DOI: https://doi.org/10.14710/ijred.6.3.193-201

Thermal Decomposition and Kinetic Studies of Pyrolysis of Spirulina Platensis Residue

Universitas Gadjah Mada, Indonesia

Published: 6 Nov 2017.
Editor(s): H Hadiyanto

Citation Format:
Abstract

 Analysis of thermal decomposition and pyrolisis reaction kinetics of Spirulina platensis residue (SPR) was performed using Thermogravimetric Analyzer. Thermal decomposition was conducted with the heating rate of 10, 20, 30, 40 and 50oC/min from 30 to 1000oC. Thermogravimetric (TG), Differential Thermal Gravimetric (DTG), and Differential Thermal Analysis (DTA) curves were then obtained. Each of the curves was divided into 3 stages. In Stage I, water vapor was released in endothermic condition. Pyrolysis occurred in exothermic condition in Stage II, which was divided into two zones according to the weight loss rate, namely zone 1 and zone 2. It was found that gasification occurred in Stage III in endothermic condition. The heat requirement and heat release on thermal decomposition of SPR are described by DTA curve, where 3 peaks were obtained for heating rate 10, 20 and 30°C/min and 2 peaks for 40 and 50°C/min, all peaks present in Zone 2. As for the DTG curve, 2 peaks were obtained in Zone 1 for similar heating rates variation. On the other hand, thermal decomposition of proteins and carbohydrates is indicated by the presence of peaks on the DTG curve, where lignin decomposition do not occur due to the low lipid content of SPR (0.01wt%). The experiment results and calculations using one-step global model successfully showed that the activation energy (Ea) for the heating rate of 10, 20, 30, 40 and 50oC/min for zone 1 were 35.455, 41.102, 45.702, 47.892 and 47.562 KJ/mol, respectively, and for zone 2 were 0.0001428, 0.0001240, 0.0000179, 0.0000100 and 0.0000096 KJ/mol, respectively.

Keywords: Spirulina platensis residue (SPR), Pyrolysis, Thermal decomposition, Peak, Activation energy.

Article History: Received June 15th 2017; Received in revised form August 12th 2017; Accepted August 20th 2017; Available online

How to Cite This Article: Jamilatun, S., Budhijanto, Rochmadi, and Budiman, A. (2017) Thermal Decomposition and Kinetic Studies of Pyrolysis of Spirulina platensis Residue, International Journal of Renewable Energy Development 6(3), 193-201.

https://doi.org/10.14710/ijred.6.3.193-201

Fulltext View|Download
Keywords: Spirulina platensis residue (SPR); Pyrolysis Thermal decomposition; Peak; Activation energy
Funding: Directorate General of Higher Education, Ministry of Research Technology and Higher Education, the Republic of Indonesia; Universitas gadjah Mada

Article Metrics:

Article Info
Section: Original Research Article
Language : EN
Recent articles
Sizing and Optimization for Hybrid Central in South Algeria Based on Three Different Generators The Determinants Factors of Biogas Technology Adoption in Cattle Farming: Evidences from Pati, Indonesia Performance Evaluation of PV Panel Under Dusty Condition More recent articles
Most cited articles
Simulation of biogas utilization effect on the economic efficiency and greenhouse gas emission: a case study in Isfahan, Iran Optimal Operation of Micro-grids Considering the Uncertainties of Demand and Renewable Energy Resources Generation Empowering Distributed Solar PV Energy for Malaysian Rural Housing: Towards Energy Security and Equitability of Rural Communities Wind Resource Assessment in Abadan Airport in Iran Biodiesel Production From the Microalgae Nannochloropsis by Microwave Using CaO and MgO Catalysts More cited articles
  1. Agrawal, A. & Chakraborty, S. (2013) A kinetic study of pyrolysis and combustion of microalgae Chlorella vulgaris using thermo-gravimetric analysis. Bioresour. Technol., 128, 72–80
  2. Ananda, V., Sunjeeva, V. & Vinua, R. (2016) Catalytic fast pyrolysis of Arthrospira platensis (spirulina) algae using zeolites. J. Anal. Appl. Pyrolysis, 118, 298–307
  3. Chisti, Y. (2008) Biodiesel from microalgae beats bioethanol. Trends. Biotechnol., 26, 126 - 131. doi: 10.1016/j.tibtech.2007.12.002
  4. Chaiwong, K., Kiatsiriroat, T., Vorayos, N. & Thararax, C. (2013) Study of bio-oil and bio-char production from algae by slow pyrolysis. Biomass Bioenerg., 56, 600-606
  5. Ceylan, S., Topcu, Y. & Ceylan, Z. (2014) Thermal behaviour and kinetics of algae Polysiphonia elongata biomass during pyrolysis. Bioresour. Technol., 171, 193–198
  6. Chen, W.H., Lin, B-J., Huang, M-Y. & Chang, J-S. (2015) Thermochemical conversion of microalgal biomass into biofuels: A review. Bioresour. Technol., 184, 314–327
  7. Dragone, G., Fernandes, B., Vicente, A. & Teixeira, J.A. (2010) Third generation biofuels from microalgae. In: Vilas AM, editor. Current research, technology and education topics in applied microbiology and microbial biotechnology. Badajoz: Formatex Research Center; 1355-66
  8. De Wild, P.J., Reith, H. & Heeres, H.J. (2011) Biomass pyrolysis for chemicals. Biofuels, 2 (2), 185 – 208
  9. Daniyanto, Sutijan, Deendarlianto, & Budiman, A. (2016) Reaction kinetic of pyrolysis in mechanism of pyrolysis-gasification process of dry torrified-sugarcane bagasse. ARPN Journal of Engineering and Applied Sciences, 11, Issue 16, 9974-9980
  10. El-Sayed, S.A. & Mostafa, M.E. (2014) Pyrolysis characteristics and kinetic parameters determination of biomass fuel powders by differential thermal gravimetric analysis (TGA/DTG). Energ. Conversion and Manag, 85, 165–172
  11. Hadiyanto, Widayat & Kumoro, A.C. (2012) Potency of microalgae as biodiesel source in Indonesia. Int. Journal of Renewable Energy Development, 1, 23-27
  12. Hadiyanto H., Christwardana, M. & Soetri, D. (2013) Phytoremediations of palm oil mill effluent (POME) by using aquatic plants and microalgae for biomass production. Journal of Environmental and Technology. ISSN 1994-7887/DOI: 10.3923/jest.2013
  13. Hu, M., Chen, Z., Guo, D., Liu, C., Xiao, B., Hu, Z. & Liu, S. (2015) Thermogravimetric study on pyrolysis kinetics of Chlorella pyrenoidosa and bloom-forming cyanobacteria. Bioresour Technol., 177, 41–50
  14. Lia, J., Wanga, G., Wanga, Z., Zhanga, L., Wang, C. & Yang, Z. (2013) Conversion of Enteromorpha prolifera to high-quality liquid oil viadeoxy-liquefaction. J. Anal. Appl. Pyrolysis, 104, 494–501
  15. Li, S., Ma, X., Liu, G. & Guo, M. (2016) A TG–FTIR investigation to the co-pyrolysis of oil shale with coal. J. Anal. Appl. Pyrolysis, 120, 540–548
  16. Ojolo, S.J., Oshekub, C.A. & Sobamowoa, M.G. (2013) Analytical investigations of kinetic and heat transfer in slow pyrolysis of a biomass particle. Int. Journal of Renewable Energy Development, 2 (2), 105-115
  17. Prakash, N. & Karunanithi, T. (2008) Kinetic modeling in biomass pyrolysis – A Review. J. Appl. Sci. Res., 4(12), 1627-1636
  18. Pratama, N.N. & Saptoadi, H. (2014) Characteristics of waste plastics pyrolytic oil and its applications as alternative fuel on our cylinder diesel engines. Int. Journal of Renewable Energy Development, 3 (1), 13-20
  19. Sunarno, Herman, S., Rochmadi, Mulyono, P. & Budiman, A. (2017) Effect of Support on Catalytic Cracking of Bio-Oil over Ni/Silica-Alumina. AIP Conference Proceedings 1823, 020089; doi: 10.1063/1.4978162
  20. Suganya, T., Varman, M., Masjuki, H.H. & Renganathan, S. (2016) Macroalgae and microalgae as a potential source for commercial applications along with biofuels production: A biorefinery approach. Renew Sust Energ Rev, 55, 909–941
  21. Wijffels, R.H., Barbosa, M.J. & Eppink, M.H.M. (2010) Microalgae for the production of bulk chemicals and biofuels. Biofuels Bioproducts & Biorefining-Biofpr. 4(3), 287-295
  22. Widiyannita, A.M., Cahyono, R.B., Budiman, Sutijan, A. & Akiyama, T. (2015) Study of pyrolysis of ulin wood residues. AIP Conference Proceedings 1755, 050004
  23. Wang, X., Hu, M., Hu, W., Chen, Z., Liu, S., Hu, Z. & Xiao, B. (2016) Thermogravimetric kinetic study of agricultural residue biomass pyrolysis based on combined kinetics. Bioresour. Technol., 219, 510–52
  24. Wicakso, D.R., Sutijan, Rochmadi, & Budiman, A. (2017) Study of catalytic upgrading of biomass tars using Indonesian iron ore. AIP Conference Proceedings 1823, 020094; doi: 10.1063/1.4978167

Last update:

  1. Rheological and kinetic studies of low density polyetyhlene (LDPE) – chitosan biocomposite film

    Y Kusumastuti, D Timotius, N R E Putri, M W Syabani, Rochmadi. IOP Conference Series: Materials Science and Engineering, 722 (1), 2020. doi: 10.1088/1757-899X/722/1/012054

  2. Inorganic elemental composition analysis of Arthrospira platensis-Activated carbon blend at mass ratio of 10:1 for considering its thermal conversion characteristics

    Ahmad Yusril Aminullah, Yahya Zakaria, Sukarni Sukarni, Avita Ayu Permanasari, Samsudin Anis, Anwar Johari. PROCEEDINGS OF THE 7TH INTERNATIONAL SYMPOSIUM ON CURRENT PROGRESS IN MATHEMATICS AND SCIENCES 2021, 3163 , 2024. doi: 10.1063/5.0228178

  3. Moving towards Valorization of Biowastes Issued from Biotrickling Filtration of Contaminated Gaseous Streams: A Thermochemical Analysis-Based Perspective

    Gabriela Lisa, Ion Anghel, Dana-Maria Preda, Catalin Lisa, Igor Cretescu, Ingrid Ioana Buciscanu, Mariana Diaconu, Gabriela Soreanu. Sustainability, 14 (17), 2022. doi: 10.3390/su141710737

  4. Advances in Manufacturing IV

    Sara Díaz, Zaida Ortega, Raúl Ríos. Lecture Notes in Mechanical Engineering, 2024. doi: 10.1007/978-3-031-56463-5_18

  5. Bio-Oil Characterizations of Spirulina Platensis Residue (SPR) Pyrolysis Products for Renewable Energy Development

    Siti Jamilatun, Aster Rahayu, Yano Surya Pradana, Budhijanto, Rochmadi, Arief Budiman. Key Engineering Materials, 849 , 2020. doi: 10.4028/www.scientific.net/KEM.849.47

  6. Conversion of bio-coke from Spirulina platensis microalgae as an alternative sustainable energy

    Nur Syahirah Kamal Baharin, Yoshinobu Ikeda, Ken Moizumi, Tamio Ida. Case Studies in Chemical and Environmental Engineering, 9 , 2024. doi: 10.1016/j.cscee.2024.100709

  7. Co-pyrolysis of empty fruit bunches impregnated with Ni and lignite into liquid oil

    Sunarno, Nada Zafirah, Tesa Agustin, Silvia Reni Yenti, Wisrayetti, Syamsu Herman, Syaiful Bahri. Materials Today: Proceedings, 63 , 2022. doi: 10.1016/j.matpr.2022.01.174

  8. Conversion of bio-coke from microalgae as a potential strategy for double fuel technology

    Nur Syahirah Kamal Baharin, Yoshinobu Ikeda, Ken Moizumi, Tamio Ida. 4TH INTERNATIONAL CONFERENCE ON SEPARATION TECHNOLOGY: SEPARATION TECHNOLOGY: RISING TOWARDS GREENER FUTURE, 3041 , 2024. doi: 10.1063/5.0195086

  9. Thermogravimetric Analysis and Kinetic Study on Catalytic Pyrolysis of Rice Husk Pellet using Its Ash as a Low-cost In-situ Catalyst

    Wusana Agung Wibowo, Rochim Bakti Cahyono, Rochmadi Rochmadi, Arief Budiman. International Journal of Renewable Energy Development, 11 (1), 2022. doi: 10.14710/ijred.2022.41887

  10. Characterization of Microalgae Biomass-Based Composites Obtained through Rotational Molding

    Sara Díaz, Francisco Romero, Luis Suárez, Raúl Ríos, Monserrat Alemán, Marianna Venuleo, Zaida Ortega. Polymers, 16 (13), 2024. doi: 10.3390/polym16131807

  11. Kinetic Study of Copyrolysis of the Green Microalgae Botryococcus braunii and Victorian Brown Coal by Thermogravimetric Analysis

    R. R. Dirgarini Julia Nurlianti Subagyono, Wardina Masdalifa, Siti Aminah, Rudy Agung Nugroho, Mamun Mollah, Veliyana Londong Allo, Rahmat Gunawan. ACS Omega, 6 (47), 2021. doi: 10.1021/acsomega.1c04818

  12. Catalytic Co-Pyrolysis of Palm Oil Empty Fruit Bunch and Coal into Liquid Oil

    Sunarno Sunarno, Ronna Puspita Sari, Tifanny Frimacia, Silvia Reni Yenti, Panca Setia Utama, Edy Saputra. International Journal of Renewable Energy Development, 11 (2), 2022. doi: 10.14710/ijred.2022.42193

  13. Catalytic and non−catalytic pyrolysis of Spirulina platensis residue (SPR): Effects of temperature and catalyst content on bio-oil yields and its composition

    Siti Jamilatun, Suhendra, Budhijanto, Rochmadi, Taufikurahman, Avido Yuliestyan, Arief Budiman. THERMOFLUID X: 10th International Conference on Thermofluids 2019, 2248 , 2020. doi: 10.1063/5.0013164

Last update: 2024-12-23 16:43:22

  1. Effects of temperature and catalysts on the yield of bio-oil during the pyrolysis of Spirulina platensis residue

    Jamilatun S.. International Journal of Renewable Energy Research, 10 (2), 2020.

  2. Rheological and kinetic studies of low density polyetyhlene (LDPE) - Chitosan biocomposite film

    Kusumastuti Y.. IOP Conference Series: Materials Science and Engineering, 127 (1), 2020. doi: 10.1088/1757-899X/722/1/012054

  3. Ex-situ catalytic upgrading of Spirulina platensis residue oil using silica alumina catalyst

    Jamilatun S.. International Journal of Renewable Energy Research, 9 (4), 2019.

  4. Catalytic pyrolysis of spirulina platensis residue (SPR): Thermochemical behavior and kinetics

    Jamilatun S.. International Journal of Technology, 11 (3), 2020. doi: 10.14716/ijtech.v11i3.2967

  5. Effect Of Grain Size, Temperature And Catalyst Amount On Pyrolysis Products Of Spirulina Platensis Residue (Spr)

    Jamilatun S.. International Journal of Technology, 10 (3), 2019. doi: 10.14716/ijtech.v10i3.2918

  6. Non-catalytic and Catalytic Pyrolysis of Spirulina platensis residue (SPR) in Fixed-Bed Reactors: Characteristic and Kinetic Study with Primary and Secondary Tar Cracking Models

    Jamilatun S.. International Journal of Renewable Energy Research, 10 (4), 2020.

  7. Catalytic and noncatalytic pyrolysis of spirulina platensis residue (spr): Effects of temperature and catalyst content on bio-oil yields and its composition

    Jamilatun S.. AIP Conference Proceedings, 127 , 2020. doi: 10.1063/5.0013164

  8. In situ resource utilization - Analogues for a lunar constructed magnetron via 3D printing and microwave casting

    Ellery A.. Proceedings of the International Astronautical Congress, IAC, 127 , 2019.

  9. Bio-oil characterizations of spirulina platensis residue (Spr) pyrolysis products for renewable energy development

    Siti J.. Key Engineering Materials, 127 , 2020. doi: 10.4028/www.scientific.net/KEM.849.47