DOI: https://doi.org/10.14710/jksa.25.1.27-33

Humic Acid-Modified Magnetite Nanoparticles for Removing [AuCl4]− in Aqueous Solutions

Departement Chemistry, Universitas Mulawarman, Jl. Barong Tongkok Kampus Gn Kelua Samarinda, Indonesia

Received: 26 Jul 2021; Revised: 22 Jan 2022; Accepted: 24 Jan 2022; Published: 31 Jan 2022.
Open Access Copyright 2022 Jurnal Kimia Sains dan Aplikasi under http://creativecommons.org/licenses/by-sa/4.0.

Citation Format:
Cover Image
Abstract

Humic acid-modified magnetite nanoparticle (MnP-HA) has been synthesized using the co-precipitation method and applied for removal of [AuCl4]−. Modifying of MnP-HA was prepared with the mass ratio of MnP-HA=10:1 and 10:3. The HA was extracted from peat soil of Sambutan Village, East Kalimantan, Indonesia, by the recommended procedure of the International Humic Substances Society (IHSS). The saturation magnetization of MnP-HA was decreased compared to unmodified MnP. The interaction between MnP and HA was occurred due to the chemical bond between Fe from MnP with the carboxylic group from HA. The coating HA on the surface of MnP unchanged the formation of the crystal structure of MnP and increased the particle size. The optimum removal of [AuCl4]− on MnP and MnP-HA materials was optimum at pH 3.0. The Langmuir isotherm model with sorption capacity was 0.23, 4.85, and 4.65 mol g–1 for MnP, MnP-HA=10:1, and 10:3, respectively. Using a pseudo-second-order equation, the degradation of the kinetics model of [AuCl4]− on MnP, MnP-HA=10:1 and 10:3 with adsorption rate constant (k) were 0.02, 0.07, and 0.06 g.mol min–1.

Fulltext View|Download
Keywords: Humic acid; modified; magnetite nanoparticle; removal; [AuCl4]−
Funding: Universitas Mulawarman; Islamic Development Bank

Article Metrics:

Article Info
Section: Research Articles
Language : EN
Recent articles
Humic Acid-Modified Magnetite Nanoparticles for Removing [AuCl4]− in Aqueous Solutions Facile synthesis of 5-Isopropyl-2,3-dimethylbenzene-1,4-diol by Friedel-Crafts and Determination of Partition Coefficient in n- Octanol/Water Antibacterial Activities of Micromonospora sp. 2310 Isolated from Marine Sediment, Baru Island, West Kalimantan More recent articles
Most cited articles
Sintesis Metil Eugenol dan Benzil Eugenol dari Minyak Daun Cengkeh Utilization of Rice Husk Cellulose as a Magnetic Nanoparticle Biocomposite Fiber Source for the Absorption of Manganese (Mn2+) Ions in Peat Water Ekstraksi dan Uji Kestabilan Zat Warna Betasianin dari Kulit Buah Naga (Hylocereus polyrhizus) serta Aplikasinya sebagai Pewarna Alami Pangan Conversion of Wood Waste to be a Source of Alternative Liquid Fuel Using Low Temperature Pyrolysis Method Sintesis Metilisoeugenol dari Metileugenol Menggunakan Katalis KOH dalam Etanol More cited articles
  1. Yusuke Kihara, Kazuto Sazawa, Hideki Kuramitz, Masaaki Kurasaki, Takeshi Saito, Toshiyuki Hosokawa, M. Suhaemi Syawal, Linda Wulandari, I. Hendri, Shunitz Tanaka, Effects of peat fires on the characteristics of humic acid extracted from peat soil in Central Kalimantan, Indonesia, Environmental Science and Pollution Research, 22, 4, (2015), 2384-2395 https://doi.org/10.1007/s11356-014-2929-1
  2. Susan Libes, Introduction to marine biogeochemistry, Academic Press, 2011
  3. Jia Li, Hongzhou Lu, Jie Guo, Zhenming Xu, Yaohe Zhou, Recycle technology for recovering resources and products from waste printed circuit boards, Environmental Science & Technology, 41, 6, (2007), 1995-2000 https://doi.org/10.1021/es0618245
  4. P. F. Sorensen, Gold recovery from carbon-in-pulp eluates by precipitation with a mineral acid I. Precipitation of gold in eluates contaminated with base metals, Hydrometallurgy, 21, 2, (1988), 235-241 https://doi.org/10.1016/0304-386X(88)90008-4
  5. Carmen P. Gomes, Manuel F. Almeida, José M. Loureiro, Gold recovery with ion exchange used resins, Separation and Purification Technology, 24, 1-2, (2001), 35-57 https://doi.org/10.1016/S1383-5866(00)00211-2
  6. Francisco José Alguacil, Paloma Adeva, M. Alonso, Processing of residual gold (III) solutions via ion exchange, Gold Bulletin, 38, 1, (2005), 9-13 https://doi.org/10.1007/BF03215222
  7. R. Ranjbar, M. Naderi, H. Omidvar, Gh. Amoabediny, Gold recovery from copper anode slime by means of magnetite nanoparticles (MNPs), Hydrometallurgy, 143, (2014), 54-59 https://doi.org/10.1016/j.hydromet.2014.01.007
  8. Feng W John Thomas, Barry Crittenden, Adsorption technology and design, Butterworth-Heinemann, 1998
  9. Nan Wang, Lihua Zhu, Dali Wang, Mingqiong Wang, Zhifen Lin, Heqing Tang, Sono-assisted preparation of highly-efficient peroxidase-like Fe3O4 magnetic nanoparticles for catalytic removal of organic pollutants with H2O2, Ultrasonics Sonochemistry, 17, 3, (2010), 526-533 https://doi.org/10.1016/j.ultsonch.2009.11.001
  10. M. Faraji, Y. Yamini, M. Rezaee, Magnetic nanoparticles: synthesis, stabilization, functionalization, characterization, and applications, Journal of the Iranian Chemical Society, 7, 1, (2010), 1-37 https://doi.org/10.1007/BF03245856
  11. Ritu D. Ambashta, Mika Sillanpää, Water purification using magnetic assistance: a review, Journal of Hazardous Materials, 180, 1-3, (2010), 38-49 https://doi.org/10.1016/j.jhazmat.2010.04.105
  12. Jung Kwon Oh, Jong Myung Park, Iron oxide-based superparamagnetic polymeric nanomaterials: design, preparation, and biomedical application, Progress in Polymer Science, 36, 1, (2011), 168-189 https://doi.org/10.1016/j.progpolymsci.2010.08.005
  13. Ligang Chen, Ting Wang, Jia Tong, Application of derivatized magnetic materials to the separation and the preconcentration of pollutants in water samples, TrAC Trends in Analytical Chemistry, 30, 7, (2011), 1095-1108 https://doi.org/10.1016/j.trac.2011.02.013
  14. K. Petcharoen, A. J. M. S. Sirivat, Synthesis and characterization of magnetite nanoparticles via the chemical co-precipitation method, Materials Science and Engineering: B, 177, 5, (2012), 421-427 https://doi.org/10.1016/j.mseb.2012.01.003
  15. D. Maity, D. C. Agrawal, Synthesis of iron oxide nanoparticles under oxidizing environment and their stabilization in aqueous and non-aqueous media, Journal of Magnetism and Magnetic Materials, 308, 1, (2007), 46-55 https://doi.org/10.1016/j.jmmm.2006.05.001
  16. Ling Zhang, Rong He, Hong-Chen Gu, Oleic acid coating on the monodisperse magnetite nanoparticles, Applied Surface Science, 253, 5, (2006), 2611-2617 https://doi.org/10.1016/j.apsusc.2006.05.023
  17. Soerja Koesnarpadi, Sri Juari Santosa, Dwi Siswanta, Bambang Rusdiarso, Humic acid coated Fe3O4 nanoparticle for phenol sorption, Indonesian Journal of Chemistry, 17, 2, (2017), 274-283 https://doi.org/10.22146/ijc.22545
  18. Erzsébet Illés, Etelka Tombácz, The role of variable surface charge and surface complexation in the adsorption of humic acid on magnetite, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 230, 1-3, (2003), 99-109 https://doi.org/10.1016/j.colsurfa.2003.09.017
  19. Erzsébet Illés, Etelka Tombácz, The effect of humic acid adsorption on pH-dependent surface charging and aggregation of magnetite nanoparticles, Journal of Colloid and Interface Science, 295, 1, (2006), 115-123 https://doi.org/10.1016/j.jcis.2005.08.003
  20. Sri Juari Santosa, Shinta Rosalia Dewi, Dwi Siswanta, Eko Sri Kunarti, Esterification of Humin and its Effect on the Removal of AuCl4− from Aqueous Solution, Journal of Ion Exchange, 25, 4, (2014), 151-154 https://doi.org/10.5182/jaie.25.151
  21. Sri Sudiono, Mustika Yuniarti, Dwi Siswanta, Eko Sri Kunarti, Triyono Triyono, Sri Juari Santosa, The Role of Carboxyl and Hydroxyl Groups of Humic Acid in Removing AuCl4- from Aqueous Solution, Indonesian Journal of Chemistry, 17, 1, (2017), 95-104 https://doi.org/10.22146/ijc.23620
  22. Philip Anggo Krisbiantoro, Sri Juari Santosa, Eko Sri Kunarti, Synthesis of Fulvic Acid-Coated Magnetite (Fe3O4–FA) and Its Application for the Reductive Adsorption of [AuCl4]–, Indonesian Journal of Chemistry, 17, 3, (2017), 453-460 https://doi.org/10.22146/IJC.24828
  23. Frank J. Stevenson, Humus chemistry: genesis, composition, reactions, John Wiley & Sons, 1994
  24. Liang Peng, Pufeng Qin, Ming Lei, Qingru Zeng, Huijuan Song, Jiao Yang, Jihai Shao, Bohan Liao, Jidong Gu, Modifying Fe3O4 nanoparticles with humic acid for removal of Rhodamine B in water, Journal of Hazardous Materials, 209, (2012), 193-198 https://doi.org/10.1016/j.jhazmat.2012.01.011
  25. Shen Wu, Aizhi Sun, Fuqiang Zhai, Jin Wang, Wenhuan Xu, Qian Zhang, Alex A. Volinsky, Fe3O4 magnetic nanoparticles synthesis from tailings by ultrasonic chemical co-precipitation, Materials Letters, 65, 12, (2011), 1882-1884 https://doi.org/10.1016/j.matlet.2011.03.065
  26. Xian Zhang, Panyue Zhang, Zhen Wu, Ling Zhang, Guangming Zeng, Chunjiao Zhou, Adsorption of methylene blue onto humic acid-coated Fe3O4 nanoparticles, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 435, (2013), 85-90 https://doi.org/10.1016/j.colsurfa.2012.12.056
  27. Sri Juari Santosa, Philip Anggo Krisbiantoro, Mustika Yuniarti, Soerja Koesnarpardi, Magnetically separable humic acid-functionalized magnetite for reductive adsorption of tetrachloroaurate (III) ion in aqueous solution, Environmental Nanotechnology, Monitoring & Management, 15, (2021), 1-10 https://doi.org/10.1016/j.enmm.2021.100454
  28. Pavel Janoš, Martin Kormunda, František Novák, Ondřej Životský, Jitka Fuitová, Věra Pilařová, Multifunctional humate-based magnetic sorbent: Preparation, properties and sorption of Cu (II), phosphates and selected pesticides, Reactive and Functional Polymers, 73, 1, (2013), 46-52 https://doi.org/10.1016/j.reactfunctpolym.2012.09.001
  29. Yuh-Shan Ho, Gordon McKay, Pseudo-second order model for sorption processes, Process Biochemistry, 34, 5, (1999), 451-465 https://doi.org/10.1016/S0032-9592(98)00112-5

Last update:

No citation recorded.

Last update: 2024-11-13 06:09:23

No citation recorded.