DOI: https://doi.org/10.14710/jksa.23.11.396-402

Synthesis of Sodium Lauryl Sulfate (SLS) and Hexadecyltrimethylammonium Bromide (HDTMA-Br) Surfactant-Modified Activated Carbon as Adsorbent for Pb2+ and NO3-

Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University, Indonesia

Received: 27 May 2020; Revised: 1 Nov 2020; Accepted: 12 Nov 2020; Published: 30 Nov 2020.
Open Access Copyright 2020 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract

The adsorption efficiency and selectivity of activated carbon as an adsorbent for ions can be improved. One way is to convert activated carbon into surfactant modified activated carbon (SMAC). The surfactants used in this study were the anionic surfactant Sodium Lauryl Sulfate (SLS) and the cationic surfactant hexadecyltrimethylammonium bromide (HDTMA-Br). This research aims to synthesize SMAC to obtain a material with a surface charge and absorb ions better than activated carbon. This research consisted of four stages. The first step was the carbonization of rice husks using a pyrolysis reactor at 400°C for 1 hour. The second stage was carbon activation using 30% ZnCl2 and microwave radiation for 5 minutes and 400 W. The third stage was the modification of activated carbon and characterization by FTIR, SEM, SAA. The fourth stage was the adsorption of Pb cations and nitrate anions by carbon, activated carbon, and SMAC. Several variables were applied, such as the type of surfactant, time, and method of modification. There are three ways of modification: (1) method A, in which activated carbon is brought into contact with SLS then HDTMA-Br. (2) Method B in which activated carbon was contacted with HDTMA-Br then SLS. (3) Method C in which activated carbon was brought into contact with SLS together with HDTMA-Br. All variables were investigated. The results showed that the optimum time for making SMAC for both surfactants was 4 hours, the optimum concentrations of SLS and HDTMA-Br were 60 and 300 ppm, respectively. SMAC made by the C method was the most effective at adsorbing Pb2+ and NO3- with adsorption capacities of 1.376 and 0.896 mg/g, respectively. The success of SMAC synthesis was evidenced by the S=O and (CH3)3N+ groups in the FTIR spectra. The SMAC surface area is smaller than activated carbon, 14.472 m2/g, but the surface morphology is smoother and more homogeneous.

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Keywords: Surfactant Modified Activated Carbon; Adsorption; adsorbate
Funding: Diponegoro University

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Section: Research Articles
Language : EN
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  1. Dipa Das, Debi Prasad Samal, BC Meikap, Preparation of activated carbon from green coconut shell and its characterization, Journal of Chemical Engineering & Process Technology, 6, 5, (2015), 1-7 http://doi.org/10.4172/2157-7048.1000248
  2. K. Gunasekaran, P. S. Kumar, M. Lakshmipathy, Mechanical and bond properties of coconut shell concrete, Construction and Building Materials, 25, 1, (2011), 92-98 https://doi.org/10.1016/j.conbuildmat.2010.06.053
  3. Dilek Cuhadaroglu, Oznur Aydemir Uygun, Production and characterization of activated carbon from a bituminous coal by chemical activation, African Journal of Biotechnology, 7, 20, (2008), 3703-3710
  4. Z. A. AlOthman, M. A. Habila, R. Ali, Preparation of activated carbon using the copyrolysis of agricultural and municipal solid wastes at a low carbonization temperature, International Conference on Biology, Environment and Chemistry, 2011
  5. Xuan Du, Wei Zhao, Shuhui Ma, Mingguo Ma, Tao Qi, Yi Wang, Chao Hua, Effect of ZnCl2 impregnation concentration on the microstructure and electrical performance of ramie-based activated carbon hollow fiber, Ionics, 22, 4, (2016), 545-553 https://doi.org/10.1007/s11581-015-1571-3
  6. İlknur Demiral, Canan Aydın Şamdan, Hakan Demiral, Production and characterization of activated carbons from pumpkin seed shell by chemical activation with ZnCl2, Desalination and Water Treatment, 57, 6, (2016), 2446-2454 https://doi.org/10.1080/19443994.2015.1027276
  7. Heng Chen, Zaher Hashisho, Fast preparation of activated carbon from oil sands coke using microwave-assisted activation, Fuel, 95, (2012), 178-182 https://doi.org/10.1016/j.fuel.2011.10.045
  8. Abdurrahman Özhan, Ömer Şahin, Mehmet Maşuk Küçük, Cafer Saka, Preparation and characterization of activated carbon from pine cone by microwave-induced ZnCl2 activation and its effects on the adsorption of methylene blue, Cellulose, 21, 4, (2014), 2457-2467 https://doi.org/10.1007/s10570-014-0299-y
  9. Eko Tri Sumarnadi Agustinus, Anggoro Tri Mursito, Happy Sembiring, Peningkatan daya serap karbon aktif terhadap ion logam hexavalent chromium (CrVI) melalui modifikasi dengan cationic surfactant (ethylinediamine), RISET Geologi dan Pertambangan, 23, 1, (2013), 15-26 http://dx.doi.org/10.14203/risetgeotam2013.v23.66
  10. Wooram Lee, Sangwon Yoon, Jong Kwon Choe, Miran Lee, Yongju Choi, Anionic surfactant modification of activated carbon for enhancing adsorption of ammonium ion from aqueous solution, Science of The Total Environment, 639, (2018), 1432-1439 https://doi.org/10.1016/j.scitotenv.2018.05.250
  11. Ikpa Mba Onwuka, Effectiveness of Coconut Shellactivated Carbon Filtermaterial Produced Under Various Carbonization and Activation Conditions, Federal University of Technology, Owerri, 2019
  12. Paul de Wild, Hans Reith, Erik Heeres, Biomass pyrolysis for chemicals, Biofuels, 2, 2, (2011), 185-208 https://doi.org/10.4155/bfs.10.88
  13. S. E. Abechi, C. E. Gimba, A. Uzairu, Y. A. Dallatu, Preparation and characterization of activated carbon from palm kernel shell by chemical activation, Research Journal of Chemical Sciences, 3, 7, (2013), 54-61
  14. C. Almansa, M. Molina-Sabio, F. Rodríguez-Reinoso, Adsorption of methane into ZnCl2-activated carbon derived discs, Microporous and Mesoporous Materials, 76, 1, (2004), 185-191 https://doi.org/10.1016/j.micromeso.2004.08.010
  15. Teawon Kim, Jaegeun Lee, Kun-Hong Lee, Microwave heating of carbon-based solid materials, Carbon letters, 15, 1, (2014), 15-24 https://doi.org/10.5714/CL.2014.15.1.015
  16. Kamoru A Salam, Assessment of Surfactant Modified Activated Carbon for Improving Water Quality, Journal of Encapsulation and Adsorption Sciences, 9, 1, (2019), 13-34 https://doi.org/10.4236/jeas.2019.91002
  17. Wasif Farooq, Hye-Jin Hong, Eun Jung Kim, Ji-Won Yang, Removal of Bromate (BrO−3) from Water using Cationic Surfactant-Modified Powdered Activated Carbon (SM-PAC), Separation Science and Technology, 47, 13, (2012), 1906-1912 10.1080/01496395.2012.664232
  18. Yingying Zhou, Zhenghua Wang, Andrew Hursthouse, Bozhi Ren, Gemini surfactant-modified activated carbon for remediation of hexavalent chromium from water, Water, 10, 1, (2018), 1-13 https://doi.org/10.3390/w10010091
  19. Arnelli, Laila N. Mastuti, Aulia D. Arini, Yayuk Astuti, Activation of carbon from rice husk using chemical activating agents and physical treatments as sodium lauryl sulfate adsorbent, AIP Conference Proceedings, 2237, 1, (2020), 020010 https://doi.org/10.1063/5.0008302
  20. Arneli, Z. F. Safitri, A. W. Pangestika, F. Fauziah, V. N. Wahyuningrum, Y. Astuti, The influence of activating agents on the performance of rice husk-based carbon for sodium lauryl sulfate and chrome (Cr) metal adsorptions, IOP Conference Series: Materials Science and Engineering, 172, (2017), 012007 http://dx.doi.org/10.1088/1757-899X/172/1/012007
  21. Pandu Jati Laksono, Pemanfaatan Zeolit Alam Termodifikasi Surfaktan HDTMA-Br (Hexadecyltrimethylammonium Bromide) Sebagai Adsorben Anion Nitrat (NO3-), Orbital: Jurnal Pendidikan Kimia, 1, 2, (2017), 40-50 https://doi.org/10.19109/ojpk.v1i2.2490
  22. Milton J. Rosen, Joy T. Kunjappu, Surfactants and Interfacial Phenomena, John Wiley & Sons, 2012
  23. Reyhaneh Saadi, Zahra Saadi, Reza Fazaeli, Narges Elmi Fard, Monolayer and multilayer adsorption isotherm models for sorption from aqueous media, Korean Journal of Chemical Engineering, 32, 5, (2015), 787-799 https://doi.org/10.1007/s11814-015-0053-7
  24. Mahmoud Mazarji, Behnoush Aminzadeh, Majid Baghdadi, Amit Bhatnagar, Removal of nitrate from aqueous solution using modified granular activated carbon, Journal of Molecular Liquids, 233, (2017), 139-148 https://doi.org/10.1016/j.molliq.2017.03.004
  25. Ouiza Allalou, Djamel Miroud, Mohamed Belmedani, Zahra Sadaoui, Performance of surfactant-modified activated carbon prepared from dates wastes for nitrate removal from aqueous solutions, Environmental Progress & Sustainable Energy, 38, s1, (2019), S403-S411 https://doi.org/10.1002/ep.13090

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