DOI: https://doi.org/10.14710/jksa.26.4.133-142

Study of Synthesis and Performance of Clay and Clay-Manganese Monoliths for Mercury Ion Removal from Water

Department of Chemical Engineering, Faculty of Engineering, Universitas Syiah Kuala, Aceh, Indonesia

Received: 23 Mar 2023; Revised: 2 Jun 2023; Accepted: 11 Jun 2023; Published: 30 Jun 2023.
Open Access Copyright 2023 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract
The pollution caused by mercury (Hg) is a matter of concern regarding worldwide ecosystems and public health. It is dangerous as it is highly poisonous and has more ways to get exposed than other heavy metal ions. Recently, the application of biomaterials with varying structures and designs for mercury adsorption has grown. In this research, clay monoliths (CM) and clay-manganese monoliths (CMM) were synthesized, investigated, and compared regarding their ability to adsorb mercury ions from water to determine the most effective adsorbents. CM and CMM were extruded through a stainless-steel molder with dimensions of 7 holes, 9 mm in radius, and 20 mm in height. The surface morphologies of both adsorbents were characterized using infrared (IR) spectroscopy and scanning electron microscopy (SEM). The effects of contact time (40, 80, 120, 160, 200, and 240 minutes) and initial concentrations (3–5 mg/L) were applied to evaluate both adsorption processes. The experiment was conducted in a batch reactor using a monolithic adsorbent that operated for 240 minutes. The experimental equilibrium data of the adsorption were examined with Langmuir and Freundlich models to find the best-fit isotherm. In the kinetic study, the pseudo-first-order was investigated in both linear and nonlinear models. The adsorption results showed that CMM had the highest adsorption efficiency (42.7%). The equilibrium study concluded that the Langmuir was the most significant isotherm model. The highest monolayer capacity and Langmuir constants (KL and aL) were 0.396, 1.329, and 0.396, respectively. The adsorption of both adsorbents was well displayed in the pseudo-first-order non-linear model. Experiments and processed data compromise the finding that CMM is more effective than CM at adsorbing mercury ions.
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Keywords: mercury; adsorption; clay; manganese; monolith
Funding: Universitas Syiah Kuala

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Language : EN
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  2. K. Grace Pavithra, P. SundarRajan, P. Senthil Kumar, Gayathri Rangasamy, Mercury sources, contaminations, mercury cycle, detection and treatment techniques: A review, Chemosphere, 312, (2022), 137314 https://doi.org/10.1016/j.chemosphere.2022.137314
  3. Fengyang Wang, Shuxiao Wang, Lei Zhang, Hai Yang, Wei Gao, Qingru Wu, Jiming Hao, Mercury mass flow in iron and steel production process and its implications for mercury emission control, Journal of Environmental Sciences, 43, (2016), 293-301 https://doi.org/10.1016/j.jes.2015.07.019
  4. Fengyang Wang, Shuxiao Wang, Lei Zhang, Hai Yang, Qingru Wu, Jiming Hao, Characteristics of mercury cycling in the cement production process, Journal of Hazardous Materials, 302, (2016), 27-35 https://doi.org/10.1016/j.jhazmat.2015.09.042
  5. Krzysztof Kogut, Jerzy Gorecki, Piotr Burmistrz, Opportunities for reducing mercury emissions in the cement industry, Journal of Cleaner Production, 293, (2021), 126053 https://doi.org/10.1016/j.jclepro.2021.126053
  6. Qingru Wu, Shuxiao Wang, Mei Yang, Haitao Su, Guoliang Li, Yi Tang, Jiming Hao, Mercury flows in large-scale gold production and implications for Hg pollution control, Journal of Environmental Sciences, 68, (2018), 91-99 https://doi.org/10.1016/j.jes.2017.03.029
  7. J. Zhang, L. Han, Y. Ji, J. Wei, G. Cai, G. Gao, J. Wu, Z. Yao, Heavy metal investigation and risk assessment along the Le'An River from non-ferrous metal mining and smelting activities in Poyang, China, Journal of Environmental Biology, 39, 4, (2018), 536-545 https://doi.org/10.22438/jeb/39/4/MRN-681
  8. S. V. Kakareka, T. I. Kukharchyk, Trends of mercury emissions from the Chlor-Alkali industry in EECCA countries, International Journal of Environmental Sciences, 2, 3, (2012), 1585-1595
  9. Felix Beckers, Jörg Rinklebe, Cycling of mercury in the environment: Sources, fate, and human health implications: A review, Critical Reviews in Environmental Science Technology, 47, 9, (2017), 693-794 https://doi.org/10.1080/10643389.2017.1326277
  10. Janet K. Kern, Anne M. Jones, Evidence of toxicity, oxidative stress, and neuronal insult in autism, Journal of Toxicology Environmental Health, Part B, 9, 6, (2006), 485-499 https://doi.org/10.1080/10937400600882079
  11. Yan Zhou, Xiao-Ming Fu, Dong-Liang He, Xue-Min Zou, Cheng-Qiu Wu, Wei-Zhen Guo, Wei Feng, Evaluation of urinary metal concentrations and sperm DNA damage in infertile men from an infertility clinic, Environmental Toxicology and Pharmacology, 45, (2016), 68-73 https://doi.org/10.1016/j.etap.2016.05.020
  12. Penggang Pei, Yingming Xu, Lin Wang, Xuefeng Liang, Yuebing Sun, Thiol-functionalized montmorillonite prepared by one-step mechanochemical grafting and its adsorption performance for mercury and methylmercury, Science of The Total Environment, 806, (2022), 150510 https://doi.org/10.1016/j.scitotenv.2021.150510
  13. Ying Li, Yangxian Liu, Wei Yang, Lei Liu, Jianfeng Pan, Adsorption of elemental mercury in flue gas using biomass porous carbons modified by microwave/hydrogen peroxide, Fuel, 291, (2021), 120152 https://doi.org/10.1016/j.fuel.2021.120152
  14. Ke Gai, Astrid Avellan, Thomas P. Hoelen, Francisco Lopez-Linares, Evan S. Hatakeyama, Gregory V. Lowry, Impact of mercury speciation on its removal from water by activated carbon and organoclay, Water Research, 157, (2019), 600-609 https://doi.org/10.1016/j.watres.2019.04.006
  15. Lesley Joseph, Byung-Moon Jun, Joseph R. V. Flora, Chang Min Park, Yeomin Yoon, Removal of heavy metals from water sources in the developing world using low-cost materials: A review, Chemosphere, 229, (2019), 142-159 https://doi.org/10.1016/j.chemosphere.2019.04.198
  16. Adane Adugna Ayalew, Comparative adsorptive performance of adsorbents developed from kaolin clay and limestone for de-fluoridation of groundwater, South African Journal of Chemical Engineering, 44, (2023), 1-13 https://doi.org/10.1016/j.sajce.2022.11.002
  17. Amit Kumar Yadav, Sunipa Bhattacharyya, Preparation of porous alumina adsorbent from kaolin using acid leach method: studies on removal of fluoride toxic ions from an aqueous system, Adsorption, 26, (2020), 1073-1082 https://doi.org/10.1007/s10450-019-00193-4
  18. Neeraj Kumari, Chandra Mohan, Basics of clay minerals and their characteristic properties, Clay and Clay Minerals, 24, (2021), 1-29 https://doi.org/10.5772/intechopen.97672
  19. Mohammad Kashif Uddin, A review on the adsorption of heavy metals by clay minerals, with special focus on the past decade, Chemical Engineering Journal, 308, (2017), 438-462 https://doi.org/10.1016/j.cej.2016.09.029
  20. S. Meenakshi, C. Sairam Sundaram, Rugmini Sukumar, Enhanced fluoride sorption by mechanochemically activated kaolinites, Journal of Hazardous Materials, 153, 1-2, (2008), 164-172 https://doi.org/10.1016/j.jhazmat.2007.08.031
  21. W. M. Gitari, T. Ngulube, V. Masindi, J. R. Gumbo, Defluoridation of groundwater using Fe3+-modified bentonite clay: optimization of adsorption conditions, Desalination and Water Treatment, 53, 6, (2015), 1578-1590 https://doi.org/10.1080/19443994.2013.855669
  22. A. Vinati, B. Mahanty, S. K. Behera, Clay and clay minerals for fluoride removal from water: a state-of-the-art review, Applied Clay Science, 114, (2015), 340-348 https://doi.org/10.1016/j.clay.2015.06.013
  23. Rajani Srinivasan, Advances in application of natural clay and its composites in removal of biological, organic, and inorganic contaminants from drinking water, Advances in Materials Science and Engineering, 2011, (2011), 872531 https://doi.org/10.1155/2011/872531
  24. G. J. Churchman, W. P. Gates, B. K. G. Theng, G. Yuan, Clays and Clay Minerals for Pollution Control, in: Developments in Clay Science, Elsevier, 2006, https://doi.org/10.1016/S1572-4352(05)01020-2
  25. Sadia Ata, Anila Tabassum, Ismat Bibi, Farzana Majid, Misbah Sultan, Samina Ghafoor, Muhammad Arif Bhatti, Naseem Qureshi, Munawar Iqbal, Lead remediation using smart materials. A review, Zeitschrift für Physikalische Chemie, 233, 10, (2019), 1377-1409 https://doi.org/10.1515/zpch-2018-1205
  26. Guodong Zhao, Huijuan Zhao, Lei Shi, Bowen Cheng, Xianlin Xu, Xupin Zhuang, In situ loading MnO2 onto 3D Aramid nanofiber aerogel as High-Performance lead adsorbent, Journal of Colloid Interface Science, 600, (2021), 403-411 https://doi.org/10.1016/j.jcis.2021.05.048
  27. M. V. Miljković, Miloš Momčilović, Maja Stanković, Bratislav Ćirković, D. Laketić, Goran S. Nikolić, Maja M. Vujović, Remediation of arsenic contaminated water by a novel carboxymethyl cellulose bentonite adsorbent, Applied Ecology and Environmental Research, 17, 1, (2019), 733-744 http://dx.doi.org/10.15666/aeer/1701_733744
  28. M. Mylarappa, V. Venkata Lakshmi, K. R. Vishnu Mahesh, H. P. Nagaswarupa, N. Raghavendra, A facile hydrothermal recovery of nano sealed MnO2 particle from waste batteries: An advanced material for electrochemical and environmental applications, IOP Conference Series: Materials Science and Engineering, 2016 https://doi.org/10.1088/1757-899X/149/1/012178
  29. S. Louati, S. Baklouti, B. Samet, Geopolymers based on phosphoric acid and illito-kaolinitic clay, Advances in Materials Science and Engineering, 2016, (2016), 2359759 https://doi.org/10.1155/2016/2359759
  30. Liping Kang, Menming Zhang, Zong-Huai Liu, Kenta Ooi, IR spectra of manganese oxides with either layered or tunnel structures, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 67, 3-4, (2007), 864-869 https://doi.org/10.1016/j.saa.2006.09.001
  31. Mohammadi Ahrouch, José M. Gatica, Khalid Draoui, Dolores Bellido, Hilario Vidal, Lead removal from aqueous solution by means of integral natural clays honeycomb monoliths, Journal of Hazardous Materials, 365, (2019), 519-530 https://doi.org/10.1016/j.jhazmat.2018.11.037
  32. O. W. Duckworth, N. A. Rivera, T. G. Gardner, M. Y. Andrews, C. M. Santelli, M. L. Polizzotto, Morphology, structure, and metal binding mechanisms of biogenic manganese oxides in a superfund site treatment system, Environmental Science: Processes & Impacts, 19, (2017), 50-58 https://doi.org/10.1039/C6EM00525J
  33. Laina Radestiani, Lia Destiarti, Winda Rahmalia, Pelapisan Mangan Dioksida pada Pasir Silika dari Kaolin Capkala dan Aplikasinya Sebagai Adsorben Besi (III) dalam Larutan, Jurnal Kimia Khatulistiwa, 7, 4, (2018), 8-15
  34. Yulistya Vidyaning Maulidya, Rudiyansyah Rudiyansyah, Nelly Wahyuni, Adsorpsi Senyawa Organik pada Lindi Menggunakan Cangkang Kerang Ale-Ale (Meretrix meretrix) Secara Batch, Chimica et Natura Acta, 9, 3, (2021), 113-117 https://doi.org/10.24198/cna.v9.n3.35607
  35. Arfiani Devi Atmasari, Faza Amaliya, Laiely Puspita Sari, Adsorption of Cr on Liquid Waste of Tannery Industry using Banana Peel Charcoal in various pH and Time Activation, Indonesian Journal of Chemistry Environment, 2, 1, (2019), 19-24 http://dx.doi.org/10.21831/ijce.v2i1.30292
  36. Fatemeh Gorzin, M. M. Bahri Rasht Abadi, Adsorption of Cr (VI) from aqueous solution by adsorbent prepared from paper mill sludge: Kinetics and thermodynamics studies, Adsorption Science & Technology, 36, 1-2, (2018), 149-169 https://doi.org/10.1177/0263617416686976
  37. Imas Eva Wijayanti, Eka Anisa Kurniawati, Solfarina Solfarina, Studi kinetika adsorpsi isoterm persamaan langmuir dan freundlich pada abu gosok sebagai adsorben, EduChemia, 4, 2, (2019), 175-184 http://dx.doi.org/10.30870/educhemia.v4i2.6119
  38. Darmadi, Mirna Rahmah Lubis, Munadiya Masrura, Aziz Syahfatra, Mahidin, Clay and Zeolite-Clay Based Monoliths as Adsorbents for the Hg (II) Removal from the Aqueous Solutions, International Journal of Technology, 14, 1, (2023), 129-141 https://doi.org/10.14716/ijtech.v14i1.5134
  39. Hui An, Bo Feng, Shi Su, Effect of monolithic structure on CO2 adsorption performance of activated carbon fiber–phenolic resin composite: a simulation study, Fuel, 103, (2013), 80-86 https://doi.org/10.1016/j.fuel.2011.06.076
  40. Oscar D. Caicedo Salcedo, Diana P. Vargas, Liliana Giraldo, Juan Carlos Moreno-Piraján, Study of mercury [Hg (II)]adsorption from aqueous solution on functionalized activated carbon, ACS Omega, 6, 18, (2021), 11849-11856 https://doi.org/10.1021/acsomega.0c06084
  41. Zhiyuan Liu, Yong Sun, Xinrui Xu, Jingbo Qu, Bin Qu, Adsorption of Hg (II) in an aqueous solution by activated carbon prepared from rice husk using KOH activation, ACS Omega, 5, 45, (2020), 29231-29242 https://doi.org/10.1021/acsomega.0c03992
  42. Chenglong Zou, Jiyan Liang, Wei Jiang, Yinyan Guan, Yichen Zhang, Adsorption behavior of magnetic bentonite for removing Hg (II) from aqueous solutions, RSC Advances, 8, 48, (2018), 27587-27595 https://doi.org/10.1039/C8RA05247F
  43. Necmettin Caner, Ahmet Sarı, Mustafa Tüzen, Adsorption characteristics of mercury (II) ions from aqueous solution onto chitosan-coated diatomite, Industrial Engineering Chemistry Research, 54, 30, (2015), 7524-7533 https://doi.org/10.1021/acs.iecr.5b01293
  44. Mohammad A. Al-Ghouti, Dana Da’ana, Mohammed Abu-Dieyeh, Majeda Khraisheh, Adsorptive removal of mercury from water by adsorbents derived from date pits, Scientific Reports, 9, (2019), 15327 https://doi.org/10.1038/s41598-019-51594-y
  45. Dalal Z. Husein, Adsorption and removal of mercury ions from aqueous solution using raw and chemically modified Egyptian mandarin peel, Desalination Water treatment, 51, 34-36, (2013), 6761-6769 https://doi.org/10.1080/19443994.2013.801793
  46. Mahshid Attari, Syed Salman Bukhari, Hossein Kazemian, Sohrab Rohani, A low-cost adsorbent from coal fly ash for mercury removal from industrial wastewater, Journal of Environmental Chemical Engineering, 5, 1, (2017), 391-399 https://doi.org/10.1016/j.jece.2016.12.014
  47. Siti Khadijah Ab. Rahman, Nor Azah Yusof, Abdul Halim Abdullah, Faruq Mohammad, Azni Idris, Hamad A. Al-Lohedan, Evaluation of porogen factors for the preparation of ion imprinted polymer monoliths used in mercury removal, PLoS ONE, 13, 4, (2018), e0195546 https://doi.org/10.1371/journal.pone.0195546
  48. Risti Ragadhita, Asep Bayu Dani Nandiyanto, How to calculate adsorption isotherms of particles using two-parameter monolayer adsorption models and equations, Indonesian Journal of Science & Technology, 6, 1, (2021), 205-234 https://doi.org/10.17509/ijost.v6i1.32354
  49. Rama Rao Karri, J. N. Sahu, Modeling and optimization by particle swarm embedded neural network for adsorption of zinc (II) by palm kernel shell based activated carbon from aqueous environment, Journal of Environmental Management, 206, (2018), 178-191 https://doi.org/10.1016/j.jenvman.2017.10.026
  50. Darmadi Darmadi, Mahidin Mahidin, Siti Syifa Azzahra, Munadiya Masrura, Adsorption of mercury (II) ion in aqueous solution by using bentonite-based monolith, Key Engineering Materials, 885, (2021), 77-84 https://doi.org/10.4028/www.scientific.net/KEM.885.77
  51. P. C. C. Siu, Len Foong Koong, Junaid Saleem, John Barford, Gordon McKay, Equilibrium and kinetics of copper ions removal from wastewater by ion exchange, Chinese Journal of Chemical Engineering, 24, 1, (2016), 94-100 https://doi.org/10.1016/j.cjche.2015.06.017
  52. Pamela Becalli Vilela, Caroline Aparecida Matias, Amanda Dalalibera, Valter Antonio Becegato, Alexandre Tadeu Paulino, Polyacrylic acid-based and chitosan-based hydrogels for adsorption of cadmium: Equilibrium isotherm, kinetic and thermodynamic studies, Journal of Environmental Chemical Engineering, 7, 5, (2019), 103327 https://doi.org/10.1016/j.jece.2019.103327
  53. Peipeng Qiu, Shuting Wang, Chen Tian, Zhang Lin, Adsorption of low-concentration mercury in water by 3D cyclodextrin/graphene composites: synergistic effect and enhancement mechanism, Environmental Pollution, 252, (2019), 1133-1141 https://doi.org/10.1016/j.envpol.2019.06.034
  54. Darmadi Darmadi, Thomas S. Y. Choong, T. G. Chuah, Robiah Yunus, Y. H. Taufiq Yap, Adsorption of methylene blue from aqueous solutions on carbon coated monolith, ASEAN Journal of Chemical Engineering, 8, 1 & 2, (2008), 26-37
  55. Shayan Faghihi, Amin Keykhosravi, Khalil Shahbazi, Modeling of kinetic adsorption of natural surfactants on sandstone minerals: Spotlight on accurate prediction and data evaluation, Colloid and Interface Science Communications, 33, (2019), 100208 https://doi.org/10.1016/j.colcom.2019.100208
  56. Tauqeer Abbas, George William Kajjumba, Meena Ejjada, Sayeda Ummeh Masrura, Erica J. Marti, Eakalak Khan, Tammy L. Jones-Lepp, Recent advancements in the removal of cyanotoxins from water using conventional and modified adsorbents—A contemporary review, Water, 12, 10, (2020), 2756 https://doi.org/10.3390/w12102756
  57. Bibiana Karling Martini, Talita Gomes Daniel, Marcela Zanetti Corazza, Adriana Evaristo de Carvalho, Methyl orange and tartrazine yellow adsorption on activated carbon prepared from boiler residue: Kinetics, isotherms, thermodynamics studies and material characterization, Journal of Environmental Chemical Engineering, 6, 5, (2018), 6669-6679 https://doi.org/10.1016/j.jece.2018.10.013
  58. Yuh-Shan Ho, Review of second-order models for adsorption systems, Journal of Hazardous Materials, 136, 3, (2006), 681-689 https://doi.org/10.1016/j.jhazmat.2005.12.043

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