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Synthesis of White Mineral Trioxide Aggregate (WMTA) Using Silica from Rice Husk and Calcium Carbonate from Limestone

1Department of Pharmacy (Diploma), Mitra Karya Mandiri Polytechnic, Brebes, Indonesia

2Department of Electromedical Engineering, Bina Trada Polytechnic, Semarang, Indonesia

3Department of Medical Laboratory Technology, Yakpermas Polytechnic, Banyumas, Indonesia

Received: 18 Nov 2022; Revised: 15 Feb 2023; Accepted: 20 Feb 2023; Published: 28 Feb 2023.
Open Access Copyright 2023 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract

White Mineral Trioxide Aggregate (WMTA) was produced using silica as the initial material extracted from rice husk ash and calcium carbonate limestone. This research was initiated by calcinating rice husk ash at 700°C for 3 hours. Silica extraction was performed using 2 M NaOH and added HCl. The extract precipitate was washed using deionized water. Calcium carbonate was made from limestone using 1 M HNO3 and NH3 and continued with carbonation. WMTA was produced by mixing SiO2, CaCO3, and Al2O3. The mixture was homogenized with deionized water and heated, then pellets calcined made at a temperature of 1000°C, and calcination products were added Bi2O3. Synthesized WMTA characterized using TGA/DSC, FTIR, and XRD showed the presence of Ca3SiO5, Ca2SiO4, and Ca3Al2O6 phases, which were like ProRoot’s WMTA.

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Keywords: SiO2; CaCO3; White Mineral Trioxide Aggregate (WMTA); Ca3SiO5; Ca2SiO4; Ca3Al2O6

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  1. G. Voicu, A. I. Bădănoiu, C. D. Ghiţulică, E. Andronescu, Sol-gel synthesis of white mineral trioxide aggregate with potential use as biocement, Digest Journal of Nanomaterials and Biostructures, 7, 4, (2012), 1639-1646
  2. Gul Celik Unal, Murat Maden, Tugba Isidan, Repair of furcal iatrogenic perforation with mineral trioxide aggregate: two years follow-up of two cases, European Journal of Dentistry, 4, 4, (2010), 475-481
  3. Camila Corral-Núñez, Eduardo Fernández-Godoy, Javier Martín Casielles, Juan Estay, Cristian Bersezio-Miranda, Patricia Cisternas-Pinto, Osmir Batista Batista-de Oliveira, Current state of calcium silicate cements in restorative dentistry: a review, Revista Facultad de Odontología Universidad de Antioquia, 27, 2, (2016), 425-441 https://doi.org/10.17533/udea.rfo.v27n2a10
  4. R. Steffen, H. van Waes, Understanding mineral trioxide aggregate/Portlandcement: a review of literature and background factors, European Archives of Paediatric Dentistry, 10, (2009), 93-97 https://doi.org/10.1007/BF03321608
  5. Robert K. Murray, Biokimia Harper, 25 ed., EGC, Jakarta, 2001
  6. Mahmoud Torabinejad, Chan-Ui Hong, Seung-Jong Lee, Mehdi Monsef, Thomas R. Pitt Ford, Investigation of mineral trioxide aggregate for root-end filling in dogs, Journal of Endodontics, 21, 12, (1995), 603-608 https://doi.org/10.1016/S0099-2399(06)81112-X
  7. Muchtar Aziz, Batu kapur dan peningkatan nilai tambah serta spesifikasi untuk industri, Jurnal Teknologi Mineral dan Batubara, 6, 3, (2010), 116-131
  8. Mita Wulandari Lukman, Sintesis Biomaterial Komposit CaO-SiO2 Berbasis Material Alam (Batuan Kapur dan Pasir Kuarsa) dengan Variasi Suhu Pemanasan dan Pengaruhnya Terhadap Porositas, Kekerasan dan Mikrostruktur, Journal Sains, Univesitas Negeri Malang, Malang, 2012
  9. Abhisk Mehta, R. P. Ugwekar, Extraction of silica and other related products from rice husk, International Journal of Engineering Research and Applications, 5, 8, (2015), 43-48
  10. Suyanta Suyanta, Agus Kuncaka, Utilization of rice husk as raw material in synthesis of mesoporous silicates MCM-41, Indonesian Journal of Chemistry, 11, 3, (2011), 279-284 https://doi.org/10.22146/ijc.21393
  11. Maurice Abou Abou Rida, Faouzi Harb, Synthesis and characterization of amorphous silica nanoparitcles from aqueous silicates uisng cationic surfactants, Journal of Metals, Materials and Minerals, 24, 1, (2014), 37-42
  12. Dwi Rasy Mujiyanti, Nuryono Nuryono, Eko Sri Kunarti, Sintesis dan karakterisasi silika gel dari abu sekam padi yang diimobilisasi dengan 3-(trimetoksisilil)-1-propantiol, Jurnal Berkala Ilmiah Sains dan Terapan Kimia, 4, 2, (2010), 150-167
  13. S. Azat, A. V. Korobeinyk, K. Moustakas, V. J. Inglezakis, Sustainable production of pure silica from rice husk waste in Kazakhstan, Journal of Cleaner Production, 217, (2019), 352-359 https://doi.org/10.1016/j.jclepro.2019.01.142
  14. Hervé Kouamo Tchakouté, Claus Henning Rüscher, Sakeo Kong, Navid Ranjbar, Synthesis of sodium waterglass from white rice husk ash as an activator to produce metakaolin-based geopolymer cements, Journal of Building Engineering, 6, (2016), 252-261 https://doi.org/10.1016/j.jobe.2016.04.007
  15. José Arnaldo Santana Costa, Caio Marcio Paranhos, Systematic evaluation of amorphous silica production from rice husk ashes, Journal of Cleaner Production, 192, (2018), 688-697 https://doi.org/10.1016/j.jclepro.2018.05.028
  16. Rohani Abu Bakar, Rosiyah Yahya, Seng Neon Gan, Production of high purity amorphous silica from rice husk, Procedia Chemistry, 19, (2016), 189-195 https://doi.org/10.1016/j.proche.2016.03.092
  17. Noviyanti Noviyanti, Jasruddin Jasruddin, Eko Hadi Sujiono, Karakterisasi kalsium karbonat (Ca(CO3)) dari batu kapur kelurahan Tellu Limpoe kecamatan Suppa, Jurnal Sains dan Pendidikan Fisika, 11, 2, (2015), 169-172
  18. Trevor L. Hughes, Claire M. Methven, Timothy G. J. Jones, Sarah E. Pelham, Philip Fletcher, Christopher Hall, Determining cement composition by Fourier transform infrared spectroscopy, Advanced Cement Based Materials, 2, 3, (1995), 91-104 https://doi.org/10.1016/1065-7355(94)00031-X
  19. Md Shahinoor Alam, Mohammad Asaduzzaman Chowdhury, Characterization of epoxy composites reinforced with CaCO3-Al2O3-MgO-TiO2/CuO filler materials, Alexandria Engineering Journal, 59, 6, (2020), 4121-4137 https://doi.org/10.1016/j.aej.2020.07.017
  20. Georgeta Voicu, Alina Bădănoiu, Ecaterina Andronescu, Carmen Chifiruc, Synthesis, characterization and bioevaluation of partially stabilized cements for medical applications, Central European Journal of Chemistry, 11, (2013), 1657-1667 https://doi.org/10.2478/s11532-013-0297-1
  21. Warda Ashraf, Jan Olek, Vahit Atakan, A comparative study of the reactivity of calcium silicates during hydration and carbonation reactions, 14th International Congress on the Chemistry of Cement (ICCC 2015), Beijing, China, 2015
  22. Anikó Meiszterics, László Rosta, Herwig Peterlik, János Rohonczy, Shiro Kubuki, Péter Henits, Katalin Sinkó, Structural characterization of gel-derived calcium silicate systems, The Journal of Physical Chemistry A, 114, 38, (2010), 10403-10411 https://doi.org/10.1021/jp1053502
  23. Wen-Hsi Wang, Chen-Ying Wang, Yow-Chyun Shyu, Cheing-Meei Liu, Feng-Huei Lin, Chun-Pin Lin, Compositional characteristics and hydration behavior of mineral trioxide aggregates, Journal of Dental Sciences, 5, 2, (2010), 53-59 https://doi.org/10.1016/S1991-7902(10)60009-8
  24. Abhishek R. Indurkar, Viraj D. Sangoi, Prashant B. Patil, Mansingraj S. Nimbalkar, Rapid synthesis of Bi2O3 nano-needles via 'green route' and evaluation of its anti-fungal activity, IET Nanobiotechnology, 12, 4, (2018), 496-499 https://doi.org/10.1049/iet-nbt.2017.0070
  25. Saeed Asgary, Mohammad Jafar Eghbal, Masoud Parirokh, Jamileh Ghoddusi, Sanam Kheirieh, Frank Brink, Comparison of mineral trioxide aggregate's composition with Portland cements and a new endodontic cement, Journal of Endodontics, 35, 2, (2009), 243-250 https://doi.org/10.1016/j.joen.2008.10.026
  26. Steven Gu, Brian J. Rasimick, Allan S. Deutsch, Barry Lee Musikant, Radiopacity of dental materials using a digital X-ray system, Dental Materials, 22, 8, (2006), 765-770 https://doi.org/10.1016/j.dental.2005.11.004
  27. Irma Araceli Belío-Reyes, Lauro Bucio, Esther Cruz-Chavez, Phase composition of ProRoot mineral trioxide aggregate by X-ray powder diffraction, Journal of Endodontics, 35, 6, (2009), 875-878 https://doi.org/10.1016/j.joen.2009.03.004

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