DOI: https://doi.org/10.14710/jksa.25.9.338-345

Synthesis of Magnetic Chitosan Composite Beads as an Adsorbent for Removal of Organic Matter from Peat Water

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Tanjungpura University, Pontianak 78124, Indonesia

Received: 4 Sep 2022; Revised: 8 Dec 2022; Accepted: 9 Dec 2022; Published: 23 Dec 2022.
Open Access Copyright 2022 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract
Groundwater in peatlands has the potential to be utilized as a water source, but its high organic matter content presents challenges. This study aimed to improve the quality of peat water through the adsorption of organic matter using chitosan magnetic beads composite adsorbent. Magnetic chitosan beads (KMB) composite was synthesized by mixing chitosan, acetic acid, and a mixture of Fe2+/Fe3+ solution with a mole ratio of 1:2. This mixture was then dropped into a sodium hydroxide solution. In addition to KMB, magnetic composite beads containing glutaraldehyde crosslinking agent (KMBG) were also synthesized. The results of composites analysis using a Fourier transform infrared (FTIR) spectrophotometer showed typical Fe-O absorption bands at 582 cm-1 and 578 cm-1 for KMB and KMBG. The typical C=N absorption band for glutaraldehyde in KMBG appeared at 1631 cm-1. X-ray diffraction (XRD) analysis revealed the characteristic peaks of Fe3O4 for KMB and KMBG at 2θ = 30.2°, 35.5°, 43.2°, 57.0°, and 62.8° with an amorphous structure. The adsorption of organic matter was performed by varying the pH (2, 3, 4, and 5) of peat water and the mass of the adsorbent (50, 70, 100, 200, and 300 mg). The optimum adsorption occurred at pH 2 with an absorbent mass of 0.1 g KMB and 0.07 g KMBG. Applying KMB on peat water reduces turbidity, color, and absorbance at a wavelength of 254 nm (Aλ=254), which is better than using KMBG. These three parameters’ efficiency percentages were 44%, 78%, and 74% for KMB and 17%, 30%, and 59% for KMBG.
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Keywords: adsorption; peat; chitosan; magnetic beads

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Section: Research Articles
Language : EN
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  2. Muthia Elma, Amalia Enggar Pratiwi, Aulia Rahma, Erdina Lulu Atika Rampun, Mahmud Mahmud, Chairul Abdi, Raissa Rosadi, Dede Heri Yuli Yanto, Muhammad Roil Bilad, Combination of coagulation, adsorption, and ultrafiltration processes for organic matter removal from peat water, Sustainability, 14, 1, (2021), 370 https://doi.org/10.3390/su14010370
  3. Chasri Nurhayati, Tri Susanto, Pemanfaatan Fly Ash Batubara Sebagai Bahan Membran Keramik Pada Unit Pengolah Air Gambut, Jurnal Dinamika Penelitian Industri, 26, 2, (2015), 95-105
  4. Endaruji Sedyadi, Khaerul Huda, Kajian Adsorpsi remazol yellow FG oleh montmorillonit-kitosan, Integrated Lab Journal, 4, 2, (2016), 139-152
  5. Ning Wang, Zhenghe Xu, Weiying Xu, Jing Xu, Yingying Chen, Min Zhang, Comparison of coagulation and magnetic chitosan nanoparticle adsorption on the removals of organic compound and coexisting humic acid: A case study with salicylic acid, Chemical Engineering Journal, 347, (2018), 514-524 https://doi.org/10.1016/j.cej.2018.04.131
  6. Feng-Chin Wu, Ru-Ling Tseng, Ruey-Shin Juang, Comparative adsorption of metal and dye on flake-and bead-types of chitosans prepared from fishery wastes, Journal of Hazardous Materials, 73, 1, (2000), 63-75 https://doi.org/10.1016/S0304-3894(99)00168-5
  7. Arh-Hwang Chen, Shin-Ming Chen, Biosorption of azo dyes from aqueous solution by glutaraldehyde-crosslinked chitosans, Journal of Hazardous Materials, 172, 2-3, (2009), 1111-1121 https://doi.org/10.1016/j.jhazmat.2009.07.104
  8. Changlong Dong, Wei Chen, Cheng Liu, Preparation of novel magnetic chitosan nanoparticle and its application for removal of humic acid from aqueous solution, Applied Surface Science, 292, (2014), 1067-1076 https://doi.org/10.1016/j.apsusc.2013.12.125
  9. Rahmi, Ishmaturrahmi, Irfan Mustafa, Methylene blue removal from water using H2SO4 crosslinked magnetic chitosan nanocomposite beads, Microchemical Journal, 144, (2019), 397-402 https://doi.org/10.1016/j.microc.2018.09.032
  10. Shengyan Pu, Hui Ma, Anatoly Zinchenko, Wei Chu, Novel highly porous magnetic hydrogel beads composed of chitosan and sodium citrate: an effective adsorbent for the removal of heavy metals from aqueous solutions, Environmental Science and Pollution Research, 24, 19, (2017), 16520-16530 https://doi.org/10.1007/s11356-017-9213-0
  11. Sirlei Rosa, Mauro C. M. Laranjeira, Humberto G. Riela, Valfredo T. Fávere, Crosslinked quaternary chitosan as an adsorbent for the removal of the reactive dye from aqueous solutions, Journal of Hazardous Materials, 155, 1-2, (2008), 253-260 https://doi.org/10.1016/j.jhazmat.2007.11.059
  12. Rahmi, Fathurrahmi, Lelifajri, Fitri PurnamaWati, Preparation of magnetic chitosan using local iron sand for mercury removal, Heliyon, 5, 5, (2019), 1-8 https://doi.org/10.1016/j.heliyon.2019.e01731
  13. Priti Rani, Rajni Johar, P. S. Jassal, Adsorption of nickel (II) ions from wastewater using glutaraldehyde crosslinked magnetic chitosan beads: isotherm, kinetics and thermodynamics, Water Science and Technology, 82, 10, (2020), 2193-2202 https://doi.org/10.2166/wst.2020.459
  14. Hans Kristianto, Edwin Reynaldi, Susiana Prasetyo, Asaf K. Sugih, Adsorbed leucaena protein on citrate modified Fe3O4 nanoparticles: synthesis, characterization, and its application as magnetic coagulant, Sustainable Environment Research, 30, 32, (2020), 1-11 https://doi.org/10.1186/s42834-020-00074-4
  15. Alfian Nuris Shafar, Pengaruh pH dan Lama Kontak terhadap Adsorpsi Ion Cd2+ Menggunakan Kitosan-Magnetik Nanopartikel, Chemistry Department, Universitas Brawijaya, Malang, 2019
  16. T. J. Sudhavani, N. Sivagangi Reddy, K. Madhusudana Rao, K. S. V. Rao, Jayshree Ramkumar, A. V. R. Reddy, Development of thiourea-formaldehyde crosslinked chitosan membrane networks for separation of Cu (II) and Ni (II) ions, Bulletin of the Korean Chemical Society, 34, 5, (2013), 1513-1520 https://doi.org/10.5012/bkcs.2013.34.5.1513
  17. Johanna Galan, Jorge Trilleras, Paula A. Zapata, Victoria A. Arana, Carlos David Grande-Tovar, Optimization of chitosan glutaraldehyde-crosslinked beads for reactive blue 4 anionic dye removal using a surface response methodology, Life, 11, 2, (2021), 85 https://doi.org/10.3390/life11020085
  18. Bin Li, Chang-Lin Shan, Qing Zhou, Yuan Fang, Yang-Li Wang, Fei Xu, Li-Rong Han, Muhammad Ibrahim, Long-Biao Guo, Guan-Lin Xie, Synthesis, characterization, and antibacterial activity of crosslinked chitosan-glutaraldehyde, Marine drugs, 11, 5, (2013), 1534-1552 https://doi.org/10.3390/md11051534
  19. Xue-Fei Sun, Shu-Guang Wang, Xian-Wei Liu, Wen-Xin Gong, Nan Bao, Yue Ma, The effects of pH and ionic strength on fulvic acid uptake by chitosan hydrogel beads, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 324, 1-3, (2008), 28-34 https://doi.org/10.1016/j.colsurfa.2008.03.023
  20. Chen Yuwei, Wang Jianlong, Preparation and characterization of magnetic chitosan nanoparticles and its application for Cu (II) removal, Chemical Engineering Journal, 168, 1, (2011), 286-292 https://doi.org/10.1016/j.cej.2011.01.006
  21. D. Harikishore Kumar Reddy, Seung-Mok Lee, Application of magnetic chitosan composites for the removal of toxic metal and dyes from aqueous solutions, Advances in Colloid and Interface Science, 201-202, (2013), 68-93 https://doi.org/10.1016/j.cis.2013.10.002
  22. Shu-Guang Wang, Xue-Fei Sun, Xian-Wei Liu, Wen-Xin Gong, Bao-Yu Gao, Nan Bao, Chitosan hydrogel beads for fulvic acid adsorption: Behaviors and mechanisms, Chemical Engineering Journal, 142, 3, (2008), 239-247 https://doi.org/10.1016/j.cej.2007.11.025
  23. X. R. B. J Zhang, Renbi Bai, Mechanisms and kinetics of humic acid adsorption onto chitosan-coated granules, Journal of Colloid and Interface Science, 264, 1, (2003), 30-38 https://doi.org/10.1016/S0021-9797(03)00393-X
  24. Mashuni Mashuni, Halimahtussaddiyah Ritonga, Muhammad Jahiding, Fitri Handayani Hamid, Sintesis Kitosan dari Kulit Udang sebagai Bahan Membran Elektrode Au/Kitosan/GTA/AChE untuk Deteksi Pestisida, ALCHEMY Jurnal Penelitian Kimia, 18, 1, 112-121 https://doi.org/10.20961/alchemy.18.1.56551.112-121
  25. Fatemeh Hosseini, Somayeh Sadighian, Hassan Hosseini-Monfared, Niyaz Mohammad Mahmoodi, Dye removal and kinetics of adsorption by magnetic chitosan nanoparticles, Desalination and Water Treatment, 57, 51, (2016), 24378-24386 https://doi.org/10.1080/19443994.2016.1143879
  26. Risa Arisna, Titin Anita Zaharah, Rudiyansyah, Adsorpsi Besi dan Bahan Organik pada Air Gambut oleh Karbon Aktif Kulit Durian, Jurnal Kimia Khatulistiwa, 5, 3, (2016), 31-39
  27. Chivon Lerebulan, Fety Fatimah, Julius Pontoh, Rendemen dan Total Fenolik Santan Kelapa dalam pada Berbagai Tingkat Kematangan, Jurnal MIPA, 7, 1, (2018), 44-46 https://doi.org/10.35799/jm.7.1.2018.19283
  28. M. A. Zulfikar, F. I. Suri, Rusnadi, H. Setiyanto, N. Mufti, M. Ledyastuti, D. Wahyuningrum, Fe3O4 nano-particles prepared by co-precipitation method using local sands as a raw material and their application for humic acid removal, International Journal of Environmental Studies, 73, 1, (2016), 79-94 https://doi.org/10.1080/00207233.2015.1108600

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