DOI: https://doi.org/10.14710/jksa.27.7.344-353

Synthesis and Characterization Membrane Nanofibers Cellulose Acetate-Zeolite for Metal Pb (II) Adsorption

1Department of Physics, Faculty of Science and Technology, Universitas Islam Negeri Walisongo, Semarang, Indonesia

2Department of Chemistry, Faculty of Science and Technology, Universitas Islam Negeri Walisongo, Semarang, Indonesia

Received: 27 Oct 2023; Revised: 21 May 2024; Accepted: 27 May 2024; Published: 31 Jul 2024.
Open Access Copyright 2024 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

Citation Format:
Cover Image
Abstract
Heavy metal waste, such as lead (Pb), released into the environment negatively affects ecosystems and human health due to its toxic properties. Consequently, it is imperative to develop methods to remove Pb from the environment. One widely used method is adsorption. Synthesizing adsorbents via electrospinning offers several advantages: simplicity, the ability to produce nano-sized fibers, lightness, chemical stability, and reusability. This research aims to determine the optimum conditions for synthesizing cellulose acetate (CA) nanofibers modified with zeolite (CA-Zeolite) by electrospinning to characterize them and evaluate their adsorption capacity. The research results showed that the optimum conditions for the synthesis of cellulose acetate nanofibers were a solution concentration of 14% (w/v), a voltage of 10.5 kV, a flow rate of 0.02 mL/hour, and a tip-to-collector distance of 10 cm. The FTIR spectrum of CA-Zeolite revealed a new peak in the 400-610 cm-1 wavelength range, indicative of O-Si-O bonds, characteristic of zeolite functional groups, confirming the successful incorporation of zeolite into the CA nanofibers. From the SEM data, it can be seen that the addition of 6% (w/w) zeolite reduced the average membrane fiber diameter from 662.4 nm to 353.1 nm. EDX results show the presence of Si and Al elements in the CA-Zeolite nanofiber membrane. Incorporating zeolite into CA nanofibers decreased the contact angle from 125.49° to 111.66°, enhancing hydrophilicity. The modified CA nanofibers with 6% (w/v) zeolite demonstrated an adsorption capacity of 1.595 mg/g.
Fulltext View|Download
Keywords: Heavy metal; nanofibers membrane; electrospinning

Article Metrics:

Article Info
Section: 18th Joint Conference on Chemistry 2023
Language : EN
Recent articles
Virtual Screening of Syzygium cumini (L.) Skeels Flavonoid Compounds as SARS-CoV-2 Main Protease Therapy Candidates Comparison of the Lipoamide Synthesis by Direct Amidation and via Amidation of Fatty Acid Methyl Esters A Cycloartane Triterpenoid and Steroid from The Leaves of Aglaia shawiana Merr. (Meliaceae) Synthesis and Characterization Membrane Nanofibers Cellulose Acetate-Zeolite for Metal Pb (II) Adsorption More recent articles
Most cited articles
New Chemicals and Routes for the Preparation of Gelatin/HA Composites using the Wet Precipitation Method Pengaruh Variasi Jenis Asam terhadap Karakter Nanosilika yang Disintesis dari Abu Sekam Padi Pengaruh Diameter Kanal Pelet Katalis Zeolit Aktif dan Ni-Zeolit terhadap Pirolisis Limbah Batang Pohon Sagu (Metroxylonsp.) Isolation of Flavonoid Compounds from Eceng Gondok (Eichhornia crassipes) and Antioxidant Tests with DPPH (1,1-Diphenyl-2-Picrylhydrazyl) Method Total Hyptolide of Indonesian Hyptis pectinata extracts in a various solvent using HPLC and UV-Vis spectroscopy and their toxicities More cited articles
  1. Bingyu Bai, Xue Mi, Xu Xiang, Patricia A. Heiden, Caryn L. Heldt, Non-enveloped virus reduction with quaternized chitosan nanofibers containing graphene, Carbohydrate Research, 380, (2013), 137-142 https://doi.org/10.1016/j.carres.2013.08.020
  2. Christos N. Christou, Theodora Krasia-Christoforou, Chapter 8 - Nanostructured electrospun fibers in environmental applications, in: V. Guarino, M.L. Focarete, D. Pisignano (Eds.) Advances in Nanostructured Materials and Nanopatterning Technologies, Elsevier, 2020, https://doi.org/10.1016/B978-0-12-816865-3.00008-1
  3. World Health Organization, 1 in 3 people globally do not have access to safe drinking water – UNICEF, WHO, World Health Organization, 2019
  4. Maryam Salehi, Global water shortage and potable water safety; Today’s concern and tomorrow’s crisis, Environment International, 158, (2022), 106936 https://doi.org/10.1016/j.envint.2021.106936
  5. Noor Mohammad, Yomen Atassi, Enhancement of removal efficiency of heavy metal ions by polyaniline deposition on electrospun polyacrylonitrile membranes, Water Science and Engineering, 14, 2, (2021), 129-138 https://doi.org/10.1016/j.wse.2021.06.004
  6. Victor Cardoso-Jaime, Nichole A. Broderick, Krystal Maya-Maldonado, Metal ions in insect reproduction: a crosstalk between reproductive physiology and immunity, Current Opinion in Insect Science, 52, (2022), 100924 https://doi.org/10.1016/j.cois.2022.100924
  7. Kibrom Alebel Gebru, Chandan Das, Removal of Pb (II) and Cu (II) ions from wastewater using composite electrospun cellulose acetate/titanium oxide (TiO2) adsorbent, Journal of Water Process Engineering, 16, (2017), 1-13 https://doi.org/10.1016/j.jwpe.2016.11.008
  8. Duy-Nam Phan, Muhammad Qamar Khan, Ngoc-Thang Nguyen, Thanh-Thao Phan, Azeem Ullah, Muzamil Khatri, Nguyen Ngoc Kien, Ick-Soo Kim, A review on the fabrication of several carbohydrate polymers into nanofibrous structures using electrospinning for removal of metal ions and dyes, Carbohydrate Polymers, 252, (2021), 117175 https://doi.org/10.1016/j.carbpol.2020.117175
  9. Marcel Mulder, Basic Principles of Membrane Technology, Springer Dordrecht, 1996, ^ https://doi.org/10.1007/978-94-009-1766-8
  10. Hyeong Yeol Choi, Jong Hyuk Bae, Yohei Hasegawa, Sol An, Ick Soo Kim, Hoik Lee, Myungwoong Kim, Thiol-functionalized cellulose nanofiber membranes for the effective adsorption of heavy metal ions in water, Carbohydrate Polymers, 234, (2020), 115881 https://doi.org/10.1016/j.carbpol.2020.115881
  11. Nicole Angel, Liping Guo, Feng Yan, Hui Wang, Lingyan Kong, Effect of processing parameters on the electrospinning of cellulose acetate studied by response surface methodology, Journal of Agriculture and Food Research, 2, (2020), 100015 https://doi.org/10.1016/j.jafr.2019.100015
  12. Fan Zhu, Yu-Ming Zheng, Bao-Gang Zhang, Yun-Rong Dai, A critical review on the electrospun nanofibrous membranes for the adsorption of heavy metals in water treatment, Journal of Hazardous Materials, 401, (2021), 123608 https://doi.org/10.1016/j.jhazmat.2020.123608
  13. Seeram Ramakrishna, Kazutoshi Fujihara, Wee-Eong Teo, Teik-Cheng Lim, Zuwei Ma, An Introduction To Electrospinning And Nanofibers, World Scientific Publishing Company, 2005, ^ https://doi.org/10.1142/5894
  14. Ye Tian, Min Wu, Ruigang Liu, Yanxiang Li, Deqian Wang, Junjun Tan, Rongcheng Wu, Yong Huang, Electrospun membrane of cellulose acetate for heavy metal ion adsorption in water treatment, Carbohydrate Polymers, 83, 2, (2011), 743-748 https://doi.org/10.1016/j.carbpol.2010.08.054
  15. Weiwen Wang, Jixin Lin, Jiaqi Cheng, Zhixiang Cui, Junhui Si, Qianting Wang, Xiangfang Peng, Lih-Sheng Turng, Dual super-amphiphilic modified cellulose acetate nanofiber membranes with highly efficient oil/water separation and excellent antifouling properties, Journal of Hazardous Materials, 385, (2020), 121582 https://doi.org/10.1016/j.jhazmat.2019.121582
  16. Alenka Ojstršek, Darinka Fakin, Silvo Hribernik, Tomaž Fakin, Matej Bračič, Manja Kurečič, Electrospun nanofibrous composites from cellulose acetate / ultra-high silica zeolites and their potential for VOC adsorption from air, Carbohydrate Polymers, 236, (2020), 116071 https://doi.org/10.1016/j.carbpol.2020.116071
  17. Fatemeh Mehrabi, Tayebeh Shamspur, Ali Mostafavi, Asma Saljooqi, Fariba Fathirad, Synthesis of cellulose acetate nanofibers and its application in the release of some drugs, Nanomedicine Research Journal, 2, 3, (2017), 199-207 https://doi.org/10.22034/nmrj.2017.03.008
  18. Ervin Tri Suryandari, Muhammad Ali Zulfikar, Rino R. Mukti, Muhamad Nasir, Preparation and Characterization of Poly(Methyl Methacrylate) (PMMA) Fibers by Electrospinning, Key Engineering Materials, 811, (2019), 163-169 https://doi.org/10.4028/www.scientific.net/KEM.811.163
  19. Abigail P. Cid-Andres, Mary Joy P. Concepcion, Edmar J. Borja, Occurrence of Lead, Cadmium and Mercury in Seaweeds from Calatagan, Batangas, Philippines, Journal of Science and Technology, 8, (2015), 1-10
  20. Xiaoyan Yuan, Yuanyuan Zhang, Cunhai Dong, Jing Sheng, Morphology of ultrafine polysulfone fibers prepared by electrospinning, Polymer International, 53, 11, (2004), 1704-1710 https://doi.org/10.1002/pi.1538
  21. Xinhua Zong, Kwangsok Kim, Dufei Fang, Shaofeng Ran, Benjamin S. Hsiao, Benjamin Chu, Structure and process relationship of electrospun bioabsorbable nanofiber membranes, Polymer, 43, 16, (2002), 4403-4412 https://doi.org/10.1016/S0032-3861(02)00275-6
  22. Shaheen Fatima Anis, Raed Hashaikeh, Electrospun zeolite-Y fibers: Fabrication and morphology analysis, Microporous and Mesoporous Materials, 233, (2016), 78-86 https://doi.org/10.1016/j.micromeso.2015.11.022
  23. R. R. Aquino, M. S. Tolentino, R. M. P. D. Elacion, R. Ladrillono, T. R. C. Laurenciana, B. A. Basilia, Adsorptive removal of lead (Pb2+) ion from water using cellulose acetate/polycaprolactone reinforced nanostructured membrane, IOP Conference Series: Earth and Environmental Science, 191, (2018), 012139 https://doi.org/10.1088/1755-1315/191/1/012139

Last update:

No citation recorded.

Last update: 2024-11-21 22:31:25

No citation recorded.