Two-Stage Hydrothermal Synthesis of TiO₂ Nanotubes with Variation of Precursor Type for Diazinon Photodegradation

Tanti Haryati; Mustafid A’yun Assiddiq; Suwardiyanto Suwardiyanto; Novita Andarini; Yudi Aris Sulistiyo

doi:10.14710/jksa.28.4.195-199

DOI: https://doi.org/10.14710/jksa.28.4.195-199

Two-Stage Hydrothermal Synthesis of TiO₂ Nanotubes with Variation of Precursor Type for Diazinon Photodegradation

Tanti Haryati

, Mustafid A’yun Assiddiq, Suwardiyanto Suwardiyanto

, Novita Andarini

, Yudi Aris Sulistiyo

Department of Chemistry, Faculty of Mathematics and Natural Science, University of Jember, Jember 68121, Indonesia

Received: 24 Oct 2024; Revised: 23 Apr 2025; Accepted: 5 May 2025; Published: 31 May 2025.

BibTex Citation Data :

@article{JKSA67673,
    author = {Tanti Haryati and Mustafid A’yun Assiddiq and Suwardiyanto Suwardiyanto and Novita Andarini and Yudi Aris Sulistiyo},
    title = {Two-Stage Hydrothermal Synthesis of TiO₂ Nanotubes with Variation of Precursor Type for Diazinon Photodegradation},
    journal = {Jurnal Kimia Sains dan Aplikasi},
  volume = {28},
    number = {4},
    year = {2025},
    keywords = {TiO2 precursor; hydrothermal; TiO2 nanotube (TNTs); photocatalytic; diazinon},
    abstract = { TiO 2  is commonly used as a photocatalyst for the photodegradation of harmful chemical compounds, such as diazinon. Its photocatalytic properties can be enhanced by fabricating it into nanotubes. TiO 2  nanotube (TNTs) has a large surface area with good photon absorption and electron transport. This study aims to determine the effect of precursor type on the morphology, crystal structure, and photocatalytic activity of the resulting TNTs against diazinon. TNTs synthesis was carried out through a two-stage hydrothermal method using TiO 2  micro powder precursors in anatase and rutile phases. The photocatalytic activity of TNTs was tested against diazinon photodegradation. The morphology of TNTs resulting from the first and second hydrothermal processes was fiber-shaped for anatase TNP precursor (TNPa) and rutile TNP precursor (TNPr). TEM characterization showed that the TNT particles were tubular with an outer diameter of 2.27-10.92 nm and an inner diameter of 1.10-4.2 nm. Some impurities, such as sodium titanate and hydrogen titanate, still appear in the diffraction patterns of TNTa and TNTr. The TNTr photocatalyst underwent crystal phase transformation into anatase, which was compared with the JCPDS data. The percentage of degradation for TNTa photocatalyst is slightly greater than TNTr, reaching 85.9% and 82.4%, respectively. },
   issn = {2597-9914},   pages = {195--199}  doi = {10.14710/jksa.28.4.195-199},
    url = {https://ejournal.undip.ac.id/index.php/ksa/article/view/67673}
}

Citation Format:

Abstract

TiO₂ is commonly used as a photocatalyst for the photodegradation of harmful chemical compounds, such as diazinon. Its photocatalytic properties can be enhanced by fabricating it into nanotubes. TiO₂ nanotube (TNTs) has a large surface area with good photon absorption and electron transport. This study aims to determine the effect of precursor type on the morphology, crystal structure, and photocatalytic activity of the resulting TNTs against diazinon. TNTs synthesis was carried out through a two-stage hydrothermal method using TiO₂ micro powder precursors in anatase and rutile phases. The photocatalytic activity of TNTs was tested against diazinon photodegradation. The morphology of TNTs resulting from the first and second hydrothermal processes was fiber-shaped for anatase TNP precursor (TNPa) and rutile TNP precursor (TNPr). TEM characterization showed that the TNT particles were tubular with an outer diameter of 2.27-10.92 nm and an inner diameter of 1.10-4.2 nm. Some impurities, such as sodium titanate and hydrogen titanate, still appear in the diffraction patterns of TNTa and TNTr. The TNTr photocatalyst underwent crystal phase transformation into anatase, which was compared with the JCPDS data. The percentage of degradation for TNTa photocatalyst is slightly greater than TNTr, reaching 85.9% and 82.4%, respectively.

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Keywords: TiO2 precursor; hydrothermal; TiO2 nanotube (TNTs); photocatalytic; diazinon

Funding: University of Jember under contract Hibah Keris 2024

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Section: Research Articles

Language : EN

In Vol 28, No 4 (2025): Volume 28 Issue 4 Year 2025

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