DOI: https://doi.org/10.14710/jksa.25.12.436-441

Synthesis of Lead Oxide Using the Oxidizing Agent (NH4)2S2O8 with Variaous Amounts of NaOH for Decolorization of Remazol Black B Solution

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Jl. Prof. Soedarto, SH., Tembalang, Semarang, Indonesia

Received: 17 Sep 2022; Revised: 30 Oct 2022; Accepted: 19 Dec 2022; Published: 31 Dec 2022.
Open Access Copyright 2022 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

Citation Format:
Abstract
In this study, the lead oxide has been successfully synthesized using oxidizing agents (NH4)2S2O8 and applied to decolorize the Remazole Black B (RBB) solution. Lead oxide was synthesized by the batch method through the mechanism of reduction-oxidation and characterized using SEM-EDX and XRD. Decolorizing RBB solution was performed using a modified Fenton method. This study aims to determine the optimum performance of RBB decolorization from lead oxide. The results showed that the crystal formed contains Pb and O. Pb oxide obtained was α-PBO2 with the orthorhombic crystal system. Based on characterization, the lead oxide obtained has a surface morphology of coral flowers-like. Synthesis utilizing equilibrium composition (1:2) and a drying temperature of 100°C yielded Pb oxide, which has a better potential as a modifier in RBB decolorization with a decolorization percentage of 80.07%. The process was then carried out for advanced synthesis less and excess of molar variations. The ratio of lead oxide: NaOH (1:4) showed optimum performance in decolorizing RBB with a decolorization percentage of 80.07 %.
Fulltext View|Download
Keywords: Lead oxide; decolorization; Remazol Black Blue; (NH4)2S2O8
Funding: Universitas Diponegoro

Article Metrics:

Article Info
Section: Research Articles
Language : EN
Recent articles
Synthesis of Lead Oxide Using the Oxidizing Agent (NH4)2S2O8 with Variaous Amounts of NaOH for Decolorization of Remazol Black B Solution Isolation and Antioxidant Activity of Flavonoid Compound in Ethanolic Extract of Celery Leaves (Apium graveolens L.) Effect of Ascorbic Acid Concentration on Cu2O Production for Photoelectrochemical Water Splitting on Photocathode Thin Films More recent articles
Most cited articles
Pengaruh Variasi Jenis Asam terhadap Karakter Nanosilika yang Disintesis dari Abu Sekam Padi Penentuan Total Kadar Fenol dari Daun Kersen Segar, Kering dan Rontok (Muntingia calabura L.) serta Uji Aktivitas Antioksidan dengan Metode DPPH Total Hyptolide of Indonesian Hyptis pectinata extracts in a various solvent using HPLC and UV-Vis spectroscopy and their toxicities Pemanfaatan Limbah Penyulingan Bunga Kenanga sebagai Kompos dan Pengaruh Penambahan Zeolit terhadap Ketersediaan Nitrogen Tanah Pengolahan Limbah Cair Industri Batik dengan Metoda Elektrokoagulasi Menggunakan Besi Bekas Sebagai Elektroda More cited articles
  1. Mohammad Mehdi Baneshi, Behnaz Naraghi, Somayeh Rahdar, Hamed Biglari, Mehdi Saeidi, Morteza Ahamadabadi, Mohammad Reza Narooie, Arsalan Salimi, Razieh Khaksefidi, Vali Alipour, Removal of remazol black B dye from aqueous solution by electrocoagulation equipped with iron and aluminium electrodes, IIOAB Journal, 7, Suppl 2, (2016), 529-535
  2. Adel Al-Kdasi, Azni Idris, Katayon Saed, Chuah Teong Guan, Treatment of textile wastewater by advanced oxidation processes—a review, Global NEST Journal, 6, 3, (2004), 222-230 https://doi.org/10.30955/gnj.000288
  3. Hasan Karami, Mohammad Ali Karimi, Saeed Haghdar, Abbas Sadeghi, Rasool Mir-Ghasemi, Saeed Mahdi-Khani, Synthesis of lead oxide nanoparticles by sonochemical method and its application as cathode and anode of lead-acid batteries, Materials Chemistry and Physics, 108, 2-3, (2008), 337-344 https://doi.org/10.1016/j.matchemphys.2007.09.045
  4. K. T. Arulmozhi, N. Mythili, Studies on the chemical synthesis and characterization of lead oxide nanoparticles with different organic capping agents, AIP Advances, 3, 12, (2013), 122122 https://doi.org/10.1063/1.4858419
  5. Shahram Ghasemi, Hassan Karami, Hassan Khanezar, Hydrothermal synthesis of lead dioxide/multiwall carbon nanotube nanocomposite and its application in removal of some organic water pollutants, Journal of Materials Science, 49, 3, (2014), 1014-1024 https://doi.org/10.1007/s10853-013-7778-7
  6. Minhua Cao, Changwen Hu, Ge Peng, Yanjuan Qi, Enbo Wang, Selected-control synthesis of PbO2 and Pb3O4 single-crystalline nanorods, Journal of the American Chemical Society, 125, 17, (2003), 4982-4983 https://doi.org/10.1021/ja029620l
  7. R. Inguanta, F. Vergottini, G. Ferrara, S. Piazza, C. Sunseri, Effect of temperature on the growth of α-PbO2 nanostructures, Electrochimica Acta, 55, 28, (2010), 8556-8562 https://doi.org/10.1016/j.electacta.2010.07.073
  8. Muhamad Abduh Hasibuan, Didik Setiyo Widodo, Retno Ariadi Lusiana, Decolorization of Remazol Black B Solution by PbO2 Modified Fenton Method in a Scaled Up Reactor, Jurnal Kimia Sains dan Aplikasi, 21, 2, (2018), 59-63 https://doi.org/10.14710/jksa.21.2.59-63
  9. Doni Sugiyana, Yulianti Harja, Dekolorisasi Fotokatalitik Air Limbah Tekstil Mengandung Zat Warna Azo Acid Red 4 Menggunakan Mikropartikel TiO2 Dan ZnO, Arena Tekstil, 29, 1, (2016), 9-16
  10. R. E. Smallman, R. J. Bishop, Metalurgi fisik modern dan rekayasa material, S. Djaprie, Erlangga, Jakarta, 2000
  11. Dinesh Pratap Singh, Onkar Nath Srivastava, Synthesis of Micron-sized Hexagonal and Flower-like Nanostructures of Lead Oxide (PbO2) by Anodic Oxidation of Lead, Nano-Micro Letters, 3, 4, (2011), 223-227 https://doi.org/10.1007/BF03353676
  12. Dale L Perry, Lead oxides: synthesis and applications, in: A. Facchetti, T.J. Marks (Eds.) Transparent Electronics: From Synthesis to Applications, Wiley, West Sussex, United Kingdom, 2010, https://doi.org/10.1002/9780470710609.ch4

Last update:

No citation recorded.

Last update: 2024-11-20 16:08:51

No citation recorded.