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Synthesis of Oil Palm Fronds Charcoal as Adsorbent to Reduce Levels of Fe (III) in Peat Water

Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Riau, Kampus Bina Widya km 12,5 Simpang Baru, Tampan, Pekanbaru, Indonesia

Received: 30 Jun 2022; Revised: 3 Oct 2022; Accepted: 10 Oct 2022; Published: 12 Oct 2022.
Open Access Copyright 2022 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract

The high content of carbon compounds in palm fronds (OPF) makes them potentially useful as an adsorbent. The carbonization method was used for the adsorbent synthesis process. This process began with collecting palm frond waste and then drying and sifting the adsorbent particle. This process resulted in the escape particles with a size of 80 mesh and suspended particles with 120 mesh. Then this process continued by carbonizing the palm fronds with temperature variations starting from (400, 500, and 600°C) for 60 minutes to obtain Charcoal Oil Palm Fronts (COPF). The obtained COPF was determined for moisture and ash content and characterized using FTIR, XRD, and SEM to determine the surface, functional groups, degree of amorphism, crystallinity, and surface morphology. The adsorption efficiency of COPF was applied to the adsorption of Fe (III) in peat water under varying contact time, adsorbent mass, and peat water volume conditions. The water and ash content of COPF qualify the technical quality requirements for activated charcoal according to SNI 06-3730-1995. FTIR analysis detected the presence of vibrations of the C-O, O-H, C=O, C-C, and C-H functional groups on the COPF surface. The XRD pattern showed the existence of a semi-crystalline (002) and (100) plane structure, which is shown at scattering angles of 2θ = 22o and 42o. The surface morphology of COPF showed that as the carbonization temperature increased, the number of pores formed increased, and the pore size decreased. The best adsorption test results were obtained with a contact time of 30 minutes, an adsorbent mass of 1.00 g, and a peat water volume of 100 mL. The highest Fe adsorption efficiency was achieved by COPF 500, where the adsorbed mass was 0.054 mg. Increasing the carbonization temperature causes the water content to decrease and the ash content to increase. High water content and ash content cause a decrease in adsorption efficiency because they can cover the pores of the adsorbent.

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Keywords: Charcoal; Oil palm fronds; Peat water
Funding: Universitas Riau

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  2. S. Maulina, M. Iriansyah, Characteristics of activated carbon resulted from pyrolysis of the oil palm fronds powder, IOP Conference Series: Materials Science and Engineering, 2018 https://doi.org/10.1088/1757-899X/309/1/012072
  3. Rananda Vinsiah, Andi Suharman, D. Desi, Pembuatan karbon aktif dari cangkang kulit buah karet (hevea brasiliensis), Jurnal Teknik Kimia, 6, 1, (2015), 189-199
  4. Muhdarina Muhdarina, Nurhayati Nurhayati, Mhd Reza Pahlepi, Zetria Pujiana, Syaiful Bahri, Penyiapan Arang Aktif Pelepah Kelapa Sawit sebagai Adsorben Asam Lemak Bebas dari CPO (Crude Palm Oil), al-Kimiya: Jurnal Ilmu Kimia dan Terapan, 7, 1, (2020), 7-13 https://doi.org/10.15575/ak.v7i1.6497
  5. Asih Melati, Galih Padmasari, Rama Oktavian, Frida A. Rakhmadi, A comparative study of carbon nanofiber (CNF) and activated carbon based on coconut shell for ammonia (NH3) adsorption performance, Applied Physics A, 128, 3, (2022), 211 https://doi.org/10.1007/s00339-022-05336-z
  6. Khadijah Lestari Lubis, Shinta Elystia, Dini Aulia Sari Ermal, Zultiniar Zultiniar, Penyisihan Logam Fe pada Air Gambut Menggunakan Membran Chitosan sebagai Adsorben: Removal of Fe From Peat Water Using Chitosan Membrane as Adsorbent, Jurnal Sains Teknologi dan Lingkungan, 8, 1, (2022), 15-24 https://doi.org/10.29303/jstl.v8i1.298
  7. Elliska Murni Harfinda, Ca-Alginat untuk Adsorpsi Fe dan Mn pada Air Gambut, Jurnal Kimia Mulawarman, 18, 1, (2020), 16-21 https://doi.org/10.30872/jkm.v18i1.844
  8. Ahmed Y. Elnour, Abdulaziz A. Alghyamah, Hamid M. Shaikh, Anesh M. Poulose, Saeed M. Al-Zahrani, Arfat Anis, Mohammad I. Al-Wabel, Effect of pyrolysis temperature on biochar microstructural evolution, physicochemical characteristics, and its influence on biochar/polypropylene composites, Applied Sciences, 9, 6, (2019), 1149 https://doi.org/10.3390/app9061149
  9. C. L. Lee, P. S. H’ng, M. T. Paridah, K. L. Chin, P. S. Khoo, R. A. R. Nazrin, S. N. Asyikin, M. Mariusz, Effect of reaction time and temperature on the properties of carbon black made from palm kernel and coconut shell, Asian Journal of Scientific Research, 10, 1, (2017), 24-33 https://dx.doi.org/10.3923/ajsr.2017.24.33
  10. Noor Afeefah Nordin, Othman Sulaiman, Rokiah Hashim, Mohamad Haafiz Mohamad Kassim, Characterization of different parts of oil palm fronds (Elaeis guineensis) and its properties, International Journal on Advanced Science, Engineering and Information Technology, 6, 1, (2016), 74-76 https://doi.org/10.18517/ijaseit.6.1.643
  11. Mohd Adib Yahya, Zakaria Al-Qodah, C. W. Zanariah Ngah, Agricultural bio-waste materials as potential sustainable precursors used for activated carbon production: A review, Renewable and Sustainable Energy Reviews, 46, (2015), 218-235 https://doi.org/10.1016/j.rser.2015.02.051
  12. Ananias Francisco Dias, Renata Nunes de Oliveira, Xavier Deglise, Natália Dias de Souza, José Otávio Brito, Infrared spectroscopy analysis on charcoal generated by the pyrolysis of Corymbia. citriodora wood, Matéria (Rio de Janeiro), 24, 3, (2019), 1-7 https://doi.org/10.1590/S1517-707620190003.0700
  13. Saptadi Darmawan, Wasrin Syafii, Nyoman J. Wistara, Akhirudin Maddu, Gustan Pari, Kajian struktur arang-pirolisis, arang-hidro dan karbon aktif dari kayu Acacia mangium Willd. menggunakan difraksi sinar-x, Jurnal Penelitian Hasil Hutan, 33, 2, (2015), 81-92 https://doi.org/10.20886/jphh.2015.33.2.81-92
  14. Rakhmawati Farma, Physical Properties Analysis of Activated Carbon From Oil Palm Empty Fruit Bunch Fiber on Methylene Blue Adsorption, Journal of Technomaterial Physics, 1, 1, (2019), 67-73 https://doi.org/10.32734/jotp.v1i1.824
  15. Panda H., N. Tiadi, M. Mohanty, C. R. Mohanty, Studies on adsorption behavior of an industrial waste for removal of chromium from aqueous solution, South African Journal of Chemical Engineering, 23, 1, (2017), 132-138 https://doi.org/10.1016/j.sajce.2017.05.002
  16. Thanchanok Pagketanang, Apichart Artnaseaw, Prasong Wongwicha, Mallika Thabuot, Microporous activated carbon from KOH-activation of rubber seed-shells for application in capacitor electrode, Energy Procedia, 79, (2015), 651-656 https://doi.org/10.1016/j.egypro.2015.11.550
  17. Pei-Hsing Huang, Shih-Han Chen, Effect of moisture content, system pressure, and temperature on the adsorption of carbon dioxide in carbon nanotube and graphite composite structures using molecular dynamics simulations, Journal of Nanoscience and Nanotechnology, 16, 8, (2016), 8654-8661 https://doi.org/10.1166/jnn.2016.11784
  18. O. A. Ekpete, A. C. Marcus, V. Osi, Preparation and characterization of activated carbon obtained from plantain (Musa paradisiaca) fruit stem, Journal of Chemistry, 2017, 8635615, (2017), 1-7 https://doi.org/10.1155/2017/8635615
  19. Fatemeh Gorzin, M. M. Bahri Rasht Abadi, Adsorption of Cr (VI) from aqueous solution by adsorbent prepared from paper mill sludge: Kinetics and thermodynamics studies, Adsorption Science and Technology, 36, 1-2, (2018), 149-169 https://doi.org/10.1177/0263617416686976
  20. K. S. Padmavathy, G. Madhu, P. V. Haseena, A study on effects of pH, adsorbent dosage, time, initial concentration and adsorption isotherm study for the removal of hexavalent chromium (Cr (VI)) from wastewater by magnetite nanoparticles, Procedia Technology, 24, (2016), 585-594 https://doi.org/10.1016/j.protcy.2016.05.127
  21. Abdulaziz Ali Alghamdi, Abdel-Basit Al-Odayni, Waseem Sharaf Saeed, Abdullah Al-Kahtani, Fahad A. Alharthi, Taieb Aouak, Efficient adsorption of lead (II) from aqueous phase solutions using polypyrrole-based activated carbon, Materials, 12, 12, (2019), 2020 https://doi.org/10.3390/ma12122020
  22. Sri Ayu Emy Istighfarini, Syarfi Daud, Edward Hs, Pengaruh massa dan ukuran partikel adsorben sabut kelapa terhadap efisiensi penyisihan Fe pada air gambut, Environmental Engineering, Riau University, Riau, 2017

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