DOI: https://doi.org/10.14710/jksa.24.2.51-57

Adsorption of Methylene Blue Dye using Fe3O4 Magnetized Natural Zeolite Adsorbent

Agrotechnology Study Program, Faculty of Agriculture, University of Flores, Indonesia

Received: 8 Jan 2021; Revised: 6 Feb 2021; Accepted: 24 Feb 2021; Published: 15 Mar 2021.
Open Access Copyright 2021 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract

Preparation and characterization of Fe3O4 magnetized natural zeolite adsorbent for adsorption of methylene blue dye have been carried out. Natural zeolite/Fe3O4 adsorbent preparation was carried out using coprecipitation of Fe2+ and Fe3+ ions (1: 2 mol ratio) on the natural zeolite surface. Characterization was carried out using X-Ray Diffraction (XRD), Fourier Transform Infra-Red (FTIR), and Scanning Electron Microscopy (SEM) to determine the effect of Fe3O4 on the natural zeolite surface. UV-Vis spectroscopy was used to determine the concentration of methylene blue after the adsorption process. The characterization results showed that Fe3O4 was successfully embedded in the natural zeolite without damaging the natural zeolite's crystallinity. Natural zeolite/Fe3O4 adsorbent showed easy separation from water medium after the adsorption process. The optimum conditions for adsorption were achieved at the contact time of 60 minutes, and the initial concentration of methylene blue was 30 ppm with an adsorbent mass of 25 mg. Adsorption kinetics followed pseudo-second-order reaction kinetics, and adsorption isotherm followed Langmuir isotherm with an adsorption capacity of 32.258 mg/g.

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Keywords: adsorption; methylene blue; magnetite; natural zeolite

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Section: Research Articles
Language : EN
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  1. D. Çaparkaya, L. Cavas, Biosorption of Methylene Blue by a Brown Alga Cystoseira barbatula Kiitzing, Acta Chimica Slovenica, 55, 3, (2008), 547-553
  2. V. Vadivelan, K. Vasanth Kumar, Equilibrium, kinetics, mechanism, and process design for the sorption of methylene blue onto rice husk, Journal of Colloid and Interface Science, 286, 1, (2005), 90-100 https://doi.org/10.1016/j.jcis.2005.01.007
  3. Shaobin Wang, Yuelian Peng, Natural zeolites as effective adsorbents in water and wastewater treatment, Chemical Engineering Journal, 156, 1, (2010), 11-24 https://doi.org/10.1016/j.cej.2009.10.029
  4. Sibel Kılınç Alpat, Özge Özbayrak, Şenol Alpat, Hüsamettin Akçay, The adsorption kinetics and removal of cationic dye, Toluidine Blue O, from aqueous solution with Turkish zeolite, Journal of Hazardous Materials, 151, 1, (2008), 213-220 https://doi.org/10.1016/j.jhazmat.2007.05.071
  5. Annamária Mockovčiaková, Marek Matik, Zuzana Orolínová, Pavol Hudec, Erika Kmecová, Structural characteristics of modified natural zeolite, Journal of Porous Materials, 15, 5, (2008), 559-564 https://doi.org/10.1007/s10934-007-9133-3
  6. Ming Liang Yuan, Liang Yu, Jia Hua Tao, Cong Song, Preparation of Magnetically Modified Zeolites and the Application of Metal Ions Adsorption, Advanced Materials Research, 299-300, (2011), 764-769 https://doi.org/10.4028/www.scientific.net/AMR.299-300.764
  7. Anoushiravan Mohseni-Bandpi, Tariq J. Al-Musawi, Esmail Ghahramani, Mansur Zarrabi, Samira Mohebi, Shiva Abdollahi Vahed, Improvement of zeolite adsorption capacity for cephalexin by coating with magnetic Fe3O4 nanoparticles, Journal of Molecular Liquids, 218, (2016), 615-624 https://doi.org/10.1016/j.molliq.2016.02.092
  8. Endang Tri Wahyuni, Mudasir, Improvement of Ion-Exchange Capacity of Indonesian Natural Zeolite by Sequential Washing Using Hydrofluoric Acid and EDTA Solutions, Journal of Ion Exchange, 18, 4, (2007), 340-345 https://doi.org/10.5182/jaie.18.340
  9. Abdelmajid Lassoued, Mohamed Saber Lassoued, Brahim Dkhil, Abdellatif Gadri, Salah Ammar, Synthesis, structural, optical and morphological characterization of hematite through the precipitation method: Effect of varying the nature of the base, Journal of Molecular Structure, 1141, (2017), 99-106 https://doi.org/10.1016/j.molstruc.2017.03.077
  10. Ilona S. Smolkova, Natalia E. Kazantseva, Harshida Parmar, Vladimir Babayan, Petr Smolka, Petr Saha, Correlation between coprecipitation reaction course and magneto-structural properties of iron oxide nanoparticles, Materials Chemistry and Physics, 155, (2015), 178-190 https://doi.org/10.1016/j.matchemphys.2015.02.022
  11. Xinyu Hu, Yongmei Wang, Liangliang Zhang, Man Xu, Jianfa Zhang, Wei Dong, Design of a pH-sensitive magnetic composite hydrogel based on salecan graft copolymer and Fe3O4@SiO2 nanoparticles as drug carrier, International Journal of Biological Macromolecules, 107, (2018), 1811-1820 https://doi.org/10.1016/j.ijbiomac.2017.10.043
  12. M. M. Rashad, H. M. El-Sayed, M. Rasly, M. I. Nasr, Induction heating studies of magnetite nanospheres synthesized at room temperature for magnetic hyperthermia, Journal of Magnetism and Magnetic Materials, 324, 23, (2012), 4019-4023 https://doi.org/10.1016/j.jmmm.2012.07.010
  13. Adrian Radoń, Aleksandra Drygała, Łukasz Hawełek, Dariusz Łukowiec, Structure and optical properties of Fe3O4 nanoparticles synthesized by co-precipitation method with different organic modifiers, Materials Characterization, 131, (2017), 148-156 https://doi.org/10.1016/j.matchar.2017.06.034
  14. Ayten Ates, Christopher Hardacre, The effect of various treatment conditions on natural zeolites: Ion exchange, acidic, thermal and steam treatments, Journal of Colloid and Interface Science, 372, 1, (2012), 130-140 https://doi.org/10.1016/j.jcis.2012.01.017
  15. Mitiko Yamaura, Denise Alves Fungaro, Synthesis and characterization of magnetic adsorbent prepared by magnetite nanoparticles and zeolite from coal fly ash, Journal of Materials Science, 48, 14, (2013), 5093-5101 https://doi.org/10.1007/s10853-013-7297-6
  16. Mohammad Khodadadi, Akbar Malekpour, Masoomeh Ansaritabar, Removal of Pb (II) and Cu (II) from aqueous solutions by NaA zeolite coated magnetic nanoparticles and optimization of method using experimental design, Microporous and Mesoporous Materials, 248, (2017), 256-265 https://doi.org/10.1016/j.micromeso.2017.04.032
  17. Jacob J. Salazar-Rabago, Roberto Leyva-Ramos, Jose Rivera-Utrilla, Raul Ocampo-Perez, Felipe J. Cerino-Cordova, Biosorption mechanism of Methylene Blue from aqueous solution onto White Pine (Pinus durangensis) sawdust: Effect of operating conditions, Sustainable Environment Research, 27, 1, (2017), 32-40 https://doi.org/10.1016/j.serj.2016.11.009
  18. Vipasiri Vimonses, Shaomin Lei, Bo Jin, Chris W. K. Chow, Chris Saint, Adsorption of congo red by three Australian kaolins, Applied Clay Science, 43, 3, (2009), 465-472 https://doi.org/10.1016/j.clay.2008.11.008
  19. Kar Yan Hor, Jasmine Mun Cheng Chee, Meng Nan Chong, Bo Jin, Christopher Saint, Phaik Eong Poh, Rupak Aryal, Evaluation of physicochemical methods in enhancing the adsorption performance of natural zeolite as low-cost adsorbent of methylene blue dye from wastewater, Journal of Cleaner Production, 118, (2016), 197-209 https://doi.org/10.1016/j.jclepro.2016.01.056
  20. Lunhong Ai, You Zhou, J. Jiang, Removal of methylene blue from aqueous solution by montmorillonite/CoFe2O4 composite with magnetic separation performance, Desalination, 266, 1, (2011), 72-77 https://doi.org/10.1016/j.desal.2010.08.004

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