DOI: https://doi.org/10.14710/jksa.26.10.391-403

Optimized Synthesis of FeNi/TiO2 Green Nanocatalyst for High-Quality Liquid Fuel Production via Mild Pyrolysis

1Chemical Engineering Department, Institut Teknologi Nasional Bandung, PHH. Mustopha 23, 40124 Bandung, Indonesia

2Environmental Engineering Department, Institut Teknologi Nasional Bandung, PHH. Mustopha 23, 40124 Bandung, Indonesia

3Civil Engineering Department, Institut Teknologi Nasional Bandung, PHH. Mustopha 23, 40124 Bandung, Indonesia

4 Nano Center Indonesia, Kawasan Puspitek, Gedung 410 – Ruang B07, Serpong, Indonesia

5 Chemistry Department, Technische Universität Berlin, Straße des 17. Juni 124, 10623 Berlin, Germany

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Received: 25 Sep 2023; Revised: 24 Nov 2023; Accepted: 27 Nov 2023; Published: 23 Dec 2023.
Open Access Copyright 2023 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract
In sustainable energy improvement, the strategic design of economical nanocatalysts has emerged as a pivotal pathway, notably within intricate processes such as asphalt pyrolysis. This study presents a new endeavor, conceptualizing a non-precious metal nanocatalyst FeNi deposited on TiO2, synthesized through an environmentally conscious green synthesis methodology employing mangosteen peel extract as a sustainable reductant. Asphalt, the most complex compound, is used as the pyrolyzed material to measure the activity of nanocatalysts in mild pyrolysis. In this study, the synthesis of the nanocatalyst and pyrolisis are optimized. The research outcomes reflect a notable work towards efficiency enhancement. Initial investigations showcased the highest values before optimization for nanocatalyst synthesis, oil yield, and calorific value, which are 63.23%, 50.78%, and 10684 cal/g, respectively. However, these values increase significantly after optimization to 68.44%, 53.72%, and 10775 cal/g, respectively. Careful validation endeavors have underscored the closeness, manifesting slight errors of 2.52%, 1.86%, and 0.36% for catalyst yield, oil yield, and calorific value, respectively. This validation features the reliability of the research findings. Intriguingly, the GC-MS analysis establishes compelling parallels in composition between the derived product and conventional diesel fuel. The minimal errors and the analogous composition to diesel fuel present a promising trajectory. The results obtained from this study contribute to the development of greener and more efficient energy production technologies, paving the way for a sustainable and eco-friendly approach to utilizing energy resources.
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Keywords: FeNi/TiO2; mild pyrolysis; nanocatalyst; asphalt; Asbuton; diesel-like oil
Funding: Ministry of Technology Research and Higher Education (Ristekdikti)

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Section: Research Articles
Language : EN
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  1. Rick Arneil D. Arancon, Carol Sze Ki Lin, King Ming Chan, Tsz Him Kwan, Rafael Luque, Advances on waste valorization: new horizons for a more sustainable society, Energy Science & Engineering, 1, 2, (2013), 53-71 https://doi.org/10.1002/ese3.9
  2. Mingyuan He, Yuhan Sun, Buxing Han, Green Carbon Science: Efficient Carbon Resource Processing, Utilization, and Recycling towards Carbon Neutrality, Angewandte Chemie International Edition, 61, 15, (2022), e202112835 https://doi.org/10.1002/anie.202112835
  3. Ahmed M. Elgarahy, Ahmed Hammad, Dina M. El-Sherif, Mohamed Abouzid, Mohamed S. Gaballah, Khalid Z. Elwakeel, Thermochemical conversion strategies of biomass to biofuels, techno-economic and bibliometric analysis: A conceptual review, Journal of Environmental Chemical Engineering, 9, 6, (2021), 106503 https://doi.org/10.1016/j.jece.2021.106503
  4. Gong Jing-Song, Fu Wei-Biao, Zhong Bei-Jing, A study on the pyrolysis of asphalt, Fuel, 82, 1, (2003), 49-52 https://doi.org/10.1016/S0016-2361(02)00136-9
  5. Zeyu Bian, Shihan Dai, Liang Wu, Zhe Chen, Mingliang Wang, Dong Chen, Haowei Wang, Thermal stability of Al–Fe–Ni alloy at high temperatures, Journal of Materials Research and Technology, 8, 3, (2019), 2538-2548 https://doi.org/10.1016/j.jmrt.2019.01.028
  6. Ningning Liang, Runrun Xu, Guanzhong Wu, Xuzhou Gao, Yonghao Zhao, High thermal stability of nanocrystalline FeNi2CoMo0.2V0.5 high-entropy alloy by twin boundary and sluggish diffusion, Materials Science and Engineering: A, 848, (2022), 143399
  7. Maryum Ali, Erum Pervaiz, Tayyaba Noor, Osama Rabi, Rubab Zahra, Minghui Yang, Recent advancements in MOF-based catalysts for applications in electrochemical and photoelectrochemical water splitting: A review, International Journal of Energy Research, 45, 2, (2021), 1190-1226 https://doi.org/10.1002/er.5807
  8. Dingding Yao, Chi-Hwa Wang, Pyrolysis and in-line catalytic decomposition of polypropylene to carbon nanomaterials and hydrogen over Fe- and Ni-based catalysts, Applied Energy, 265, (2020), 114819 https://doi.org/10.1016/j.apenergy.2020.114819
  9. Shifei Kang, Maofen He, Chaochuang Yin, Haiyang Xu, Qing Cai, Yangang Wang, Lifeng Cui, Graphitic carbon embedded with Fe/Ni nano-catalysts derived from bacterial precursor for efficient toluene cracking, Green Chemistry, 22, 6, (2020), 1934-1943 https://doi.org/10.1039/C9GC03357B
  10. Qiming Sun, Ning Wang, Qiming Bing, Rui Si, Jingyao Liu, Risheng Bai, Peng Zhang, Mingjun Jia, Jihong Yu, Subnanometric Hybrid Pd-M(OH)2, M = Ni, Co, Clusters in Zeolites as Highly Efficient Nanocatalysts for Hydrogen Generation, Chem, 3, 3, (2017), 477-493 https://doi.org/10.1016/j.chempr.2017.07.001
  11. Yumei Peng, Yiwen Zhang, An Guo, Mingyue Mao, Yi Wang, Yan Long, Guangyin Fan, Universal low-temperature oxidative thermal redispersion strategy for green and sustainable fabrication of oxygen-rich carbons anchored metal nanoparticles for hydrogen evolution reactions, Chemical Engineering Journal, 433, (2022), 133648 https://doi.org/10.1016/j.cej.2021.133648
  12. Haifeng Xiong, Abhaya K. Datye, Yong Wang, Thermally Stable Single-Atom Heterogeneous Catalysts, Advanced Materials, 33, 50, (2021), 2004319 https://doi.org/10.1002/adma.202004319
  13. R. Kumar, V. Strezov, H. Weldekidan, J. He, S. Singh, T. Kan, B. Dastjerdi, Lignocellulose biomass pyrolysis for bio-oil production: A review of biomass pre-treatment methods for production of drop-in fuels, Renewable and Sustainable Energy Reviews, 123, (2020), 109763 https://doi.org/10.1016/j.rser.2020.109763
  14. Abhishek Sharma, Vishnu Pareek, Dongke Zhang, Biomass pyrolysis—A review of modelling, process parameters and catalytic studies, Renewable and Sustainable Energy Reviews, 50, (2015), 1081-1096 https://doi.org/10.1016/j.rser.2015.04.193
  15. Xiaocong Gu, Zong Liu, Meng Li, Jingqi Tian, Ligang Feng, Surface structure regulation and evaluation of FeNi-based nanoparticles for oxygen evolution reaction, Applied Catalysis B: Environmental, 297, (2021), 120462 https://doi.org/10.1016/j.apcatb.2021.120462
  16. Xin Wu, Lei He, Xiaoyang Wang, Enhanced oxygen evolution reaction performance of synergistic effect of TiO2/Ti3C2/FeNi LDH, Ceramics International, 47, 18, (2021), 25755-25762 https://doi.org/10.1016/j.ceramint.2021.05.302
  17. Runze Li, Dingsheng Wang, Superiority of Dual-Atom Catalysts in Electrocatalysis: One Step Further Than Single-Atom Catalysts, Advanced Energy Materials, 12, 9, (2022), 2103564 https://doi.org/10.1002/aenm.202103564
  18. Huidong Xu, Jack Yang, Riyue Ge, Jiujun Zhang, Ying Li, Mingyuan Zhu, Liming Dai, Sean Li, Wenxian Li, Carbon-based bifunctional electrocatalysts for oxygen reduction and oxygen evolution reactions: Optimization strategies and mechanistic analysis, Journal of Energy Chemistry, 71, (2022), 234-265 https://doi.org/10.1016/j.jechem.2022.03.022
  19. Yihu Dai, Ye Wang, Bin Liu, Yanhui Yang, Metallic Nanocatalysis: An Accelerating Seamless Integration with Nanotechnology, Small, 11, 3, (2015), 268-289 https://doi.org/10.1002/smll.201400847
  20. Rongge Zou, Moriko Qian, Chenxi Wang, Wendy Mateo, Yunpu Wang, Leilei Dai, Xiaona Lin, Yunfeng Zhao, Erguang Huo, Lu Wang, Xuesong Zhang, Xiao Kong, Roger Ruan, Hanwu Lei, Biochar: From by-products of agro-industrial lignocellulosic waste to tailored carbon-based catalysts for biomass thermochemical conversions, Chemical Engineering Journal, 441, (2022), 135972 https://doi.org/10.1016/j.cej.2022.135972
  21. David Buceta, Concha Tojo, Miomir B. Vukmirovic, Francis Leonard Deepak, M. Arturo López-Quintela, Controlling Bimetallic Nanostructures by the Microemulsion Method with Subnanometer Resolution Using a Prediction Model, Langmuir, 31, 27, (2015), 7435-7439 https://doi.org/10.1021/acs.langmuir.5b01455
  22. Riny Yolandha Parapat, Michael Schwarze, Alwin Ibrahim, Minoo Tasbihi, Reinhard Schomäcker, Efficient preparation of nanocatalysts. Case study: green synthesis of supported Pt nanoparticles by using microemulsions and mangosteen peel extract, RSC Advances, 12, 53, (2022), 34346-34358 https://doi.org/10.1039/D2RA04134K
  23. Riny Y. Parapat, Firman A. Yudatama, Maya R. Musadi, Michael Schwarze, Reinhard Schomäcker, Antioxidant as Structure Directing Agent in Nanocatalyst Preparation. Case Study: Catalytic Activity of Supported Pt Nanocatalyst in Levulinic Acid Hydrogenation, Industrial & Engineering Chemistry Research, 58, 7, (2019), 2460-2470 https://doi.org/10.1021/acs.iecr.8b03555
  24. Riny Y. Parapat, Veronica Parwoto, Michael Schwarze, Bingsen Zhang, Dang Sheng Su, Reinhard Schomäcker, A new method to synthesize very active and stable supported metal Pt catalysts: thermo-destabilization of microemulsions, Journal of Materials Chemistry, 22, 23, (2012), 11605-11614 https://doi.org/10.1039/C2JM15468D
  25. Concha Tojo, David Buceta, Manuel Arturo López-Quintela, On Metal Segregation of Bimetallic Nanocatalysts Prepared by a One-Pot Method in Microemulsions, Catalysts, 7, 2, (2017), 68 https://doi.org/10.3390/catal7020068
  26. Mustafa Balat, Mehmet Balat, Elif Kırtay, Havva Balat, Main routes for the thermo-conversion of biomass into fuels and chemicals. Part 1: Pyrolysis systems, Energy Conversion and Management, 50, 12, (2009), 3147-3157 https://doi.org/10.1016/j.enconman.2009.08.014
  27. Daegi Kim, Gabin Kim, Doo Young Oh, Kee-Won Seong, Ki Young Park, Enhanced hydrogen production from anaerobically digested sludge using microwave assisted pyrolysis, Fuel, 314, (2022), 123091 https://doi.org/10.1016/j.fuel.2021.123091
  28. Oxana N. Fedyaeva, Anatoly A. Vostrikov, Mikhail Ya Sokol, Anna V. Shatrova, Zinc sulfidation by H2S and H2S/H2O supercritical fluids: Synthesis of nanoparticles and catalytic effect of water, The Journal of Supercritical Fluids, 95, (2014), 669-676 https://doi.org/10.1016/j.supflu.2014.09.046
  29. Yıldırım İsmail Tosun, Benefaction and Pyrolysis of Sirnak Asphaltite and Lignite, International Journal of Clean Coal and Energy, 3, 2, (2014), 13-18 http://dx.doi.org/10.4236/ijcce.2014.32002
  30. Neel Narayan, Ashokkumar Meiyazhagan, Robert Vajtai, Metal Nanoparticles as Green Catalysts, Materials, 12, 21, (2019), 3602 https://doi.org/10.3390/ma12213602
  31. Rajender S. Varma, Greener approach to nanomaterials and their sustainable applications, Current Opinion in Chemical Engineering, 1, 2, (2012), 123-128 https://doi.org/10.1016/j.coche.2011.12.002
  32. Manh Tung Nguyen, Dang Le Tri Nguyen, Changlei Xia, Thanh Binh Nguyen, Mohammadreza Shokouhimehr, Siva Sankar Sana, Andrews Nirmala Grace, Mortaza Aghbashlo, Meisam Tabatabaei, Christian Sonne, Soo Young Kim, Su Shiung Lam, Quyet Van Le, Recent advances in asphaltene transformation in heavy oil hydroprocessing: Progress, challenges, and future perspectives, Fuel Processing Technology, 213, (2021), 106681 https://doi.org/10.1016/j.fuproc.2020.106681
  33. Innocent Chukwunonso Ossai, Aziz Ahmed, Auwalu Hassan, Fauziah Shahul Hamid, Remediation of soil and water contaminated with petroleum hydrocarbon: A review, Environmental Technology & Innovation, 17, (2020), 100526 https://doi.org/10.1016/j.eti.2019.100526
  34. Nurullafina Saadah, Susianto Susianto, Ali Altway, Yeni Rachmawati, Catalytic pyrolysis of Asbuton into liquid fuel with Zeolite as catalyst, Malaysian Journal of Fundamental and Applied Sciences, 16, 2, (2020), 196-200
  35. Laibao Zhang, Zhenghong Bao, Shunxiang Xia, Qiang Lu, Keisha B. Walters, Catalytic Pyrolysis of Biomass and Polymer Wastes, Catalysts, 8, 12, (2018), 659 https://doi.org/10.3390/catal8120659
  36. Ashley Zachariah, Lin Wang, Shaofeng Yang, Vinay Prasad, Arno de Klerk, Suppression of Coke Formation during Bitumen Pyrolysis, Energy & Fuels, 27, 6, (2013), 3061-3070 https://doi.org/10.1021/ef400314m
  37. Ronaldo Irzon, Perbandingan calorific value beragam bahan bakar minyak yang dipasarkan di Indonesia menggunakan bomb calorimeter, Jurnal Geologi dan Sumberdaya Mineral, 22, 4, (2012), 217-223
  38. Yang Mu, Tingting Wang, Jian Zhang, Changgong Meng, Yifu Zhang, Zongkui Kou, Single-Atom Catalysts: Advances and Challenges in Metal-Support Interactions for Enhanced Electrocatalysis, Electrochemical Energy Reviews, 5, (2022), 145-186 https://doi.org/10.1007/s41918-021-00124-4
  39. Dongze Li, Hui Liu, Ligang Feng, A Review on Advanced FeNi-Based Catalysts for Water Splitting Reaction, Energy & Fuels, 34, 11, (2020), 13491-13522 https://doi.org/10.1021/acs.energyfuels.0c03084
  40. Riny Y. Parapat, Muliany Wijaya, Michael Schwarze, Sören Selve, Marc Willinger, Reinhard Schomäcker, Particle shape optimization by changing from an isotropic to an anisotropic nanostructure: preparation of highly active and stable supported Pt catalysts in microemulsions, Nanoscale, 5, 2, (2013), 796-805 https://doi.org/10.1039/C2NR32122J

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