danar Purwonugroho and Darjito Darjito, Adsorpsi Seng (II) Menggunakan Biomassa Azolla microphylla Diesterifikasi dengan Asam Sitrat, Jurnal Ilmu Kimia Universitas Brawijaya, 2, 2, (2014) 534-540
  15. Muhammad Raziq Rahimi Kooh, Muhammad Khairud Dahri and Linda B. L. Lim, The removal of rhodamine B dye from aqueous solution using Casuarina equisetifolia needles as adsorbent, Cogent Environmental Science, 2, 1, (2016) 1-14 https://doi.org/10.1080/23311843.2016.1140553
  16. Jesús Beltrán-Heredia, Patricia Palo, Jesús Sánchez-Martín, Joaquín R. Domínguez and Teresa González, Natural Adsorbents Derived from Tannin Extracts for Pharmaceutical Removal in Water, Industrial & Engineering Chemistry Research, 51, 1, (2012) 50-57 https://doi.org/10.1021/ie201017t
  17. Nour-Eddine Es-Safi, Véronique Cheynier and Michel Moutounet, Role of Aldehydic Derivatives in the Condensation of Phenolic Compounds with Emphasis on the Sensorial Properties of Fruit-Derived Foods, Journal of Agricultural and Food Chemistry, 50, 20, (2002) 5571-5585 https://doi.org/10.1021/jf025503y
  18. S. Martinez, Inhibitory mechanism of mimosa tannin using molecular modeling and substitutional adsorption isotherms, Materials Chemistry and Physics, 77, 1, (2003) 97-102 https://doi.org/10.1016/S0254-0584(01)00569-7
  19. P. Senthil Kumar, R. V. Abhinaya, K. Gayathri Lashmi, V. Arthi, R. Pavithra, V. Sathyaselvabala, S. Dinesh Kirupha and S. Sivanesan, Adsorption of methylene blue dye from aqueous solution by agricultural waste: Equilibrium, thermodynamics, kinetics, mechanism and process design, Colloid Journal, 73, 5, (2011) 651 https://doi.org/10.1134/S1061933X11050061
  20. Adhitiyawarman Anita Imawati, Kapasitas adsorpsi maksimum ion Pb (II) oleh arang aktif ampas kopi teraktivasi HCl dan H3PO4, Jurnal Kimia Khatulistiwa, 4, 2, (2015) 50-61
  21. I. A. Gede Widihati, Adsorpsi Ion Pb2+ oleh Lempung Terinterkalasi Surfaktan, Jurnal Kimia, 3, 1, (2009) 27-32
  22. Zurida Agustiningtyas, Optimisasi Adsorpsi Ion Pb (II) Menggunakan Zeolit Alam Termodifikasi Ditizon, Departemen Kimia, Institut Pertanian Bogor, Bogor
  23. Jian-Hui Ye, Liu-Xiang Wang, Hao Chen, Jun-Jie Dong, Jian-Liang Lu, Xin-Qiang Zheng, Ming-Yan Wu and Yue-Rong Liang, Preparation of tea catechins using polyamide, Journal of Bioscience and Bioengineering, 111, 2, (2011) 232-236 https://doi.org/10.1016/j.jbiosc.2010.09.019

Last update: 2021-05-15 14:33:36

  1. Study of Kinetics and Adsorption Isotherm of Methylene Blue Dye using Tannin Gel from Ceriops tagal

    Thamrin Azis, La Ode Ahmad, Keke Awaliyah, Laode Abdul Kadir. Jurnal Kimia Sains dan Aplikasi, 23 (10), 2020. doi: 10.14710/jksa.23.10.370-376

Last update: 2021-05-15 14:33:36

No citation recorded.